发布求助
文献互助 智能选刊 最新文献

Figshare最新文献

筛选
英文 中文
Photoredox-MediatednRemote C(sp<sup>3</sup>)–HnHeteroarylation of <i>N</i>‑Alkyl Sulfonamides 光氧化还原介导的nRemote C(sp&lt;sup&gt;3&lt;/sup&gt;) -H n杂化&lt； N&lt;/i&gt； -烷基磺酰胺
Figshare Pub Date : 2019-12-05 DOI: 10.1021/acs.joc.9b02502.s002
Zhiqiang Deng (532593), Guo-Xing Li (1688056), Gang He (239353), Gong Chen (198359)
{"title":"Photoredox-MediatednRemote C(sp&lt;sup&gt;3&lt;/sup&gt;)–HnHeteroarylation of &lt;i&gt;N&lt;/i&gt;‑Alkyl Sulfonamides","authors":"Zhiqiang Deng (532593), Guo-Xing Li (1688056), Gang He (239353), Gong Chen (198359)","doi":"10.1021/acs.joc.9b02502.s002","DOIUrl":"https://doi.org/10.1021/acs.joc.9b02502.s002","url":null,"abstract":"A Minisci-type δ-selective C­(sp&lt;sup&gt;3&lt;/sup&gt;)–Hnheteroarylationnof sulfonyl-protected primary aliphatic amines with &lt;i&gt;N&lt;/i&gt;-heteroarenes under photoredox-catalyzed conditions was developed.nThe reaction typically uses a slight excess of amine reactant. Thenuse of benziodoxole acetate (BI-OAc) oxidant and hexafluoroisopropanolnsolvent is critical to achieve high yield. Besides methylene C–Hnbonds, heteroarylation reactions of δ methyl C–H bondsnalso worked under more forced conditions. The reactions show a broadnscope for both amine and &lt;i&gt;N&lt;/i&gt;-heteroarene substrates,noffering a straightforward method for synthesis of complex δ-heteroarylalkylminesnfrom simple precursors.","PeriodicalId":522075,"journal":{"name":"Figshare","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147891081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们：info@booksci.cn Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号：604180095
Book学术官方微信
小红书