Inorganica Chimica Acta Reviews最新文献

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The application of Mössbauer spectroscopy in the study of mixed ligand complexes Mössbauer光谱在混合配体配合物研究中的应用
Inorganica Chimica Acta Reviews Pub Date : 1972-12-01 DOI: 10.1016/0073-8085(72)80010-X
K Burger
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引用次数: 12
Anticancer drug design involving complexes of amino-acids and metal ions 涉及氨基酸和金属离子复合物的抗癌药物设计
Inorganica Chimica Acta Reviews Pub Date : 1972-12-01 DOI: 10.1016/0073-8085(72)80014-7
David R Williams
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引用次数: 21
Hydrido complexes of rhenium: Synthesis and reactivity 铼的氢化物配合物:合成及反应性
Inorganica Chimica Acta Reviews Pub Date : 1972-12-01 DOI: 10.1016/0073-8085(72)80012-3
D Guisto
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引用次数: 11
Anticancer drug design involving complexes of amino-acids and metal ions 涉及氨基酸和金属离子复合物的抗癌药物设计
Inorganica Chimica Acta Reviews Pub Date : 1972-12-01 DOI: 10.1016/0073-8085(72)80014-7
David R. Williams
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引用次数: 21
Metal complexes of sulphur-containing amino acids 含硫氨基酸的金属配合物
Inorganica Chimica Acta Reviews Pub Date : 1972-12-01 DOI: 10.1016/0073-8085(72)80013-5
C.A McAuliffe, S.G Murray
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引用次数: 70
Electronic crystal spectra for coordination complexes of platinum(II) 铂(II)配位配合物的电子晶体光谱
Inorganica Chimica Acta Reviews Pub Date : 1971-12-01 DOI: 10.1016/0073-8085(71)80014-1
Don S. Martin Jr.
{"title":"Electronic crystal spectra for coordination complexes of platinum(II)","authors":"Don S. Martin Jr.","doi":"10.1016/0073-8085(71)80014-1","DOIUrl":"10.1016/0073-8085(71)80014-1","url":null,"abstract":"<div><p>The limited number of crystals of platinum(II), discussed here have provided a great deal of information both about the molecular energy levels and about crystal interactions. The spectra have provided a definitive assignment of energy states of PtCl<sup>2</sup><sub>4</sub> from the vibronic selection rules in a system with a rigorous center of symmetry. With KPt(NH<sub>3</sub>)Cl<sub>3</sub>·H<sub>2</sub>O the effect of a ligand field asymmetry combined with vibronic excitation has been demonstrated. With Pt(en)Cl<sub>2</sub>, however, spectra are dominated by crystal effects, and compelling evidence for the excitation of ionic exciton has been uncovered. Each of these crystals possesses a structure in either tetragonal or orthorhombic lattices with alignment of ions or molecules which could scarcely be more favorable for interpretation. Unfortunately, such ideal structures must be rare. In addition, it is necessary to prepare exceedingly thin and fragile crystals in order to exploit even the highly forbidden d-d bands. Limitations in preparative techniques for crystals suitable for spectral work may well severely curtail the number of systems which can be studied profitably.</p></div>","PeriodicalId":100676,"journal":{"name":"Inorganica Chimica Acta Reviews","volume":"5 ","pages":"Pages 107-125"},"PeriodicalIF":0.0,"publicationDate":"1971-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0073-8085(71)80014-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82068446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
Magnetic exchange in transition metal complexes vi: Aspects of exchange coupling in magnetic cluster complexes 过渡金属配合物中的磁交换vi:磁团簇配合物中交换耦合的方面
Inorganica Chimica Acta Reviews Pub Date : 1971-12-01 DOI: 10.1016/0073-8085(71)80012-8
A. P. Gingsberg
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引用次数: 197
Uranyl chelate complexes 铀酰螯合物
Inorganica Chimica Acta Reviews Pub Date : 1971-12-01 DOI: 10.1016/0073-8085(71)80011-6
L. Cattalini, U. Croatto, S. Degetto, E. Tondello
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引用次数: 85
Uranyl chelate complexes 铀酰螯合物
Inorganica Chimica Acta Reviews Pub Date : 1971-12-01 DOI: 10.1016/0073-8085(71)80011-6
L. Cattalini , U. Croatto , S. Degetto , E. Tondello
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引用次数: 85
Trans activation and limiting SN1 mechanisms for substitution reactions of cobalt(III) complexes in aqueous solution 水溶液中钴(III)配合物取代反应的反式活化和限制SN1机制
Inorganica Chimica Acta Reviews Pub Date : 1971-12-01 DOI: 10.1016/0073-8085(71)80010-4
J.E. Byrd, W.K. Wilmarth
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引用次数: 18
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