China Particuology最新文献

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Dispersion behavior of core–shell silica-polymer nanoparticles 核-壳硅-聚合物纳米颗粒的分散行为
China Particuology Pub Date : 2007-08-01 DOI: 10.1016/j.cpart.2007.04.004
Yi Wang, Yangchuan Ke, Jingzi Li, Shouqin Du, Yanfeng Xia
{"title":"Dispersion behavior of core–shell silica-polymer nanoparticles","authors":"Yi Wang,&nbsp;Yangchuan Ke,&nbsp;Jingzi Li,&nbsp;Shouqin Du,&nbsp;Yanfeng Xia","doi":"10.1016/j.cpart.2007.04.004","DOIUrl":"10.1016/j.cpart.2007.04.004","url":null,"abstract":"<div><p>Core–shell silica nanoparticles are superior in modifying surface wetting behavior, enhancing nucleation and growth in crystallization, improving dispersion of naked nanoparticles, and thus upgrading the overall properties of organic polymers. The dispersion behavior and morphology of monodisperse core–shell silica particles in several polymers including polyesters are reviewed and their potential applications are discussed.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 4","pages":"Pages 300-304"},"PeriodicalIF":0.0,"publicationDate":"2007-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.04.004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88566747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 15
Numerical modeling of gas-phase kinetics in formation of secondary aerosol 二次气溶胶形成气相动力学的数值模拟
China Particuology Pub Date : 2007-08-01 DOI: 10.1016/j.cpart.2007.05.002
Wang-Kun Chen , Ping Wang
{"title":"Numerical modeling of gas-phase kinetics in formation of secondary aerosol","authors":"Wang-Kun Chen ,&nbsp;Ping Wang","doi":"10.1016/j.cpart.2007.05.002","DOIUrl":"10.1016/j.cpart.2007.05.002","url":null,"abstract":"<div><p>Three basic modules of gas-phase photochemical reactions involved in the formation of secondary aerosol are developed for modeling the concentration variation of precursors of aerosol, including ketone (RCO<sub><em>x</em></sub>), aldehyde (ALD), peroxyacetylnitrate (PAN), NO<sub>2</sub>, and SO<sub>2</sub>, followed by numerical solution for each of the modules. Reasonable trends of concentration variation of the precursors can be obtained from the proposed modules.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 4","pages":"Pages 267-273"},"PeriodicalIF":0.0,"publicationDate":"2007-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.05.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85770673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Bubble dynamics in a two-dimensional gas–solid fluidized bed 二维气固流化床中的气泡动力学
China Particuology Pub Date : 2007-08-01 DOI: 10.1016/j.cpart.2007.04.002
Ruoyu Hong , Zhiqiang Ren, Jianmin Ding , M. Kawaji , Hongzhong Li
{"title":"Bubble dynamics in a two-dimensional gas–solid fluidized bed","authors":"Ruoyu Hong ,&nbsp;Zhiqiang Ren,&nbsp;Jianmin Ding ,&nbsp;M. Kawaji ,&nbsp;Hongzhong Li","doi":"10.1016/j.cpart.2007.04.002","DOIUrl":"10.1016/j.cpart.2007.04.002","url":null,"abstract":"<div><p>Related referential studies on gas–solid two-phase flows were briefly reviewed. Bubble ascending in a two-dimensional (2D) gas–solid fluidized bed was studied both experimentally and numerically. A modified continuum model expressed in the conservation form was used in numerical simulation. Solid-phase pressure was modeled via local sound speed; gas-phase turbulence was described by the <em>K</em>–<em>ɛ</em> two-equation model. The modified implicit multiphase formulation (IMF) scheme was used to solve the model equations in 2D Cartesian/cylindrical coordinates. The bubble ascending velocity and particle motion in the 2D fluidized bed were measured using the photochromic dye activation (PDA) technique, which was based on UV light activation of particles impregnated with the dye. Effects of bed height and superficial gas velocity on bubble formation and ascent were investigated numerically. The numerically obtained bubble ascending velocities were compared with experimental measurements. Gas bubble in jetting gas–solids fluidized bed was also simulated numerically.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 4","pages":"Pages 284-294"},"PeriodicalIF":0.0,"publicationDate":"2007-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.04.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75209779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Characteristics of elemental carbon and organic carbon in PM10 during spring and autumn in Chongqing, China 重庆地区春秋季PM10中元素碳和有机碳特征
China Particuology Pub Date : 2007-08-01 DOI: 10.1016/j.cpart.2007.03.009
Di Ye, Qi Zhao, Changtan Jiang, Jun Chen, Xiaoxing Meng
{"title":"Characteristics of elemental carbon and organic carbon in PM10 during spring and autumn in Chongqing, China","authors":"Di Ye,&nbsp;Qi Zhao,&nbsp;Changtan Jiang,&nbsp;Jun Chen,&nbsp;Xiaoxing Meng","doi":"10.1016/j.cpart.2007.03.009","DOIUrl":"10.1016/j.cpart.2007.03.009","url":null,"abstract":"<div><p>PM<sub>10</sub> (particulate matter with aerodynamic diameter less than 10<!--> <!-->μm) samples were collected simultaneously at nine urban sites and one urban background site during two intensive observation campaigns in 2006. Concentrations of elemental carbon (EC) and organic carbon (OC) in PM<sub>10</sub> were analyzed using an element analyzer. The characteristics regarding spatial and seasonal distribution patterns of OC and EC concentrations and their contributions to PM<sub>10</sub> mass, as well as correlation between OC and EC, were investigated in detail. The average OC and EC concentrations for urban sites were 57.5<!--> <!-->±<!--> <!-->20.8 and 8.3<!--> <!-->±<!--> <!-->3.9<!--> <!-->μg/m<sup>3</sup>, respectively, both being around three times higher than those for urban background site. As a whole, EC concentrations did not show distinct seasonal variations, though OC concentrations were generally higher in autumn than in spring. For urban sites, total carbonaceous aerosol (TCA) accounted for 33.2% in spring and 35.0% in autumn of PM<sub>10</sub> mass. The OC and EC concentrations were found significantly correlated to each other both in spring and in autumn, implying the existence of similar emission sources such as coal combustion. The OC/EC ratios generally exceeded 2.0, indicating the presence of secondary organic carbon (SOC), whose estimated concentration for urban Chongqing was 26.7 and 39.4<!--> <!-->μg/m<sup>3</sup>, accounting for 48.9 and 61.9% of the total OC observed in the samples, in spring and in autumn, respectively.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 4","pages":"Pages 255-260"},"PeriodicalIF":0.0,"publicationDate":"2007-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.03.009","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87466726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 17
Effect of process conditions on the synthesis of carbon nanotubes by catalytic decomposition of methane 工艺条件对甲烷催化分解合成碳纳米管的影响
China Particuology Pub Date : 2007-06-01 DOI: 10.1016/j.cpart.2007.03.004
Shuanglin Zhan , Yajun Tian , Yanbin Cui , Hao Wu , Yonggang Wang , Shufeng Ye , Yunfa Chen
{"title":"Effect of process conditions on the synthesis of carbon nanotubes by catalytic decomposition of methane","authors":"Shuanglin Zhan ,&nbsp;Yajun Tian ,&nbsp;Yanbin Cui ,&nbsp;Hao Wu ,&nbsp;Yonggang Wang ,&nbsp;Shufeng Ye ,&nbsp;Yunfa Chen","doi":"10.1016/j.cpart.2007.03.004","DOIUrl":"10.1016/j.cpart.2007.03.004","url":null,"abstract":"<div><p>A new dual-composition catalyst based on Ni–Mo/MgO with high efficiency of producing carbon nanotubes (CNTs) from methane was reported recently. In the present article, with this type of catalyst, the impact of such experimental parameters as reaction temperature, reaction time, concentration of H<sub>2</sub>, flow rate ratio of CH<sub>4</sub> to H<sub>2</sub> on yield and graphitization were investigated, leading to the following optimal growth conditions: reaction time 60<!--> <!-->min, reaction temperature 900<!--> <!-->°C, CH<sub>4</sub>:H<sub>2</sub> about 100:20<!--> <!-->mL/min, under which high-yield multi-walled CNTs bundles were synthesized. Raman measurement indicated that the as-synthesized product was well-graphitized, and the purity was estimated over 95% by TG–DSC analysis. In terms of the above results, an explanation of high-efficiency formation of CNTs bundles and the co-catalysis mechanism of Ni–Mo/MgO were suggested.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 3","pages":"Pages 213-219"},"PeriodicalIF":0.0,"publicationDate":"2007-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.03.004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84019945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 31
Nanohybrid TiO2/carbon black sensor for NO2 gas 二氧化钛/炭黑纳米杂化传感器用于NO2气体
China Particuology Pub Date : 2007-06-01 DOI: 10.1016/J.CPART.2007.03.005
W. Liou, Hong‐Ming Lin
{"title":"Nanohybrid TiO2/carbon black sensor for NO2 gas","authors":"W. Liou, Hong‐Ming Lin","doi":"10.1016/J.CPART.2007.03.005","DOIUrl":"https://doi.org/10.1016/J.CPART.2007.03.005","url":null,"abstract":"","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"23 1","pages":"225-229"},"PeriodicalIF":0.0,"publicationDate":"2007-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86821992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
Ground-based measurements of aerosol optical properties and radiative forcing in North China 中国北方气溶胶光学特性和辐射强迫的地面测量
China Particuology Pub Date : 2007-06-01 DOI: 10.1016/j.cpart.2007.03.008
Hongbin Chen, Xiangao Xia, Pucai Wang, Wenxing Zhang
{"title":"Ground-based measurements of aerosol optical properties and radiative forcing in North China","authors":"Hongbin Chen,&nbsp;Xiangao Xia,&nbsp;Pucai Wang,&nbsp;Wenxing Zhang","doi":"10.1016/j.cpart.2007.03.008","DOIUrl":"https://doi.org/10.1016/j.cpart.2007.03.008","url":null,"abstract":"<div><p>In order to gain an insight into the aerosol properties and their climatic effect over the continental source regions of China, it is of significance to carry out long-term ground-based measurements of aerosol optical properties and radiative forcing. A couple of temporary and permanent Aerosol Robotic Network (AERONET) sites and three comprehensive radiative sites were established in China as a result of international cooperation in recent years. Heavy aerosol loading and significant temporal and spatial variation over North China are revealed by the AERONET data. Aerosol-induced reductions in surface radiation budget are examined on the basis of collocated observations by sun photometers and pyranometers.</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 3","pages":"Pages 202-205"},"PeriodicalIF":0.0,"publicationDate":"2007-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.03.008","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91675617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
A novel method of supporting gold nanoparticles on MWCNTs: Synchrotron X-ray reduction 在MWCNTs上负载金纳米颗粒的新方法:同步加速器x射线还原
China Particuology Pub Date : 2007-06-01 DOI: 10.1016/j.cpart.2007.03.007
Kuan-Nan Lin , Tsung-Yeh Yang , Hong-Ming Lin , Yeu-Kuang Hwu , She-Huang Wu , Chung-Kwei Lin
{"title":"A novel method of supporting gold nanoparticles on MWCNTs: Synchrotron X-ray reduction","authors":"Kuan-Nan Lin ,&nbsp;Tsung-Yeh Yang ,&nbsp;Hong-Ming Lin ,&nbsp;Yeu-Kuang Hwu ,&nbsp;She-Huang Wu ,&nbsp;Chung-Kwei Lin","doi":"10.1016/j.cpart.2007.03.007","DOIUrl":"https://doi.org/10.1016/j.cpart.2007.03.007","url":null,"abstract":"<div><p>Gold nanoparticles decorating the surface of multiwalled carbon nanotubes (MWCNTs) are prepared by photochemical reduction. The gold clusters form different interesting geometrical faceted shapes in accordance to time duration of synchrotron X-ray irradiation. The shape of nanogold could be spherical, rod-like, or triangular. Carbon nanotubes serve as optimal templates for the heterogeneous nucleation of gold nanocrystals. These nanocrystal structures are characterized by transmission electron microscope (TEM) and element analysis by energy dispersive spectroscopy (EDS).</p></div>","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"5 3","pages":"Pages 237-241"},"PeriodicalIF":0.0,"publicationDate":"2007-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cpart.2007.03.007","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91763380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Atomic resolution in noncontact AFM by probing cantilever frequency shifts 探测悬臂频移在非接触式原子力显微镜中的原子分辨率
China Particuology Pub Date : 2007-06-01 DOI: 10.1016/J.CPART.2006.09.001
H. Xie
{"title":"Atomic resolution in noncontact AFM by probing cantilever frequency shifts","authors":"H. Xie","doi":"10.1016/J.CPART.2006.09.001","DOIUrl":"https://doi.org/10.1016/J.CPART.2006.09.001","url":null,"abstract":"","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"11 1","pages":"242-246"},"PeriodicalIF":0.0,"publicationDate":"2007-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88683352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Improved algorithm of light scattering by a coated sphere 涂层球光散射的改进算法
China Particuology Pub Date : 2007-06-01 DOI: 10.1016/J.CPART.2007.03.003
Lei Liu, Huarui Wang, B. Yu, Yamin Xu, Jianqi Shen
{"title":"Improved algorithm of light scattering by a coated sphere","authors":"Lei Liu, Huarui Wang, B. Yu, Yamin Xu, Jianqi Shen","doi":"10.1016/J.CPART.2007.03.003","DOIUrl":"https://doi.org/10.1016/J.CPART.2007.03.003","url":null,"abstract":"","PeriodicalId":100239,"journal":{"name":"China Particuology","volume":"35 1","pages":"230-236"},"PeriodicalIF":0.0,"publicationDate":"2007-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89388451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 25
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