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Bulletin of the Hunt Institute for Botanical Documentation. Hunt Institute for Botanical Documentation最新文献

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Prologue 序言
Bulletin of the Hunt Institute for Botanical Documentation. Hunt Institute for Botanical Documentation Pub Date : 2017-04-15 DOI: 10.2307/j.ctv224v08p.2
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引用次数: 0
Acknowledgments 致谢。
Bulletin of the Hunt Institute for Botanical Documentation. Hunt Institute for Botanical Documentation Pub Date : 2017-04-15 DOI: 10.2307/j.ctv224v08p.57
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引用次数: 0
4 4
Bulletin of the Hunt Institute for Botanical Documentation. Hunt Institute for Botanical Documentation Pub Date : 2017-04-15 DOI: 10.2307/j.ctv224v08p.6
Filipe Correia
{"title":"4","authors":"Filipe Correia","doi":"10.2307/j.ctv224v08p.6","DOIUrl":"https://doi.org/10.2307/j.ctv224v08p.6","url":null,"abstract":": We explored a new isonitrile, namely 4-( N -phthalimido)phenyl isonitrile, with extraordinary features. The novel isocyanide has a pharmacophore, the phthalimido (Pht) group, that possesses promising pharmaceutical activities. We found that the novel isonitrile is unexpectedly odorless as an extra bonus which makes its handling easy in organic synthesis to serve as a scaffold for building several new amide derivatives through multicomponent reactions, overcoming the stink of common aromatic isonitriles such as phenyl isonitrile, benzyl isonitrile, p -nitrophenyl isonitrile, and ethyl 4-isocyano benzoate. The novel isonitrile 9 serves as a source of N -protected isonitrile with a Pht group, where the Pht group can be easily removed via hydrazinolysis, affording the corresponding primary amine/alcohol scaffold which could be used as a precursor to synthesize Passerini products via acylation directly to afford Passerini adducts 14 and 15 without carrying out the traditional Passerini three-component reaction; this new isonitrile is considered as a novel convertible isocyanide analogue.","PeriodicalId":80808,"journal":{"name":"Bulletin of the Hunt Institute for Botanical Documentation. Hunt Institute for Botanical Documentation","volume":"28 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2017-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82865957","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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