Surface Engineering and Applied Electrochemistry最新文献

筛选
英文 中文
Graphene Modified ZnO/Polyaniline Electrode Material for Electrochemical Sensing of Phenol Compounds 用于苯酚化合物电化学传感的石墨烯改性氧化锌/聚苯胺电极材料
IF 0.9
Surface Engineering and Applied Electrochemistry Pub Date : 2023-12-14 DOI: 10.3103/S1068375523060133
La Ode Agus Salim, Kurnia Sri Yunita, Irwan Irwan, Toshiyuki Nakai
{"title":"Graphene Modified ZnO/Polyaniline Electrode Material for Electrochemical Sensing of Phenol Compounds","authors":"La Ode Agus Salim,&nbsp;Kurnia Sri Yunita,&nbsp;Irwan Irwan,&nbsp;Toshiyuki Nakai","doi":"10.3103/S1068375523060133","DOIUrl":"10.3103/S1068375523060133","url":null,"abstract":"<p>This study was aimed at developing an electrochemical sensor for the detection of phenol, a harmful organic pollutant for both humans and the environment. The sensor was developed by investigating metal oxide and conductive polymer modifiers on graphene electrodes to enhance the sensitivity for the phenol detection. In this research, the production of an electrode is discussed that is very sensitive to phenolic compounds using a composite of zinc oxide and polyaniline modified graphene (Gr/ZnO@PANi). The Gr/ZnO nanocomposite synthesis was carried out using a simple hydrothermal method and modification of PANi on the electrode surface by the electropolymerization method. It was found that the Gr/ZnO@PANi composite electrode can detect phenol effectively, with an efficient electron transfer occurring at a low oxidation potential. Additionally, it was observed that the electrode sensitivity to the phenol concentration was remarkably linear within a range of 10<sup>–6</sup>–10<sup>–1</sup> M, and its limit of detection was as low as 0.0515 μM. Furthermore, the Gr/ZnO@PANi composite electrode exhibited excellent stability in detecting phenolic compounds, as indicated by the low stability coefficients of the relative standard deviation for reproducibility (0.37%) and the randomized strategic demand reduction (1.02%). Those findings suggest that the new Gr/ZnO@ PANi composite electrode is a promising tool for the sensitive detection of phenol in the environment, which could contribute to mitigating its negative impacts on human health and ecosystems. Future studies could explore the potential applications of this sensor for detecting other types of pollutants as well.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 6","pages":"764 - 771"},"PeriodicalIF":0.9,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138630893","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of the Volume of a Cylindrical Discharge Chamber with Rigid Walls on the Pressure Field in the Water Filling It 带刚性壁的圆柱形排放室容积对填充水中压力场的影响
IF 0.9
Surface Engineering and Applied Electrochemistry Pub Date : 2023-12-14 DOI: 10.3103/S1068375523060121
V. M. Kosenkov
{"title":"Influence of the Volume of a Cylindrical Discharge Chamber with Rigid Walls on the Pressure Field in the Water Filling It","authors":"V. M. Kosenkov","doi":"10.3103/S1068375523060121","DOIUrl":"10.3103/S1068375523060121","url":null,"abstract":"<p>The volume of the discharge chamber has a great influence on the pressure field in the water filling it and on the efficiency of many technological processes; therefore, the study of the relationship between the volume of the chamber and the pressure in it is an urgent task. However, at present, the role of the volume of the discharge chamber in the formation of the pressure field in it has been insufficiently studied. The purpose of this work is to fill the gap. The study was carried out on the basis of a previously developed mathematical model of an electric discharge in water, the adequacy of which was substantiated via a comparison of the simulation results with experimental data. It is determined that the closed volume of the discharge chamber with rigid walls significantly affects the formation of the pressure field in the water filling it. In this case, the interaction of waves reflected from the walls of the discharge chamber with the surface of the discharge channel in water and the vapor-gas cavity is of decisive importance. The reflected waves determine the period and amplitude of the pulsation of the discharge channel and the vapor-gas cavity, thereby influencing the electrical characteristics of the discharge. This influence increases with decreasing the chamber volume.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 6","pages":"742 - 753"},"PeriodicalIF":0.9,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138631031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kinetics and Mechanism of Methylene Blue Adsorption by a TiO2/Diatomite Nanocomposite and Its Components TiO2/Diatomite 纳米复合材料及其成分吸附亚甲基蓝的动力学和机理
IF 0.9
Surface Engineering and Applied Electrochemistry Pub Date : 2023-12-14 DOI: 10.3103/S1068375523060078
T. Ya. Datsko, V. I. Zelentsov
{"title":"Kinetics and Mechanism of Methylene Blue Adsorption by a TiO2/Diatomite Nanocomposite and Its Components","authors":"T. Ya. Datsko,&nbsp;V. I. Zelentsov","doi":"10.3103/S1068375523060078","DOIUrl":"10.3103/S1068375523060078","url":null,"abstract":"<p>A study was made of the kinetics of the adsorption of the methylene blue dye from an aqueous solution on the photocatalyst DDT (nanosized titanium dioxide in the anatase phase, deposited on diatomite) and its components: diatomite D and anatase TiO<sub>2</sub>. The effect of the initial concentration and pH of the methylene blue solution on the rate of the adsorption process was investigated. The kinetic data of adsorption were processed using two simplified kinetic models, one of the pseudo-first-order and the other of pseudo-second-order. To investigate the adsorption mechanism, a model of intraparticle diffusion kinetics was employed. The adsorption kinetics of methylene blue on the surfaces of D, TiO<sub>2</sub>, and DDT was found to be best described by the pseudo-second-order model. It was shown that the adsorption of methylene blue on the D and DDT adsorbents is a multistep process involving adsorption on the external surface and inside particles, with the limiting step being a chemical reaction. For the adsorption on TiO<sub>2</sub>, the limiting step is the external diffusion.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 6","pages":"772 - 779"},"PeriodicalIF":0.9,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138631030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electroactivation: An Advanced Method of Processing of Whey with Medium Protein Content 电激活:加工中等蛋白质含量乳清的先进方法
IF 0.9
Surface Engineering and Applied Electrochemistry Pub Date : 2023-12-14 DOI: 10.3103/S1068375523060145
I. V. Paladii, E. G. Vrabie, M. K. Bologa, V. G. Vrabie, T. G. Stepurina, A. A. Polikarpov, K. G. Sprinchan
{"title":"Electroactivation: An Advanced Method of Processing of Whey with Medium Protein Content","authors":"I. V. Paladii,&nbsp;E. G. Vrabie,&nbsp;M. K. Bologa,&nbsp;V. G. Vrabie,&nbsp;T. G. Stepurina,&nbsp;A. A. Polikarpov,&nbsp;K. G. Sprinchan","doi":"10.3103/S1068375523060145","DOIUrl":"10.3103/S1068375523060145","url":null,"abstract":"<p>The results of the studies of electroactivation, an emerging method of nonwaste processing of secondary dairy products, namely, whey with a medium protein content, in order to recover whey proteins into protein mineral concentrates, are presented. Processing was carried out in electrolyzers with different ratios of the volume of the processed whey to the surface of the electrode/cathode with different constructive and geometric parameters, which influences the specific energy consumption per unit volume. The main purpose was the maximum recovery of whey proteins into protein mineral concentrates at low energy costs, and the exclusion of “dead” or inefficient zones of diaphragm electrolyzers. The degree of the recovery of whey protein depending on the pH values, the redox potential, and the temperature during electroactivation was analyzed. This justifies the optimization of the technical parameters of electrolyzers for whey with a medium protein content.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 6","pages":"824 - 835"},"PeriodicalIF":0.9,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138631038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of L(+)-Lactic Acid upon Electroactivation of Serum 电活化血清制备 L(+)- 乳酸
IF 0.9
Surface Engineering and Applied Electrochemistry Pub Date : 2023-12-14 DOI: 10.3103/S1068375523060182
I. I. Vutkareva, G. K. Balan, M. K. Bologa
{"title":"Preparation of L(+)-Lactic Acid upon Electroactivation of Serum","authors":"I. I. Vutkareva,&nbsp;G. K. Balan,&nbsp;M. K. Bologa","doi":"10.3103/S1068375523060182","DOIUrl":"10.3103/S1068375523060182","url":null,"abstract":"<p>The results from investigations of obtaining the L(+) optical isomer of lactic acid from different types of whey are presented: of the initial, fermented, and concentrated in an electrolysis-type apparatus with a separating diaphragm. The rate of obtaining the L(+) isomer of lactic acid in the anode chamber of the electrolyzer was determined depending on the concentration of whey.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 6","pages":"836 - 840"},"PeriodicalIF":0.9,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138631607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing the Efficiency of Silicon Solar Cells through Nickel Doping 通过掺镍提高硅太阳能电池的效率
IF 0.9
Surface Engineering and Applied Electrochemistry Pub Date : 2023-12-14 DOI: 10.3103/S1068375523060108
Z. T. Kenzhaev, N. F. Zikrillaev, K. S. Ayupov, K. A. Ismailov, S. V. Koveshnikov, T. B. Ismailov
{"title":"Enhancing the Efficiency of Silicon Solar Cells through Nickel Doping","authors":"Z. T. Kenzhaev,&nbsp;N. F. Zikrillaev,&nbsp;K. S. Ayupov,&nbsp;K. A. Ismailov,&nbsp;S. V. Koveshnikov,&nbsp;T. B. Ismailov","doi":"10.3103/S1068375523060108","DOIUrl":"10.3103/S1068375523060108","url":null,"abstract":"<p>It was demonstrated that the concentration of nickel atoms near the surface of solar cells (SCs) is higher by 2–3 orders of magnitude in comparison with the bulk material, resulting in a significantly increased gettering rate in the former case. Experiments determined the optimal gettering conditions for nickel clusters (nickel diffusion temperature 800–850°C and additional thermal annealing temperature 750–800°C) and the structure of a silicon SC that enhances its efficiency by 25–30% in comparison with the reference structure. Physical mechanisms were identified for the effect of the diffusion of nickel impurity atoms and additional thermal annealing on the state of nickel atoms near the surface and the SC base and, consequently, on SC parameters. Physical models were developed for the structure of a cluster of nickel atoms in silicon and for the gettering process of fast-diffusing impurities by clusters of nickel atoms. The binding energy of fast-diffusing impurity atoms with a nickel cluster was estimated to be approximately 1.39 eV. Calculations showed that nickel doping can increase the minority carrier lifetime and the collection coefficient by factors of 2–4 and 1.4–2, respectively. Experiments demonstrated a twofold increase in minority carrier lifetime and a 25–30% improvement in the efficiency of SCs.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 6","pages":"858 - 866"},"PeriodicalIF":0.9,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138631604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Peculiarities of Transfer and Heat Losses of Electromagnetic Energy in the Two-Wire Overhead Line with Alternating Electric Conduction Current 交变传导电流双线架空线路中电磁能传输和热损耗的特殊性
IF 0.9
Surface Engineering and Applied Electrochemistry Pub Date : 2023-12-14 DOI: 10.3103/S1068375523060042
M. I. Baranov
{"title":"Peculiarities of Transfer and Heat Losses of Electromagnetic Energy in the Two-Wire Overhead Line with Alternating Electric Conduction Current","authors":"M. I. Baranov","doi":"10.3103/S1068375523060042","DOIUrl":"10.3103/S1068375523060042","url":null,"abstract":"<p>The results of the research related to the establishment of basic features of transfer and heat (Joule) losses of electromagnetic energy in a uniform two-wire overhead power line with the metal wires of finite sizes (<i>r</i><sub>0</sub> in radius and <i>l</i><sub>0</sub> ⪢ <i>r</i><sub>0</sub> in length) and alternating (pulse) electric conduction current <i>i</i><sub>0</sub>(<i>t</i>) of different amplitude and time parameters are presented. In view of the quantum-wave nature of the electric conduction current <i>i</i><sub>0</sub>(<i>t</i>), it was found that, in the metal wires of studied overhead lines, there appear the standing transverse electromagnetic waves (EMWs) that cannot transfer electromagnetic energy over a distance. It is demonstrated that, due to a weak dissipation of the quantized longitudinal electronic de Broglie half-waves on the crystal lattice sites of a metal (alloy) of the wires of the studied line, the heat losses of energy are released on those lattice sites. The features of the influence of the traveling transverse EMWs in the air environment of the studied lines on the process of transmission of electromagnetic energy in the overhead power lines over a distance are established.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 6","pages":"816 - 823"},"PeriodicalIF":0.9,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139022133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation and Modelling of Copper Electroforming Process for Surface Roughness Parameters Using Regression and Pareto ANOVA Analyses 利用回归分析和帕累托方差分析对铜电铸工艺的表面粗糙度参数进行研究和建模
IF 0.9
Surface Engineering and Applied Electrochemistry Pub Date : 2023-12-14 DOI: 10.3103/S1068375523060066
Amir Masoud Behagh,  Alireza Fadaei Tehrani
{"title":"Investigation and Modelling of Copper Electroforming Process for Surface Roughness Parameters Using Regression and Pareto ANOVA Analyses","authors":"Amir Masoud Behagh,&nbsp; Alireza Fadaei Tehrani","doi":"10.3103/S1068375523060066","DOIUrl":"10.3103/S1068375523060066","url":null,"abstract":"<p>The objective of this paper was to examine the effect of such deposited copper electroforming process control parameters as the applied voltage, the process time, the filler content, and the copper sulfate concentration on the surface roughness. For this purpose, an electroforming setup was made using a copper sulfate electroforming bath. A full factorial method was used to design the experiments with four control factors, each of them of two levels. After conducting each experiment, the prepared copper electroformed samples were characterized using a contact profilemeter and measuring certain surface roughness parameters, namely, the average roughness, the root mean square roughness, the average maximum height of the profile, and the autocorrelation length. Finally, the regression modelling was used to obtain a predictive model based on the measurements data. Also, the Pareto ANOVA analysis was performed for each surface roughness parameter to evaluate the contribution ratio of the control factors. The results demonstrated that a different control factor is dominant for each surface roughness parameter.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 6","pages":"780 - 790"},"PeriodicalIF":0.9,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138631256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On the Issue of Calculating the Magnitude of Induced Charges and the Electrostatic Dipole of an Oblate Spheroid with an Axis of Symmetry Collinear to the External Homogeneous Electrostatic Field 关于计算对称轴与外部均质静电场平行的扁球体的感应电荷量和静电偶极子的问题
IF 0.9
Surface Engineering and Applied Electrochemistry Pub Date : 2023-12-14 DOI: 10.3103/S106837552306011X
N. Yu. Kolbneva
{"title":"On the Issue of Calculating the Magnitude of Induced Charges and the Electrostatic Dipole of an Oblate Spheroid with an Axis of Symmetry Collinear to the External Homogeneous Electrostatic Field","authors":"N. Yu. Kolbneva","doi":"10.3103/S106837552306011X","DOIUrl":"10.3103/S106837552306011X","url":null,"abstract":"<p>The values of the surface induced charges, the positions of their centers, and the value of the equivalent dipole of an oblate conducting spheroid are determined by transition from spheroidal coordinates to a spherical system of coordinates in the analytical asymptotic calculations of the first order of smallness with respect to the squared eccentricity. The characteristics of the equivalent dipole are obtained depending on the value of the electrostatic field strength, squared eccentricity, and the radius of an equal sphere.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 6","pages":"734 - 741"},"PeriodicalIF":0.9,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138630892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Industrial Application of the Diamond Electrochemical Honing Method 金刚石电化学珩磨法的工业应用
IF 0.9
Surface Engineering and Applied Electrochemistry Pub Date : 2023-12-14 DOI: 10.3103/S1068375523060170
S. V. Usov, I. P. Tochilin, A. V. Zhdanov
{"title":"Industrial Application of the Diamond Electrochemical Honing Method","authors":"S. V. Usov,&nbsp;I. P. Tochilin,&nbsp;A. V. Zhdanov","doi":"10.3103/S1068375523060170","DOIUrl":"10.3103/S1068375523060170","url":null,"abstract":"<p>Changes in surface roughness, residual stresses, and other parameters are studied under various selected conditions of diamond-electrochemical honing (DEH) of parts made of the steels 30KhGSA, 30KhN2MFA, 35KhN2MFASh, 23KhGS2MFALU, and St.50A. The honing tool design is presented, and the question of the geometric characteristics of the cathodic section, insulating coating, and material of the guides of the honing tool is resolved. The results are obtained, demonstrating the effect of DEH on the reliability and durability indicators of parts manufactured by this method. The technical and economic efficiency of the created industrial DEH department is demonstrated.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 6","pages":"849 - 857"},"PeriodicalIF":0.9,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138631149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信