Figshare最新文献

筛选
英文 中文
Charged andnDischarged States of Cathode/Sulfide ElectrolytenInterfaces in All-Solid-State Lithium Ion Batteries 全固态锂离子电池中阴极/硫化物电解质界面的充电和放电状态
Figshare Pub Date : 2016-06-27 DOI: 10.1021/acs.jpcc.6b01207.s001
Masato Sumita (672347), Yoshinori Tanaka (259005), Minoru Ikeda (253194), Takahisa Ohno (1268106)
{"title":"Charged andnDischarged States of Cathode/Sulfide ElectrolytenInterfaces in All-Solid-State Lithium Ion Batteries","authors":"Masato Sumita (672347), Yoshinori Tanaka (259005), Minoru Ikeda (253194), Takahisa Ohno (1268106)","doi":"10.1021/acs.jpcc.6b01207.s001","DOIUrl":"https://doi.org/10.1021/acs.jpcc.6b01207.s001","url":null,"abstract":"Interfaces between cathodes and sulfidenelectrolytes exhibit highnresistance in all-solid-state lithium ion batteries. In this paper,nto elucidate the origin of the high interface resistance we have theoreticallyninvestigated the properties of the cathode interfaces with the sulfidenelectrolyte and oxide electrolyte for comparison. From the densitynfunctional molecular dynamics simulations of the LiFePO<sub>4</sub>/Li<sub>3</sub>PS<sub>4</sub> interface in both discharged and chargednstates, we have demonstrated the instability of the sulfide interfacenin the charged state, that is, the lithium depletion and oxidationnon the sulfide side near the interface, in contrast to the oxide interfaces.nThe obtained results imply the formation of a Li-depleted layer aroundnthe sulfide interfaces during charging and support the validity ofnthe insertion of oxide buffer layers at the interface to reduce theninterface resistance.","PeriodicalId":523782,"journal":{"name":"Figshare","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2016-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147921831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信
小红书