Spectrochimica Acta最新文献_第6页

Infra-red spectra of some metal acetylacetonates 某些金属乙酰丙酮酸酯的红外光谱

Spectrochimica Acta Pub Date : 1966-09-01 DOI: 10.1016/0371-1951(66)80157-1

Y. Kawasaki, T. Tanaka, R. Okawara

{"title":"Infra-red spectra of some metal acetylacetonates","authors":"Y. Kawasaki, T. Tanaka, R. Okawara","doi":"10.1016/0371-1951(66)80157-1","DOIUrl":"10.1016/0371-1951(66)80157-1","url":null,"abstract":"<div>Infra-red spectra of a series of acetylacetonates XX′Sn(acac)2 (X, X′ = alkyl, aryl and/or halogen), (CH3)2Pb(acac)2, Cl2Ti(acac)2, Cl2Ge(acac)2 and Cl4Sb(acac) have been measured in the region of 4000-400 cm−1. The absorption bands in XX′Sn(acac)2 are classified into three groups. The bands in the first group decrease in frequency with increasing electron attracting power of substituents X and/or X′ and those in the second group show an opposite behaviour. The bands in the third group are almost independent of the substituents. From the substituent dependence of the frequency, the upper strong band in the region of 1600-1500 cm−1 is assigned to a perturbed CO stretching band and the lower band to a perturbed CC stretching band. The separation of these two bands becomes small as the electron attracting power of substituents increases and in Cl4Sb(acac), which may be an extreme case, only a single sharp band is observed. The substituent sensitive bands in XX′Sn(acac)2 in the region of 700-400 cm−1 have been found to correspond to metal sensitive bands of usual metal acetylacetonates M(acac)n (n = 1, 2, 3 and 4).</div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 9","pages":"Pages 1571-1579"},"PeriodicalIF":0.0,"publicationDate":"1966-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80157-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81953072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 36

Steric factors affecting hydrogen-bonding between amide groups 影响酰胺基团间氢键的位阻因素

Spectrochimica Acta Pub Date : 1966-09-01 DOI: 10.1016/0371-1951(66)80155-8

R.Lumley Jones

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引用次数: 18

Intramolecular hydrogen bonding of methoxynaphthoic acids and methyl hydroxynaphthoates 甲氧基萘酸和甲基羟基萘酸的分子内氢键

Spectrochimica Acta Pub Date : 1966-09-01 DOI: 10.1016/0371-1951(66)80153-4

M. Ōki , M. Hirota , S. Hirofuji

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引用次数: 8

Mechanism of delayed excimer fluorescence in solution 溶液中延迟准分子荧光的机理

Spectrochimica Acta Pub Date : 1966-09-01 DOI: 10.1016/0371-1951(66)80167-4

C.A. Parker

引用次数: 15

CH-Bindungsmomente und IR-Intensität von Benzol-Derivaten—IV. CH-Valenzschwingungen 2-, 3- und 4-substituierter Pyridinderivate 苯类衍生品的国际互操作性。2、3、4换过的迷幻剂

Spectrochimica Acta Pub Date : 1966-09-01 DOI: 10.1016/0371-1951(66)80165-0

E.D. Schmid, R. Joeckle

引用次数: 16

Investigations on the microwave spectrum of meta-di-fluoro-benzene 间位二氟苯的微波光谱研究

Spectrochimica Acta Pub Date : 1966-09-01 DOI: 10.1016/0371-1951(66)80154-6

A Rachmant

引用次数: 5

Infrared intensity measurements—II. Chloroethylenes 红外强度测量- 2。氯乙烯

Spectrochimica Acta Pub Date : 1966-09-01 DOI: 10.1016/0371-1951(66)80160-1

J.T. Shimozawa , M.K. Wilson

引用次数: 5

CH-Bindungsmomente und IR-Intensitäten von Benzol-Derivaten—I. Einführung 苯类衍生品之间的国际联系时间。引入

Spectrochimica Acta Pub Date : 1966-09-01 DOI: 10.1016/0371-1951(66)80162-5

E.D. Schmid, V. Hoffmann, R. Joeckle, F. Langenbucher

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引用次数: 11

Infrared intensity measurements—I. Experimental conditions and a standard band 红外强度测量- 1。实验条件和标准波段

Spectrochimica Acta Pub Date : 1966-09-01 DOI: 10.1016/0371-1951(66)80159-5

J.T. Shimozawa , M.K. Wilson

引用次数: 10

Spectrochemical analysis of molten metal using a pulsed laser source 用脉冲激光源对熔融金属进行光谱化学分析

Spectrochimica Acta Pub Date : 1966-09-01 DOI: 10.1016/0371-1951(66)80168-6

E.F. Runge, S. Bonfiglio, F.R. Bryan

引用次数: 37