Yian Zhao , Runhua Guo , Chunkai Sheng , Long Wen , Gang Chen , Jianyu Zong
{"title":"Evaluation of high-proportion RAP mixtures modified with diatomite-rock asphalt composite through gray correlational analysis: Insights into pavement performance","authors":"Yian Zhao , Runhua Guo , Chunkai Sheng , Long Wen , Gang Chen , Jianyu Zong","doi":"10.1016/j.jclepro.2025.146185","DOIUrl":"10.1016/j.jclepro.2025.146185","url":null,"abstract":"<div><div>The application of RAP is favored by researchers for lower carbon emissions. However the poly modifiers and rejuvenators produce risks to the environment and limit high-proportion RAP application, therefore, this study investigates the natural mineral, Qingchuan rock asphalt (QRA) and Shengzhou diatomite (SD), to improve high-RAP-proportion mixtures performance. Firstly, microscopic tests were conducted to elucidate the modification mechanism via DSC, SEM and FTIR. Then, binders conventional properties were performed and mixtures road performance tests were conducted. Finally, Gray Correlation Analysis (GCA) combined with Entropy Weight Method (EWM) was employed to reveal the optimal dosage and correlation degree between modifiers and performance of high-RAP-proportion mixtures. The results demonstrated that the modified binders incorporating SD and QRA exhibited improved thermal and structural stability. SD could significantly improve the low-temperature performance, but QRA acted as a brake in a certain range. However, SD, QRA and RAP substantially improve the high-temperature performance, which enhance the dynamic stability nearly nearly sixfold. Conversely, SD reduces BPN by about 10 %, while QRA can enhance it by up to 20 %. Meanwhile, moisture stability reduced a lot by the large contents of RAP, but SD and QRA significantly improved it and SD played a crucial role in the anti-freeze-thaw performance. The best performing combination was D10Q10, while the worst was D10Q5, which manifested the QRA-SD-RAP synergistically improving the road performance. The coupling effect of natural mineral QRA and SD provides a comprehensive performance enhancement and strategy for solving high-proportion RAP applications.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"522 ","pages":"Article 146185"},"PeriodicalIF":10.0,"publicationDate":"2025-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144763854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nachiket Aashish Gokhale , Saurabh Nitin Joglekar , Siddhartha Panda
{"title":"Life cycle assessment of enzymatic and non-enzymatic electrochemical sensors: A comparative study using glucose oxidase and metal nano-catalysts","authors":"Nachiket Aashish Gokhale , Saurabh Nitin Joglekar , Siddhartha Panda","doi":"10.1016/j.jclepro.2025.146327","DOIUrl":"10.1016/j.jclepro.2025.146327","url":null,"abstract":"<div><div>This study investigates the environmental impacts of enzymatic and non-enzymatic recognition elements for electrochemical detection of readily oxidizable biomarkers, using glucose oxidase and metal nano-catalysts based glucose sensors as a model system. A comprehensive Life Cycle Assessment (LCA), encompassing raw material extraction to end-of-life disposal, was performed. Non-enzymatic sensors demonstrated significantly lower environmental impacts, exhibiting, for example, 15 times lower global warming potential (GWP) than enzymatic sensors, primarily due to the reusability. Even if the reusability of non-enzymatic sensors is not considered, the GWP of enzymatic sensors remains 66 % higher. The storage and use of the enzyme contributed substantially (10–50 %) to the environmental impacts across most midpoint indicators. The analysis revealed that enzymatic sensors require at least 16 cycles of reusability to achieve comparable environmental performance to non-enzymatic sensors. This study provides a valuable framework for future research comparing the environmental profiles of enzymatic and non-enzymatic sensing technologies for other analytes.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"522 ","pages":"Article 146327"},"PeriodicalIF":10.0,"publicationDate":"2025-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144763868","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of advanced cyclo-branched alkanes for jet fuel from biomass-derived platform compounds","authors":"Wuyu Wang , Jiapeng Zhang , Xuelai Zhao , Zhenjing Jiang , Lungang Chen , Qi Zhang , Xinghua Zhang , Longlong Ma","doi":"10.1016/j.jclepro.2025.146319","DOIUrl":"10.1016/j.jclepro.2025.146319","url":null,"abstract":"<div><div>Bio-derived jet fuel offers significant potential to reduce carbon emissions in the aviation sector. This study utilizes lignocellulosic biomass derivatives—cyclopentanone, butyraldehyde, and 2-methyl furan—as feedstocks to synthesize high-density, low-freezing-point cyclo-branched alkanes suitable for jet fuel. The process involves three key stages: aldol condensation, alkylation, and hydrodeoxygenation, facilitated by NaOH (1 wt%), Amberlyst-15, and Pd/C catalysts, achieving respective yields of 74.90 %, 87.65 %, and 88.79 %. The resulting bio-jet fuel exhibits a density of 0.88 g mL<sup>−1</sup> and a freezing point of −68.3 °C, outperforming the properties of commercially available Jet-A fuel. Furthermore, the process achieves a biomass-to-fuel conversion efficiency of 16.7 %, demonstrating a sustainable and scalable approach for advancing renewable jet-fuel.</div></div>","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"522 ","pages":"Article 146319"},"PeriodicalIF":10.0,"publicationDate":"2025-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144763920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Robert J. Fletcher Jr., Rhys E. Green, Eleanor K. Bladon, Philip W. Atkinson, Benjamin T. Phalan, David Williams, Piero Visconti, Andrew Balmford
{"title":"Beyond Species Richness for Biological Conservation","authors":"Robert J. Fletcher Jr., Rhys E. Green, Eleanor K. Bladon, Philip W. Atkinson, Benjamin T. Phalan, David Williams, Piero Visconti, Andrew Balmford","doi":"10.1111/conl.13124","DOIUrl":"https://doi.org/10.1111/conl.13124","url":null,"abstract":"<p>Recent global policy developments have highlighted the need for straightforward, robust, and meaningful biodiversity metrics. However, much of conservation science is dominated by the use of a single metric, species richness, despite several known limitations. Here, we review and synthesize why species richness (i.e., the number of species in a local area) is a poor metric for a variety of topical- and policy-relevant conservation problems. We identify the following three key issues: (1) increasing evidence emphasizes that species richness is often not a robust metric for identifying biodiversity change, (2) species richness ignores species identity and so may often not reflect impacts on species of concern, and (3) species richness does not provide information needed on the persistence of biodiversity or the provision of ecosystem services. We highlight the unappreciated practical outcomes of these limitations with examples from three ongoing conservation debates: whether local biodiversity is declining, how habitat fragmentation affects biodiversity, and the extent to which land sharing or sparing is more beneficial for biodiversity conservation. To address these limitations, we offer a set of guidelines for the use of biodiversity metrics in conservation policy and practice.</p>","PeriodicalId":157,"journal":{"name":"Conservation Letters","volume":"18 4","pages":""},"PeriodicalIF":7.7,"publicationDate":"2025-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/conl.13124","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144764120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"What Do We Know About the Environmental Status of European Seas?","authors":"Athanasios Nikolaou, Angel Borja, Stelios Katsanevakis","doi":"10.1111/conl.13118","DOIUrl":"https://doi.org/10.1111/conl.13118","url":null,"abstract":"<p>The European Union (EU) established the Marine Strategy Framework Directive (MSFD) to achieve good environmental status (GES) in European seas through an ecosystem-based approach to management. EU Member States implementing the MSFD must assess the environmental status of their marine waters, as well as the human pressures and impacts affecting them. The MSFD follows a 6-year cycle, with assessments made based on 11 descriptors linked to specific pressure, state and impact-related criteria. Member States assessments should determine the extent to which GES is achieved. However, for coherent management of EU seas, comparable assessments across Member States and EU-wide overview of the status and MSFD progress are essential. This study developed pressure, state, and impact indices, by integrating available MSFD data reported by EU Member States. For the first time, MSFD data across all descriptors have been integrated to produce a European regional assessment. Findings indicate that most European regions are far from demonstrating GES, suffering from intense pressures and impacts. Significant knowledge gaps were identified, particularly in the eastern Mediterranean. The findings highlight the urgent need for enhanced ecological monitoring and setting environmental targets to improve the dire state of European seas, advocating for stronger regional cooperation and standardized methodologies.</p>","PeriodicalId":157,"journal":{"name":"Conservation Letters","volume":"18 4","pages":""},"PeriodicalIF":7.7,"publicationDate":"2025-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/conl.13118","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144764121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Economic, ecological and social perspectives of industrial hemp cultivation in Germany: A qualitative analysis.","authors":"Marius Michels, Adrian Brinkmann, Oliver Mußhoff","doi":"10.1016/j.jenvman.2025.126117","DOIUrl":"10.1016/j.jenvman.2025.126117","url":null,"abstract":"<p><p>Hemp cultivation is experiencing a resurgence in Europe, with the European Commission identifying it as a strategic crop for achieving Green Deal objectives. This study investigates opportunities and challenges of hemp cultivation from German farmers' perspectives across all three sustainability pillars. We conducted qualitative interviews with 14 agricultural enterprises across northern Germany in 2024, analyzing data through deductive category formation. Economic findings reveal opportunities through diversified revenue streams and reduced input costs, though scale requirements and market uncertainties present challenges. Ecologically, farmers confirm hemp's benefits for soil health and reduced chemical inputs, while noting specific management requirements for water and soil conditions. Social acceptance is improving when hemp is effectively distinguished from the drug cannabis, though regulations and conservative attitudes remain barriers for adoption. Success in hemp cultivation requires establishing stable market structures, developing region-specific management practices, and implementing effective knowledge transfer programs. This study provides the first comprehensive analysis of European farmers' experiences with hemp cultivation and offers practical insights for policymakers, farmers, and industry stakeholders while connecting farmer perspectives with European Green Deal objectives.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"389 ","pages":"126117"},"PeriodicalIF":8.0,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144293087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Francisco José Castillo-Díaz, Luis J Belmonte-Ureña, Francisco Jesús Gálvez-Sánchez, Francisco Camacho-Ferre
{"title":"Sustainable technological innovations in agriculture: Financial challenges and investment priorities under the European Green Deal.","authors":"Francisco José Castillo-Díaz, Luis J Belmonte-Ureña, Francisco Jesús Gálvez-Sánchez, Francisco Camacho-Ferre","doi":"10.1016/j.jenvman.2025.126150","DOIUrl":"10.1016/j.jenvman.2025.126150","url":null,"abstract":"<p><p>This study explores the important financial challenges faced by Spanish agricultural and livestock companies to meet stringent environmental regulations without compromising their competitiveness. Using a Delphi method integrated with a systematic literature review, the research identifies key sustainable technological innovations (STIs) that require significant financial investment. Priority STIs include renewable energy sources, water use efficiency, by-product management, alternative fertilizers, and digital technologies, among others, each of which plays a key role in mitigating environmental impacts and aligning with overarching European sustainability frameworks, notably the European Green Deal and the 2030 Agenda for Sustainable Development. The findings support the formulation of specific policy recommendations aimed at overcoming the financial constraints that hinder the adoption of STIs. These include designing progressive financing schemes, launching green credit lines with subsidized interest rates, and increasing agri-environmental subsidies linked to STIs adoption. Furthermore, the study advocates the expansion of public-private investment frameworks and the establishment of technical advisory services to support producers in the selection, integration and implementation of appropriate technologies. These measures are essential to reduce economic barriers and accelerate the sector's technological transition to greater environmental and economic resilience.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"389 ","pages":"126150"},"PeriodicalIF":8.0,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144293137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The impact of green finance reform and innovation pilot zones on corporate pollution and carbon reduction: From the perspective of dual objective constraints.","authors":"Min Fan, Weixuan Liu, Di Yao","doi":"10.1016/j.jenvman.2025.126110","DOIUrl":"10.1016/j.jenvman.2025.126110","url":null,"abstract":"<p><p>This paper explores the impact of green finance reform and innovation pilot zones on corporate pollution and carbon reduction based on panel data of A-share listed enterprises from 2010 to 2022. The study finds that green finance reform and innovation pilot zones promote the synergistic effects of corporate pollution and carbon reduction, with mechanisms such as alleviating financing constraints, promoting environmental investment, and enhancing green technological innovation playing important roles. The effects are more pronounced for heavily polluting enterprises, high-tech enterprises, and enterprises cities in low-carbon pilot with environmental courts and eastern area. Under effective economic and environmental objective constraints, green finance reform and innovation pilot zones will provide greater \"acceleration\" for corporate pollution and carbon reduction. The study indicates that green financing serves as a viable strategy to enhance the combined impact of corporate efforts in reducing both pollution and carbon emissions. It also represents a practical approach to simultaneously achieving economic development and ecological environmental goals.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"389 ","pages":"126110"},"PeriodicalIF":8.0,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144293138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Auto-photocatalytic valorization of ZnS into ZnS/ZnO nanocomposite using O<sub>3</sub>/UV oxidation for photocatalytic dye degradation.","authors":"Jamshid Behin, Pegah Amiri, Sahar Ghabaee","doi":"10.1016/j.jenvman.2025.126166","DOIUrl":"10.1016/j.jenvman.2025.126166","url":null,"abstract":"<p><p>Cost-effective valorization of zinc sulfide (ZnS), by-product from desulfurization of zinc oxide (ZnO), poses a significant challenge due to energy requirement under high temperature and reaction time. This study introduces an innovative synthesis of ZnS/ZnO nanocomposites (NCs) from ZnS nanoparticles (NPs) for environmental remediation. Aqueous colloidal solution of ZnS NPs (10 g/L) was oxidized in an airlift photoreactor (5 L) at room-temperature using ozone (O<sub>3</sub>) and ozone/ultraviolet (O<sub>3</sub>/UV), respectively. The effects of pH (3-11), time (10-90 min), and oxidation modes were explored on oxygen content (OC) of NCs. The optimization results using RSM showed that higher pHs and longer reaction times led to increased OC of NCs up to 7.14 and 11.12 wt% in O<sub>3</sub> and O<sub>3</sub>/UV oxidation, respectively. Interaction of O<sub>3</sub>/UV and ZnS exerts a dual-effect involving O<sub>3</sub>-induced oxidation of ZnS, and promoted-photocatalytic role of ZnS precursor (auto-photocatalytic effect). This effect facilitates ZnS to ZnO conversion and enhances reaction kinetics across a broader pH range. Optical bandgap analysis revealed a decrease in the bandgap energy from 3.70 eV for ZnS NPs to 3.41 eV for ZnS/ZnO NCs synthesized under O<sub>3</sub>/UV (pH: 11 and time: 90 min). The proposed method was subsequently applied to spent ZnS NPs, yielding in ZnS/ZnO NCs with an OC of 9.32 wt%. The NCs synthesized from virgin and spent ZnS NPs were used for photocatalytic degradation of Congo red dye and the efficiencies of 91 and 98 % were achieved, respectively. Both NCs demonstrated reusable and environmentally friendly waste valorization, retaining 62-72 % efficiency after four recycling cycles. Cost-effectiveness of the suggested approach was also demonstrated in photocatalytic dye degradation.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"389 ","pages":"126166"},"PeriodicalIF":8.0,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144300903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Performance analysis of machine learning algorithms for the prediction of disinfection byproducts formation during chlorination: Effect of background water characteristics.","authors":"Gamze Ersan, Eda Goz, Tanju Karanfil","doi":"10.1016/j.jenvman.2025.126144","DOIUrl":"10.1016/j.jenvman.2025.126144","url":null,"abstract":"<p><p>This study investigated the comparison of the nonlinear machine learning algorithms and linear regression models to predict the formation of trihalomethanes (THM4), haloacetic acids (HAA5 and HAA9), and haloacetonitriles (HAN4 and HAN6) under uniform formation conditions in chlorinated waters. A wide range of water sources including wastewater effluent organic matters (EfOM), laboratory grown algal organic matters (AOM) samples from different algal species, and raw/treated/isolated natural organic matter (NOM) samples were selected to investigate background water effect on the model performance. Models for THM4, HAA5, HAA9, HAN4 and HAN6 formation were developed for all water sources combined (including NOM, AOM, and EfOM-impacted waters) and for NOM separately. The results showed that Least squares support vector machine (LS-SVM) delivered the best performance for both regulated THM (R<sup>2</sup><sub>train</sub>/R<sup>2</sup><sub>test</sub>: 0.92/0.80) and HAA5 (R<sup>2</sup><sub>train</sub>/R<sup>2</sup><sub>test</sub>: 0.91/0.72), while Kernel extreme learning machine (KELM) outperformed the other models for unregulated HAN4 (R<sup>2</sup><sub>train</sub>/R<sup>2</sup><sub>test</sub>: 0.89/0.70) and HAN6 (R<sup>2</sup><sub>train</sub>/R<sup>2</sup><sub>test</sub>: 0.91/0.41), across all water sources. For individual NOM waters, the Artificial neural network (ANN) model outperformed in predicting THMs (R<sup>2</sup><sub>train</sub>/R<sup>2</sup><sub>test</sub>: 0.97/0.94), HAA9 (R<sup>2</sup><sub>train</sub>/R<sup>2</sup><sub>test</sub>: 0.92/0.84), HAN4 (R<sup>2</sup><sub>train</sub>/R<sup>2</sup><sub>test</sub>: 0.98/0.96), and HAN6 (R<sup>2</sup><sub>train</sub>/R<sup>2</sup><sub>test</sub>: 0.98/0.89), emphasizing its ability to generalize across narrower, more specific datasets. This suggests that while LS-SVM and KELM models are more effective for both regulated and unregulated disinfection byproducts (DBPs) modeling as the variability in water source characteristics increases, the ANN model excels for more homogeneous DBP precursor types. These findings indicate the importance of selecting the appropriate modeling approach and the characteristics of the datasets for DBP modeling.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"389 ","pages":"126144"},"PeriodicalIF":8.0,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144300915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}