Journal of innovative science and engineering最新文献

筛选
英文 中文
N-Boc-Amino Acid Mediated Morita-Baylis Hillman reaction of methylphenyl glyoxylate n - boc氨基酸介导的甲基苯乙酯Morita-Baylis Hillman反应
Journal of innovative science and engineering Pub Date : 2023-10-16 DOI: 10.38088/jise.1333127
Gamze KOZ, Nejdet COŞKUN
{"title":"N-Boc-Amino Acid Mediated Morita-Baylis Hillman reaction of methylphenyl glyoxylate","authors":"Gamze KOZ, Nejdet COŞKUN","doi":"10.38088/jise.1333127","DOIUrl":"https://doi.org/10.38088/jise.1333127","url":null,"abstract":"The organocatalyzed Morita-Baylis Hillman (MBH) reaction of α-keto esters is a challenging carbon-carbon bond-forming reaction. We developed a catalytic system for the MBH reaction of methylphenyl glyoxylate with methyl vinyl ketone in a polar aprotic solvent. We used N-Boc-L-pipecolinic acid as a proton transfer mediator and 4-dimethylaminopyridine as the tertiary amine catalyst. We obtained the MBH adduct with a 66% yield in 48h. We proposed a detailed reaction mechanism involving a transition state that includes the hydrogen transfer by the acid functional group of N-Boc-L-pipecolinic acid.","PeriodicalId":499824,"journal":{"name":"Journal of innovative science and engineering","volume":"95 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136183295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Arbitrary Phase Optimization Through Adaptively-Scheduled Nanophotonic Inverse Design 基于自适应调度纳米光子逆设计的任意相位优化
Journal of innovative science and engineering Pub Date : 2023-10-05 DOI: 10.38088/jise.1346005
Emir Salih MAĞDEN
{"title":"Arbitrary Phase Optimization Through Adaptively-Scheduled Nanophotonic Inverse Design","authors":"Emir Salih MAĞDEN","doi":"10.38088/jise.1346005","DOIUrl":"https://doi.org/10.38088/jise.1346005","url":null,"abstract":"Design of integrated photonic devices continues to drive innovation in electro-optical systems for many applications ranging from communications to sensing and computing. Traditional design methods for integrated photonics involve using fundamental physical principles of guided-wave behavior to engineer optical functionalities for specific application requirements. While these traditional approaches may be sufficient for basic functionalities, the set of physically realizable optical capabilities these methods remains limited. Instead, photonic design can be formulated as an inverse problem where the target device functionality is specified, and a numerical optimizer creates the device with appropriate geometrical features within specified constraints. However, even with inverse design methods, achieving arbitrarily-specified phase offsets on-chip remains an important problem to solve for the reliability of interferometry-based nanophotonic applications. In order to address difficulties in achieving simultaneous phase and power optimization in inverse nanophotonic design, in this paper, we develop a set of optimization approaches that can enable user-specified phase differences in single-wavelength and multi-wavelength nanophotonic devices. By specifying phase offset targets for each output, we prevent convergence failures resulting from the changes in the figure of merit and gradient throughout the iterative optimization process. Additionally, by introducing phase-dependent figure of merit terms through an adaptive scheduling approach during the optimization, we accelerate device convergence up to a factor of 4.4 times. Our results outline a clear path towards the optimization of nanophotonic components with arbitrary phase-handling capabilities, with potential applications in a wide variety of integrated photonic systems and platforms.","PeriodicalId":499824,"journal":{"name":"Journal of innovative science and engineering","volume":"31 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135546232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Simultaneous Numerical Integration Routine for the Fast Calculation of Similar Integrations 用于快速计算相似积分的同时数值积分程序
Journal of innovative science and engineering Pub Date : 2023-08-21 DOI: 10.38088/jise.1246719
Aytaç ALPARSLAN
{"title":"A Simultaneous Numerical Integration Routine for the Fast Calculation of Similar Integrations","authors":"Aytaç ALPARSLAN","doi":"10.38088/jise.1246719","DOIUrl":"https://doi.org/10.38088/jise.1246719","url":null,"abstract":"In this paper, a fast and simultaneous integration routine that is tailored for obtaining the results of multiple numerical integrations is introduced. The routine uses the same nodes for multiple integrations defined for similar integrands. In the paper it is demonstrated by several examples that if the integrands of interest are similar on the integration path, then using the same nodes decreases the computational costs dramatically. The method is introduced by updating the popular Gauss-Kronrod quadrature rule, but the same steps given in the paper can be applied to any other numerical integration rule.","PeriodicalId":499824,"journal":{"name":"Journal of innovative science and engineering","volume":"51 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135877383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Laboratory Study on the Design and Performance Evaluation of Pitot-Tube 皮托管设计与性能评价的实验室研究
Journal of innovative science and engineering Pub Date : 2023-08-17 DOI: 10.38088/jise.1233700
Yasemin ESKİ, Babak VAHEDDOOST, Damla YILMAZ
{"title":"A Laboratory Study on the Design and Performance Evaluation of Pitot-Tube","authors":"Yasemin ESKİ, Babak VAHEDDOOST, Damla YILMAZ","doi":"10.38088/jise.1233700","DOIUrl":"https://doi.org/10.38088/jise.1233700","url":null,"abstract":"Due to the increasing demand for water resources worldwide, this commodity and its spatial and temporal properties are of the interest of decision makers and scientists. In this respect, the accuracy in detecting the physical characteristics of the water movement such as velocity and its associated phenomena should be preauthorized in hydraulic studies. Although velocity, as the deriving factor of the water flow, can be determined with the help of theoretical or practical approaches, researchers continuously pushes the limits of science by improving the existing methods to the best. The pitot tube, which is not widely used in open channel hydraulic practices, is one of these methods. In this study, we have addressed a case from design to conducting a set of laboratory experiments. A 3D-printed pitot-tube is designed and used in a set of experiments carried out in an open channel, with different flow rates (three experiments). As a result, the relative error rates were interpreted by comparing the velocity rates obtained with the help of the water level difference in the differential manometer (Vm) and the velocity rates obtained from the flow continuity equation in the open channel (Vo). Results indicated a 50% bias in the experiments, while scatter analysis showed that the associated deviations matches a linear equation.","PeriodicalId":499824,"journal":{"name":"Journal of innovative science and engineering","volume":"7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136337640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信