{"title":"Visible Light Assisted Photocatalytic Degradation of Chromium (VI) by Using Nanoporous Fe2O3","authors":"Abhilash Mavinakere Ramesh, S. Shivanna","doi":"10.1155/2018/1593947","DOIUrl":"https://doi.org/10.1155/2018/1593947","url":null,"abstract":"A Fe2O3 nanoporous structure was prepared by using hydrothermal route; its physicochemical properties were effectively characterized using XRF, BET, FT-IR, VSM, SEM and EDX, DLS, XRD, and PL techniques. The surface area of the magnetic nanoporous structure Fe2O3 was higher than the normally synthesized Fe2O3 nanoparticle. The outcome of the photocatalytic removal of the chromium (VI) below the visible light irradiation confirmed that 82.11% of Cr(VI) was degraded by the Fe2O3 nanomaterials at 120 min of irradiation time. The improved photocatalytic activity of the nanoparticle was ascribed to efficient electron-hole separation. Fe2O3 was set up to be a tough and constant photocatalyst throughout recycling experiments. The conceivable mechanism for the electron-hole separation process on the heterojunction was probable. The synthesized samples own low band gap energy and a hollow structure appropriate for the improved photocatalytic activity. The toxicity of the samples was measured by using Mus musculus skin melanoma cells (B16-F10 (ATCC®, CRL-6475TM) which are set up to be safe for human cells; as a result, this systematic approach provides a better alternative upconversion material for integral photoabsorption.","PeriodicalId":16158,"journal":{"name":"Journal of Materials","volume":"30 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80477930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Advances in Tendon and Ligament Tissue Engineering: Materials Perspective","authors":"F. Alshomer, Camilo Chaves, D. Kalaskar","doi":"10.1155/2018/9868151","DOIUrl":"https://doi.org/10.1155/2018/9868151","url":null,"abstract":"Introduction. Tendons are specialised, heterogeneous connective tissues, which represent a significant healthcare challenge after injury. Primary surgical repair is the gold standard modality of care; however, it is highly dependent on the extent of injuries. Tissue engineering represents an alternative solution for good tissue integration and regeneration. In this review, we look at the advanced biomaterial composites employed to improve cellular growth while providing appropriate mechanical properties for tendon and ligament repair. Methodology. Comprehensive literature searches focused on advanced composite biomaterials for tendon and ligament tissue engineering. Studies were categorised depending on the application. Results. In the literature, a range of natural and/or synthetic materials have been combined to produce composite scaffolds tendon and ligament tissue engineering. In vitro and in vivo assessment demonstrate promising cellular integration with sufficient mechanical strength. The biological properties were improved with the addition of growth factors within the composite materials. Most in vivo studies were completed in small-scale animal models. Conclusions. Advanced composite materials represent a promising solution to the challenges associated with tendon and ligament tissue engineering. Nevertheless, these approaches still demonstrate limitations, including the necessity of larger-scale animal models to ease future clinical translation and comprehensive assessment of tissue response after implantation.","PeriodicalId":16158,"journal":{"name":"Journal of Materials","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79581851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. Saitoh, Kohei Kuramitsu, Tomohiro Sato, M. Takuma, Y. Takahashi
{"title":"Molecular Dynamics Study on Deformation Mechanism of Grain Boundaries in Magnesium Crystal: Based on Coincidence Site Lattice Theory","authors":"K. Saitoh, Kohei Kuramitsu, Tomohiro Sato, M. Takuma, Y. Takahashi","doi":"10.1155/2018/4153464","DOIUrl":"https://doi.org/10.1155/2018/4153464","url":null,"abstract":"As for magnesium (Mg) alloys, it has been noted that they are inferior to plastic deformation, but improvement in the mechanical properties by further refinement of grain size has been recently suggested. It means the importance of atomistic view of polycrystalline interface of Mg crystal. In this study, to discuss the deformation mechanism of polycrystalline Mg, atomistic grain boundary (GB) models by using coincidence site lattice (CSL) theory are constructed and are simulated for their relaxed and deformatted structures. First, GB structures in which the axis of rotation is in [11¯00] direction are relaxed at 10 Kelvin, and the GB energies are evaluated. Then, the deformation mechanism of each GB model under uniaxial tensile loading is observed by using the molecular dynamics (MD) method. The present MD simulations are based on embedded atom method (EAM) potential for Mg crystal. As a result, we were able to observe atomistically a variety of GB structures and to recognize significant difference in deformation mechanism between low-angle GBs and high-angle GBs. A close scrutiny is made on phenomena of dislocation emission processes peculiar to each atomistic local structure in high-angle GBs.","PeriodicalId":16158,"journal":{"name":"Journal of Materials","volume":"10 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84609516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Reexamination of Solvothermal Synthesis of Layered Carbon Nitride","authors":"Y. Kojima, H. Ohfuji","doi":"10.1155/2018/6576457","DOIUrl":"https://doi.org/10.1155/2018/6576457","url":null,"abstract":"“Graphitic carbon nitride” synthesized by the solvothermal reaction between cyanuric chloride (C3N3Cl3) and sodium amide (NaNH2), which was one of the most common methods reported so far, was carefully examined by several analytical techniques for its chemical and structural characteristics. The chemical quantification by the electron microprobe and combustion methods showed that the product synthesized has a significant amount of hydrogen with a composition C3N5H3. Moreover, we found by FT-IR and IR-Raman measurements that the product consists mainly of stacked s-triazine units on the basis of the structural framework of cyanuric chloride, suggesting that s-triazine-based carbon nitride is more stable than heptazine-based one under a mild temperature condition (~200°C). The present study clearly demonstrates that hydrogen-free, pure graphitic C3N4 cannot be produced by the present solvothermal reaction proposed by the earlier study.","PeriodicalId":16158,"journal":{"name":"Journal of Materials","volume":"9 7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90251830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ahmed Al-Obeidi, Chenhao Ge, Kristina S Orosz, S Scott Saavedra
{"title":"ITO/poly(aniline)/sol-gel glass: An optically transparent, pH-responsive substrate for supported lipid bilayers.","authors":"Ahmed Al-Obeidi, Chenhao Ge, Kristina S Orosz, S Scott Saavedra","doi":"10.1155/2013/676920","DOIUrl":"10.1155/2013/676920","url":null,"abstract":"<p><p>Described here is fabrication of a pH-sensitive, optically transparent transducer composed of a planar indium-tin oxide (ITO) electrode overcoated with a a poly(aniline) (PANI) thin film and a porous sol-gel layer. Adsorption of the PANI film renders the ITO electrode sensitive to pH, whereas the sol-gel spin-coated layer makes the upper surface compatible with fusion of phospholipid vesicles to form a planar supported lipid bilayer (PSLB). The response to changes in the pH of the buffer contacting the sol-gel/PANI/ITO electrode is pseudo-Nernstian with a slope of 52 mV/pH over a pH range of 4-9. Vesicle fusion forms a laterally continuous PSLB on the upper sol-gel surface that is fluid with a lateral lipid diffusion coefficient of 2.2 μm<sup>2</sup>/s measured by fluorescence recovery after photobleaching. Due to its lateral continuity and lack of defects, the PSLB blocks the pH response of the underlying electrode to changes in the pH of the overlying buffer. This architecture is simpler to fabricate than previously reported ITO electrodes derivatized for PSLB formation, and should be useful for optical monitoring of proton transport across supported membranes derivatized with ionophores and ion channels.</p>","PeriodicalId":16158,"journal":{"name":"Journal of Materials","volume":"2013 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2013/676920","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"32759338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}