Supramolecular Catalysis最新文献

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Chemical Catalyst‐Promoted Regioselective Histone Acylation 化学催化剂-促进区域选择性组蛋白酰化
Supramolecular Catalysis Pub Date : 2021-12-31 DOI: 10.1002/9783527832033.ch36
Yuki Yamanashi, M. Kanai
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引用次数: 0
Supramolecular Interactions in Distal C – H Activation of (Hetero)arenes (杂)芳烃远端C - H活化中的超分子相互作用
Supramolecular Catalysis Pub Date : 2021-12-31 DOI: 10.1002/9783527832033.ch10
J. Biswas, D. Maiti
{"title":"Supramolecular Interactions in Distal\u0000 C\u0000 –\u0000 H\u0000 Activation of (Hetero)arenes","authors":"J. Biswas, D. Maiti","doi":"10.1002/9783527832033.ch10","DOIUrl":"https://doi.org/10.1002/9783527832033.ch10","url":null,"abstract":"","PeriodicalId":103115,"journal":{"name":"Supramolecular Catalysis","volume":"30 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121404941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Supramolecular Catalysis by Metallohosts Based on Glycoluril 基于羟基脲的金属宿主的超分子催化作用
Supramolecular Catalysis Pub Date : 2021-12-31 DOI: 10.1002/9783527832033.ch21
J. P. Bruekers, J. Elemans, R. Nolte
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引用次数: 0
Index 指数
Supramolecular Catalysis Pub Date : 2021-12-31 DOI: 10.1002/9783527832033.index
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引用次数: 0
Supramolecularly Regulated Enantioselective Catalysts 超分子调控对映选择性催化剂
Supramolecular Catalysis Pub Date : 2021-12-31 DOI: 10.1002/9783527832033.ch40
A. Vidal‐Ferran
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引用次数: 0
Surfactant Assemblies as Nanoreactors for Organic Transformations 表面活性剂组装体作为有机转化的纳米反应器
Supramolecular Catalysis Pub Date : 2021-12-31 DOI: 10.1002/9783527832033.ch32
M. Cortes‐Clerget, Joseph R. A. Kincaid, Nnamdi Akporji, B. Lipshutz
{"title":"Surfactant Assemblies as Nanoreactors for Organic Transformations","authors":"M. Cortes‐Clerget, Joseph R. A. Kincaid, Nnamdi Akporji, B. Lipshutz","doi":"10.1002/9783527832033.ch32","DOIUrl":"https://doi.org/10.1002/9783527832033.ch32","url":null,"abstract":"","PeriodicalId":103115,"journal":{"name":"Supramolecular Catalysis","volume":"38 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134048982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Supramolecular Construction of Bidentate Ligands Through Self‐assembly by Hydrogen Bonding 通过氢键自组装构建双齿配体的超分子结构
Supramolecular Catalysis Pub Date : 2021-12-31 DOI: 10.1002/9783527832033.ch1
Felix Bauer, B. Breit
{"title":"Supramolecular Construction of Bidentate Ligands Through Self‐assembly by Hydrogen Bonding","authors":"Felix Bauer, B. Breit","doi":"10.1002/9783527832033.ch1","DOIUrl":"https://doi.org/10.1002/9783527832033.ch1","url":null,"abstract":"In classical transition metal catalysis, phosphine ligands have a dominant position in controlling catalysts activity and selectivity [1, 2]. Monodentate phosphine ligands show in many catalytic transformations higher catalytic activity but lower selectivity. In contrast, bidentate ligands in which two phosphorus donors are combined by a covalent backbone often show superior selectivity in many transformations. Some of these bidentate ligands were designed to achieve high selectivity in a specific reaction. However, a disadvantage is their often lower activity compared with monodentate ligands. Moreover, the synthesis of these ligands is in most cases complicated involving a multistep route to the target ligand. This is especially a drawback in the synthesis of nonsymmetrical bidentate ligands equipped with two different donor sites. In order to overcome these limitations, supramolecular chemistry offers a powerful tool [3–5]. In this conceptually new approach, structurally less complicated monodentate ligands might self-assemble into a bidentate coordination mode in a transition metal complex by noncovalent interactions. Nature provides many noncovalent interactions such as van der Waals interactions, π-stacking, electrostatic interactions, coordinative interactions, or hydrogen bonding [3]. Among them probably the most prominent interaction is hydrogen bonding, highlighted especially in DNA where they connect the single strands of the double helix [3, 6]. This feature can be seen as an inspiration to replace covalent bonds in the backbone of a bidentate ligand (Scheme 1.1). The high potential of this approach is beyond a simplified ligand design and lies in the inherent possibility to generate a combinatorial ligand library through simple mixing of two ligands. This means if two different ligands are coordinated to one transition metal center from n different monodentate donor ligands, a catalyst library with (n2 + n)/2MLxLy could be obtained (Table 1.1). On the other hand, when the interaction between two ligands bound to one metal center is noncomplementary, a mixture of two homodimeric and one heterodimeric","PeriodicalId":103115,"journal":{"name":"Supramolecular Catalysis","volume":"85 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114272482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Asymmetric Supramolecular Organocatalysis: The Fourth Pillar of Catalysis 不对称超分子有机催化:催化的第四支柱
Supramolecular Catalysis Pub Date : 2021-12-31 DOI: 10.1002/9783527832033.ch30
K. Anebouselvy, K. S. Shruthi, D. Ramachary
{"title":"Asymmetric Supramolecular Organocatalysis: The Fourth Pillar of Catalysis","authors":"K. Anebouselvy, K. S. Shruthi, D. Ramachary","doi":"10.1002/9783527832033.ch30","DOIUrl":"https://doi.org/10.1002/9783527832033.ch30","url":null,"abstract":"","PeriodicalId":103115,"journal":{"name":"Supramolecular Catalysis","volume":"66 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128724866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Supramolecular Assembly of DNA ‐ and Protein‐Based Artificial Metalloenzymes 基于DNA和蛋白质的人工金属酶的超分子组装
Supramolecular Catalysis Pub Date : 2021-12-31 DOI: 10.1002/9783527832033.ch38
G. Roelfes
{"title":"Supramolecular Assembly of\u0000 DNA\u0000 ‐ and Protein‐Based Artificial Metalloenzymes","authors":"G. Roelfes","doi":"10.1002/9783527832033.ch38","DOIUrl":"https://doi.org/10.1002/9783527832033.ch38","url":null,"abstract":"","PeriodicalId":103115,"journal":{"name":"Supramolecular Catalysis","volume":"60 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123239528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self‐amplification of Enantioselectivity in Asymmetric Catalysis by Supramolecular Recognition and Stereodynamics 超分子识别和立体动力学对不对称催化中对映体选择性的自扩增
Supramolecular Catalysis Pub Date : 2021-12-31 DOI: 10.1002/9783527832033.ch4
O. Trapp
{"title":"Self‐amplification of Enantioselectivity in Asymmetric Catalysis by Supramolecular Recognition and Stereodynamics","authors":"O. Trapp","doi":"10.1002/9783527832033.ch4","DOIUrl":"https://doi.org/10.1002/9783527832033.ch4","url":null,"abstract":"","PeriodicalId":103115,"journal":{"name":"Supramolecular Catalysis","volume":"24 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125219404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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