Figshare最新文献
筛选
英文
中文
Pd-Catalyzed Ring-Opening Polymerization of Cyclobutanolsnthrough C(sp<sup>3</sup>)–C(sp<sup>3</sup>) Bond Cleavage
通过C(sp<sup>3</sup>) -C （sp<sup>3</sup>）键裂解催化环丁醇开环聚合
Sergio Parra-García (17735760), Isabel Saura-Llamas (1716469), Delia Bautista (1573645), Juan Gil-Rubio (1573639), José-Antonio García-López (1317633)
{"title":"Pd-Catalyzed Ring-Opening Polymerization of Cyclobutanolsnthrough C(sp<sup>3</sup>)–C(sp<sup>3</sup>) Bond Cleavage","authors":"Sergio Parra-García (17735760), Isabel Saura-Llamas (1716469), Delia Bautista (1573645), Juan Gil-Rubio (1573639), José-Antonio García-López (1317633)","doi":"10.1021/acs.macromol.4c01089.s001","DOIUrl":"https://doi.org/10.1021/acs.macromol.4c01089.s001","url":null,"abstract":"A new approach tonring-opening polymerization (ROP) based on C(sp<sup>3</sup>)–C(sp<sup>3</sup>) bond cleavage is reported. Thisnprocess is based on the ability of Pd to promote both the β-carbonnelimination of a bifunctional cyclobutanol precursor and the C–Cncoupling process with the resulting Pd-alkyl intermediate. Consequently,nnovel polyketone materials are obtained. Owing to the modular synthesisnof the used cyclobutanol monomers, the present ROP reaction allowsnthe introduction of substitution patterns in the polymeric chain thatnare not accessible by current polyketone synthesis methodologies.nWe have explored in detail the initiation, propagation, and terminationnsteps of this new polymerization process.","PeriodicalId":522887,"journal":{"name":"Figshare","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147905527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
影响因子
展开
类型
展开
期刊
展开
全部
Acc. Chem. Res.
ACS Applied Bio Materials
ACS Appl. Electron. Mater.
ACS Appl. Energy Mater.
ACS Appl. Mater. Interfaces
ACS Appl. Nano Mater.
ACS Appl. Polym. Mater.
ACS BIOMATER-SCI ENG
ACS Catal.
ACS Cent. Sci.
ACS Chem. Biol.
ACS Chemical Health & Safety
ACS Chem. Neurosci.
ACS Comb. Sci.
ACS Earth Space Chem.
ACS Energy Lett.
ACS Infect. Dis.
ACS Macro Lett.
ACS Mater. Lett.
ACS Med. Chem. Lett.
ACS Nano
ACS Omega
ACS Photonics
ACS Sens.
ACS Sustainable Chem. Eng.
ACS Synth. Biol.
Anal. Chem.
BIOCHEMISTRY-US
Bioconjugate Chem.
BIOMACROMOLECULES
Chem. Res. Toxicol.
Chem. Rev.
Chem. Mater.
CRYST GROWTH DES
ENERG FUEL
Environ. Sci. Technol.
Environ. Sci. Technol. Lett.
Eur. J. Inorg. Chem.
IND ENG CHEM RES
Inorg. Chem.
J. Agric. Food. Chem.
J. Chem. Eng. Data
J. Chem. Educ.
J. Chem. Inf. Model.
J. Chem. Theory Comput.
J. Med. Chem.
J. Nat. Prod.
J PROTEOME RES
J. Am. Chem. Soc.
LANGMUIR
MACROMOLECULES
Mol. Pharmaceutics
Nano Lett.
Org. Lett.
ORG PROCESS RES DEV
ORGANOMETALLICS
J. Org. Chem.
J. Phys. Chem.
J. Phys. Chem. A
J. Phys. Chem. B
J. Phys. Chem. C
J. Phys. Chem. Lett.
Analyst
Anal. Methods
Biomater. Sci.
Catal. Sci. Technol.
Chem. Commun.
Chem. Soc. Rev.
CHEM EDUC RES PRACT
CRYSTENGCOMM
Dalton Trans.
Energy Environ. Sci.
ENVIRON SCI-NANO
ENVIRON SCI-PROC IMP
ENVIRON SCI-WAT RES
Faraday Discuss.
Food Funct.
Green Chem.
Inorg. Chem. Front.
Integr. Biol.
J. Anal. At. Spectrom.
J. Mater. Chem. A
J. Mater. Chem. B
J. Mater. Chem. C
Lab Chip
Mater. Chem. Front.
Mater. Horiz.
MEDCHEMCOMM
Metallomics
Mol. Biosyst.
Mol. Syst. Des. Eng.
Nanoscale
Nanoscale Horiz.
Nat. Prod. Rep.
New J. Chem.
Org. Biomol. Chem.
Org. Chem. Front.
PHOTOCH PHOTOBIO SCI
PCCP
Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX
EndNote
RefMan
NoteFirst
NoteExpress
求助内容：
应助结果提醒方式：请完成安全验证×
京公网安备 11010802042870号
