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Polymerization in non-aqueous lyotropic liquid crystals: Influence of the unsaturation site 非水溶性液晶中的聚合:不饱和位点的影响
Colloids and Surfaces Pub Date : 1993-01-18 Epub Date: 2001-10-15 DOI: 10.1016/0166-6622(93)80005-Z
Stig E. Friberg , Bing Yu , Ahsan U. Ahmed , Gregory A. Campbell
{"title":"Polymerization in non-aqueous lyotropic liquid crystals: Influence of the unsaturation site","authors":"Stig E. Friberg ,&nbsp;Bing Yu ,&nbsp;Ahsan U. Ahmed ,&nbsp;Gregory A. Campbell","doi":"10.1016/0166-6622(93)80005-Z","DOIUrl":"10.1016/0166-6622(93)80005-Z","url":null,"abstract":"<div><p>Two surfactants, bis[2-(dodecyloxycarbonyl)ethyl](<em>p</em>-vinylbenzoyl)methylammonium chloride (SI) and bis[2-(10-undecenoyloxycarbonyl)ethyl](<em>p</em>-methylbenzoyl)methylammonium chloride (SII) were synthesized and copolymerized with polar and non-polar monomers to form regularly layered structures.</p><p>The results showed a pronounced difference between the two surfactants. SI with the double bond close to the polar group accepted a large number of monomers, in contrast to the behavior of SII. For SI the polymerization changed the conformation of the <em>p</em>-vinylbenzoyl group depending on the location of the added monomer while copolymerization of the monomers with SII gave no significant change.</p><p>A comparison with earlier results from bis[2-(10-undecenoyloxycarbonyl)ethyl](<em>p</em>-vinylbenzoyl)methylammonium chloride provided proof of copolymerization of all the groups.</p></div>","PeriodicalId":10488,"journal":{"name":"Colloids and Surfaces","volume":"69 4","pages":"Pages 239-247"},"PeriodicalIF":0.0,"publicationDate":"1993-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-6622(93)80005-Z","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73862379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
On the stability of concentrates. Non-aqueous dispersions 精矿稳定性研究。非水乳液
Colloids and Surfaces Pub Date : 1993-01-18 Epub Date: 2001-10-15 DOI: 10.1016/0166-6622(93)80008-4
E. Ruckenstein
{"title":"On the stability of concentrates. Non-aqueous dispersions","authors":"E. Ruckenstein","doi":"10.1016/0166-6622(93)80008-4","DOIUrl":"10.1016/0166-6622(93)80008-4","url":null,"abstract":"<div><p>It is demonstrated that the depth of the potential well between two colloidal particles which interact via van der Waals interactions can be minimized if they are covered with a shell of adsorbed surfactant molecules whose Hamaker constant is near to that or the liquid medium. This result is used to explain some experimental observations (I. Sushumna, R.P. Gupta and E. Ruckenstein, J. Mater. Res., 7 (1992) 2884) which indicate that long-chain fatty acids with an alkyl side chain of 5–10 carbon atoms located far from the head group of the surfactant lead to lower paste viscosities than those without side chains or with longer side alkyl chains. It is also suggested that, in concentrated suspensions, the collective interactions when the pair interaction is attractive can lead to an effective repulsion component between two neighboring particles, and that this effect may contribute to the stability of the concentrated dispersions.</p></div>","PeriodicalId":10488,"journal":{"name":"Colloids and Surfaces","volume":"69 4","pages":"Pages 271-275"},"PeriodicalIF":0.0,"publicationDate":"1993-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-6622(93)80008-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85957537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Micelle dissociation kinetics study by dynamic surface tension of micellar solutions 胶束解离动力学的动态表面张力研究
Colloids and Surfaces Pub Date : 1993-01-18 Epub Date: 2001-10-15 DOI: 10.1016/0166-6622(93)80006-2
V.B. Fainerman, A.V. Makievski
{"title":"Micelle dissociation kinetics study by dynamic surface tension of micellar solutions","authors":"V.B. Fainerman,&nbsp;A.V. Makievski","doi":"10.1016/0166-6622(93)80006-2","DOIUrl":"10.1016/0166-6622(93)80006-2","url":null,"abstract":"<div><p>The dynamic surface of sodium tetradecylsulphate and sodium bexadecylsulphate solutions in water and also in Triton X-100 solutions was measured by the maximum bubble-pressure method, using modern computerized instrumentation, for a wide range of surface lifetimes (from 0.001 to 10 s), temperatures (from 30 to 80°C) and surfactant concentrations (from 1 to 200 CMC). On the basis of a previously suggested adsorption kinetics theory for micellar solutions of ionogenic surfactants (V.B. Fainerman, Colloids Surfaces, 62 (1992) 333) a method was developed for the calculation of the micellar dissociation rate constant <em>k</em>. For the surfactants studied, <em>k</em> increases with increasing concentration. Moreover, for ionic surfactants the dependence of <em>k</em> on concentration (<em>C</em>) becomes more striking for <em>C</em>&gt; (10–30) CMC. This can be explained by a micelle shape transition and by a strengthening of the intermolecular repulsion in micelles. In solutions of the ionic surfactants the constant <em>k</em> increasing with increasing temperature, whereas in Triton X-100 solutions a temperature dependence is absent. This phenomenon is associated with the different nature of the molecular interactions for ionogenic and non-ionogenic surfactants in micelles. The <em>k</em> values, obtained from results of dynamic surface tension measurements, are in satisfactory agreement with the results of a study of the relaxation of micellar solutions published previously.</p></div>","PeriodicalId":10488,"journal":{"name":"Colloids and Surfaces","volume":"69 4","pages":"Pages 249-263"},"PeriodicalIF":0.0,"publicationDate":"1993-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-6622(93)80006-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77473609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
Contact angle kinetics of human albumin solutions at solid surfaces 人白蛋白溶液在固体表面的接触角动力学
Colloids and Surfaces Pub Date : 1993-01-18 Epub Date: 2001-10-15 DOI: 10.1016/0166-6622(93)80001-V
R. Miller , S. Treppo , A. Voigt , W. Zingg , A.W. Neumann
{"title":"Contact angle kinetics of human albumin solutions at solid surfaces","authors":"R. Miller ,&nbsp;S. Treppo ,&nbsp;A. Voigt ,&nbsp;W. Zingg ,&nbsp;A.W. Neumann","doi":"10.1016/0166-6622(93)80001-V","DOIUrl":"10.1016/0166-6622(93)80001-V","url":null,"abstract":"<div><p>Contact angle kinetics of sessile drops of albumin solution on hydrophilic acetal and hydrophobic FC 721 surfaces were measured using axisymmetric drop shape analysis. Young's equation is used to calculate the solid/liquid interfacial tension from measured contact angles and surface tensions as a function of time. The change in solid/liquid interfacial tension is a result of protein adsorption. It indicates that at the hydrophilic acetal surface the albumin molecules, interact only weakly, whereas the interaction with the hydrophobic FC 721 surface is quite strong.</p></div>","PeriodicalId":10488,"journal":{"name":"Colloids and Surfaces","volume":"69 4","pages":"Pages 203-208"},"PeriodicalIF":0.0,"publicationDate":"1993-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-6622(93)80001-V","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73325431","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 33
Open circuit potential measurements with Ti/TiO2 electrodes Ti/TiO2电极开路电位测量
Colloids and Surfaces Pub Date : 1993-01-18 Epub Date: 2001-10-15 DOI: 10.1016/0166-6622(93)80003-X
Marcelo J. Avena, Osvaldo R. Cámara, Carlos P. De Pauli
{"title":"Open circuit potential measurements with Ti/TiO2 electrodes","authors":"Marcelo J. Avena,&nbsp;Osvaldo R. Cámara,&nbsp;Carlos P. De Pauli","doi":"10.1016/0166-6622(93)80003-X","DOIUrl":"10.1016/0166-6622(93)80003-X","url":null,"abstract":"<div><p>The open circuit potential (OCP) vs pH response of Ti/TiO<sub>2</sub> electrodes prepared by thermal and electrochemical oxidation of metallic titanium was measured in KNO<sub>3</sub> aqueous solutions in order to establish whether the slopes of the OCP-pH curves can be used as a measure of the variation of surface potential (ψ<sub>o</sub>) of TiO<sub>2</sub> with the pH of the aqueous solution. For comparison purposes, ψ<sub>o</sub>—pH slopes were also evaluated from surface charge-pH data obtained by acid-base potentiometric titrations of TiO<sub>2</sub> dispersions.</p><p>Ti/TiO<sub>2</sub> electrodes showed a linear OCP-pH response in the range of ph 5–10 with slopes of −0.039 ± 0.005 V ph<sup>−1</sup>. The OCP-pH dependence of Ti/TiO<sub>2</sub> electrodes was lower than that predicted thermodynamically. According to the triple-layer model, used to describe the oxide/aqueous solution interface, the OCP-pH slopes obtained for Ti/TiO<sub>2</sub> electrodes cannot be identified with the variation of ψ<sub>o</sub> with the pH. Calculations with this model indicated that neither the single nor the double extrapolation methods used to evaluate the intrinsic ionization constant of oxide surface sites render realistic values of these parameters for the TiO<sub>2</sub> surface.</p><p>The analysis of surface charge—pH data and the use of the triple-layer model to predict experimental values indicated that the ψ<sub>o</sub>—pH slopes of TiO<sub>2</sub> surfaces must be greater (in absolute magnitude) than 0.041 V pH<sup>−1</sup>.</p></div>","PeriodicalId":10488,"journal":{"name":"Colloids and Surfaces","volume":"69 4","pages":"Pages 217-228"},"PeriodicalIF":0.0,"publicationDate":"1993-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-6622(93)80003-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79238073","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 30
Science and technology of carbon black 炭黑科技
Colloids and Surfaces Pub Date : 1993-01-18 Epub Date: 2001-10-15 DOI: 10.1016/0166-6622(93)80011-4
{"title":"Science and technology of carbon black","authors":"","doi":"10.1016/0166-6622(93)80011-4","DOIUrl":"https://doi.org/10.1016/0166-6622(93)80011-4","url":null,"abstract":"","PeriodicalId":10488,"journal":{"name":"Colloids and Surfaces","volume":"69 4","pages":"Page 293"},"PeriodicalIF":0.0,"publicationDate":"1993-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-6622(93)80011-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136520840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The adsorption of phosphamidon on the surface of antimony(V) phosphate: A thermodynamic study 磷酸锑(V)表面吸附磷酰胺的热力学研究
Colloids and Surfaces Pub Date : 1993-01-18 Epub Date: 2001-10-15 DOI: 10.1016/0166-6622(93)80007-3
K.G. Varshney, A.A. Khan, Upma Gupta, S.M. Maheshwari
{"title":"The adsorption of phosphamidon on the surface of antimony(V) phosphate: A thermodynamic study","authors":"K.G. Varshney,&nbsp;A.A. Khan,&nbsp;Upma Gupta,&nbsp;S.M. Maheshwari","doi":"10.1016/0166-6622(93)80007-3","DOIUrl":"10.1016/0166-6622(93)80007-3","url":null,"abstract":"<div><p>The thermodynamics of the adsorption of phosphamidon on antimony(V) phosphate cation exchanger has been studied at 30, 45 and 50°C and the thermodynamic equilibrium constant (<em>K</em><sub>0</sub>), standard free energy change (Δ<em>G</em>°), enthalpy change (Δ<em>H</em>°) and entropy change (Δ<em>S</em>°) have been calculated to predict its adsorption behaviour. All the data are adequately represented by the Freundlich isotherms.</p></div>","PeriodicalId":10488,"journal":{"name":"Colloids and Surfaces","volume":"69 4","pages":"Pages 265-269"},"PeriodicalIF":0.0,"publicationDate":"1993-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-6622(93)80007-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89678061","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Zeolite '93 沸石93
Colloids and Surfaces Pub Date : 1993-01-18 Epub Date: 2001-10-15 DOI: 10.1016/0166-6622(93)80010-D
{"title":"Zeolite '93","authors":"","doi":"10.1016/0166-6622(93)80010-D","DOIUrl":"https://doi.org/10.1016/0166-6622(93)80010-D","url":null,"abstract":"","PeriodicalId":10488,"journal":{"name":"Colloids and Surfaces","volume":"69 4","pages":"Page 293"},"PeriodicalIF":0.0,"publicationDate":"1993-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-6622(93)80010-D","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136520838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Relaxation of adsorption layers at solution/air interfaces using axisymmetric drop-shape analysis 利用轴对称液滴形状分析溶液/空气界面吸附层的松弛
Colloids and Surfaces Pub Date : 1993-01-18 Epub Date: 2001-10-15 DOI: 10.1016/0166-6622(93)80002-W
R. Miller , R. Sedev , K.-H. Schano , C. Ng , A.W. Neumann
{"title":"Relaxation of adsorption layers at solution/air interfaces using axisymmetric drop-shape analysis","authors":"R. Miller ,&nbsp;R. Sedev ,&nbsp;K.-H. Schano ,&nbsp;C. Ng ,&nbsp;A.W. Neumann","doi":"10.1016/0166-6622(93)80002-W","DOIUrl":"10.1016/0166-6622(93)80002-W","url":null,"abstract":"<div><p>Axisymmetric drop-shape analysis is used to investigate the relaxation of surfactant adsorption layers after transient interfacial area changes, e.g. square-pulse or step-type disturbances. The response functions for sodium dodecyl sulfate solutions of different origin and for sodium tetradecyl sulfate are measured and interpreted in terms of a diffusion-controlled matter-exchange model. For both surfactant systems the data can be explained by considering small amounts of surface-active contaminations.</p></div>","PeriodicalId":10488,"journal":{"name":"Colloids and Surfaces","volume":"69 4","pages":"Pages 209-216"},"PeriodicalIF":0.0,"publicationDate":"1993-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-6622(93)80002-W","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79558619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 67
Dissolution of solid particles in liquids: A reaction—diffusion model 固体颗粒在液体中的溶解:一个反应-扩散模型
Colloids and Surfaces Pub Date : 1993-01-18 Epub Date: 2001-10-15 DOI: 10.1016/0166-6622(93)80004-Y
Jyh-Ping Hsu, Bo-Tau Liu
{"title":"Dissolution of solid particles in liquids: A reaction—diffusion model","authors":"Jyh-Ping Hsu,&nbsp;Bo-Tau Liu","doi":"10.1016/0166-6622(93)80004-Y","DOIUrl":"10.1016/0166-6622(93)80004-Y","url":null,"abstract":"<div><p>The dissolution of solid particles in liquids involves the dissociation of solute molecules through a surface reaction and the subsequent diffusion of these molecules toward the bulk liquid phase. The conventional analysis is mainly based upon extreme cases, i.e. the rate of dissolution is either controlled by surface reaction or by molecular diffusion. Here, the analysis is generalized so that the diffusional resistance and the resistance for the surface reaction are considered simultaneously. Also, the effect of the variation of the solute concentration in the bulk liquid phase on dissolution is taken into account. The applicability of the present model is justified by analyzing the experimental results for the dissolution or human enamel powder in water. The evaporation of a water drop in air and the dissolution of 2-naphthol in water are also discussed. It is concluded that neglecting the effect of the surface reaction in the dissolution kinetics may lead to a significant deviation between experimental data and theoretical calculation.</p></div>","PeriodicalId":10488,"journal":{"name":"Colloids and Surfaces","volume":"69 4","pages":"Pages 229-238"},"PeriodicalIF":0.0,"publicationDate":"1993-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0166-6622(93)80004-Y","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77815690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
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