Current Opinion in Colloid & Interface Science最新文献_第7页

Biobased ordered porous materials in the nano-to microscales 纳米到微米级的生物有序多孔材料

IF 7.9 2区化学

Current Opinion in Colloid & Interface Science Pub Date : 2024-06-14 DOI: 10.1016/j.cocis.2024.101822

Yeedo Chun , Yeling Zhu , Cosima Stubenrauch , Yi Lu , Orlando J. Rojas

{"title":"Biobased ordered porous materials in the nano-to microscales","authors":"Yeedo Chun , Yeling Zhu , Cosima Stubenrauch , Yi Lu , Orlando J. Rojas","doi":"10.1016/j.cocis.2024.101822","DOIUrl":"10.1016/j.cocis.2024.101822","url":null,"abstract":"<div><p>Ordered porous materials (OPMs) are defined according to pore size, where ordered macropores (>50 nm) govern transport of fluids and mesopores (>2 nm, <50 nm) and micropores (<2 nm, IUPAC definitions) control molecular or ionic interactions. The growing importance of sustainable materials has incentivized the development of biobased OPMs (bioOPMs) with pore sizes ranging from 0.3 nm–9 nm and 1 μm–500 μm. Synthesizing bioOPMs typically involves aqueous solutions and suspensions which require a thorough understanding of biobased precursor-water interactions. Emerging approaches in templating based on liquid foams, breath-figure, and micelles are pivotal for achieving ordered assemblies, with solidity and consolidation occurring through water removal. This review describes recent advances in the design and utilization of bioOPMs, particularly those produced by water-based templating. It also highlights notable exceptions to water-based synthesis and identifies gaps in the science and technology of bioOPMs, offering perspectives on future developments in the field.</p></div>","PeriodicalId":293,"journal":{"name":"Current Opinion in Colloid & Interface Science","volume":"73 ","pages":"Article 101822"},"PeriodicalIF":7.9,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1359029424000402/pdfft?md5=e926c217fd19d043179bec79a892f2a6&pid=1-s2.0-S1359029424000402-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141401792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Foams based on biosurfactants solutions. Part I. Influence of biosurfactant origin on foaming properties 基于生物表面活性剂溶液的泡沫。第一部分：生物表面活性剂来源对发泡特性的影响

IF 7.9 2区化学

Current Opinion in Colloid & Interface Science Pub Date : 2024-06-12 DOI: 10.1016/j.cocis.2024.101821

Marcel Krzan , Anna Drabczyk , Sonia Kudłacik-Kramarczyk , Mateusz Jamroży

引用次数: 0

Equilibrium surface complexation modeling with metastable natural colloids: The key to predict the oxidation state distribution of trace elements? 利用可陨落的天然胶体建立平衡表面络合模型：预测微量元素氧化态分布的关键？

IF 7.9 2区化学

Current Opinion in Colloid & Interface Science Pub Date : 2024-06-08 DOI: 10.1016/j.cocis.2024.101820

Rémi Marsac , Charlotte Catrouillet , Mathieu Pédrot , Marc F. Benedetti , Aline Dia , Eric D. van Hullebusch , Mélanie Davranche , Yann Sivry , Anne-Catherine Pierson-Wickmann , Mickael Tharaud , Frank Heberling

{"title":"Equilibrium surface complexation modeling with metastable natural colloids: The key to predict the oxidation state distribution of trace elements?","authors":"Rémi Marsac , Charlotte Catrouillet , Mathieu Pédrot , Marc F. Benedetti , Aline Dia , Eric D. van Hullebusch , Mélanie Davranche , Yann Sivry , Anne-Catherine Pierson-Wickmann , Mickael Tharaud , Frank Heberling","doi":"10.1016/j.cocis.2024.101820","DOIUrl":"10.1016/j.cocis.2024.101820","url":null,"abstract":"<div><p>Predicting the behavior and fate of redox-sensitive trace elements (TEs; e.g. As, U, Cu, Cr) in natural systems is challenging. Colloids have been reported to control TEs speciation and catalyze TEs redox reactions in many aquatic environments. We hypothesize that the lack of accurate thermodynamic models that account for the role of colloids in TEs speciation explains our inability to predict their redox state distribution in the environment. The slow evolution of the colloidal compartment in response to the prevailing bio/hydro/pedo/climatological conditions need to be decoupled from the fast TEs redox reactions promoted by colloidal surfaces. Further progress is hampered by experimental and theoretical challenges associated with capturing the extreme physical and chemical heterogeneity of colloids, their metastable structures, and their dynamic transformation behavior.</p></div>","PeriodicalId":293,"journal":{"name":"Current Opinion in Colloid & Interface Science","volume":"72 ","pages":"Article 101820"},"PeriodicalIF":7.9,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1359029424000384/pdfft?md5=0b42978cadbabfbd36d9226625ceef70&pid=1-s2.0-S1359029424000384-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141407462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Engineering of hierarchical mesoporous silica nanoparticles via control over surfactant nanoarchitectonics for biological applications 通过控制表面活性剂纳米结构设计分层介孔二氧化硅纳米颗粒，用于生物应用

IF 7.9 2区化学

Current Opinion in Colloid & Interface Science Pub Date : 2024-06-06 DOI: 10.1016/j.cocis.2024.101819

Yang Yang, Jingcheng Hao, Jiwei Cui

{"title":"Engineering of hierarchical mesoporous silica nanoparticles via control over surfactant nanoarchitectonics for biological applications","authors":"Yang Yang, Jingcheng Hao, Jiwei Cui","doi":"10.1016/j.cocis.2024.101819","DOIUrl":"10.1016/j.cocis.2024.101819","url":null,"abstract":"<div><p>Compared to conventional mesoporous silica nanoparticles (MSNs) with ordered porous structures, hierarchical MSNs (HMSNs) have attracted increasing research interests in biological fields, owing to their highly porous structures with multiple distinct interfaces, which create more possibilities to explore complex biological realms. However, due to the structural complexity, the controllable assembly of HMSNs with desired nanostructures and well-defined particle properties is challenging. Herein, we review the advances of engineering HMSNs via control over surfactant nanoarchitectonics and discuss the synthesis-guiding principles and formation mechanisms. Based on the structural features of HMSNs, the corresponding bio-applications (e.g., macromolecule encapsulation, drug release, biointerface adhesion, immune cell activation and stimuli-responsive target motion) are summarized, highlighting the importance of structure–activity relationship. Challenges and future perspectives are also proposed for characterizations and extended applications of HMSNs.</p></div>","PeriodicalId":293,"journal":{"name":"Current Opinion in Colloid & Interface Science","volume":"72 ","pages":"Article 101819"},"PeriodicalIF":7.9,"publicationDate":"2024-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141413800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cleaning solid surfaces with liquid interfaces and foams: From theory to applications 用液体界面和泡沫清洁固体表面：从理论到应用

IF 7.9 2区化学

Current Opinion in Colloid & Interface Science Pub Date : 2024-05-31 DOI: 10.1016/j.cocis.2024.101818

Cosima Stubenrauch , Wiebke Drenckhan

{"title":"Cleaning solid surfaces with liquid interfaces and foams: From theory to applications","authors":"Cosima Stubenrauch , Wiebke Drenckhan","doi":"10.1016/j.cocis.2024.101818","DOIUrl":"10.1016/j.cocis.2024.101818","url":null,"abstract":"<div><p>All personal and industrial cleaning sectors search for environmentally friendly methods to clean contaminated solid surfaces. Having relied for a long time on chemical and physico-chemical means with non-negligible environmental impact, these sectors are increasingly exploring the use of physical phenomena to improve cleaning efficiency. We summarise here recent progress in the area of cleaning methods that exploit the physical properties of liquid interfaces created by liquid menisci, bubbles, drops or foams. The high energy of these interfaces leads to a complex interplay between (1) interfacial forces, (2) viscous stresses created by flow fields under confinement, and (3) the capacity to adsorb solid and liquid contaminations. In appropriately designed cleaning processes, this interplay can reach an astounding efficiency, in many cases even with pure water, i.e. in the absence of any detergent. We will also show that whilst foams have always been assumed to be a mere side product of cleaning processes, recent research puts in evidence that they can actually be highly efficient cleaning agents, provided that their physical properties are properly chosen. We discuss a wide range of examples in which different interface-based cleaning methods have been investigated, including solid and liquid contaminations, or biological contaminations (bacteria, biofilms and biofouling).</p></div>","PeriodicalId":293,"journal":{"name":"Current Opinion in Colloid & Interface Science","volume":"72 ","pages":"Article 101818"},"PeriodicalIF":7.9,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1359029424000360/pdfft?md5=9c7678121ea012f8b273a4e3fd04139f&pid=1-s2.0-S1359029424000360-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141512052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Amphiphilic lipids for food functionality 用于食品功能的两性脂质

IF 7.9 2区化学

Current Opinion in Colloid & Interface Science Pub Date : 2024-05-28 DOI: 10.1016/j.cocis.2024.101817

Rafael V.M. Freire, Stefan Salentinig

{"title":"Amphiphilic lipids for food functionality","authors":"Rafael V.M. Freire, Stefan Salentinig","doi":"10.1016/j.cocis.2024.101817","DOIUrl":"https://doi.org/10.1016/j.cocis.2024.101817","url":null,"abstract":"<div><p>Amphiphilic lipids are essential biomolecules, critical components in nature's functional materials, and crucial nutrients in food. Being sustainable, biocompatible, and biodegradable with versatile structural properties, they have great potential as functional building blocks for innovative food materials. They can tailor factors including texture, mouthfeel, appearance, and nutrient delivery. Their structural analysis from the angstrom to the micrometer range lies at the core of the functional material design and is fundamental for their further biological understanding.</p><p>We discuss recent advances in colloidal structure formation and challenges in characterizing structures and dynamics in lipid-based materials on the microstructural level. We provide examples of how lipid self-assemblies, particularly lyotropic liquid crystalline structures, can enhance food materials. The interdisciplinary development of this growing research field helps explore new functionalities for food applications.</p></div>","PeriodicalId":293,"journal":{"name":"Current Opinion in Colloid & Interface Science","volume":"72 ","pages":"Article 101817"},"PeriodicalIF":7.9,"publicationDate":"2024-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1359029424000359/pdfft?md5=5e089bc3bfa8f4ec516240ae012f5239&pid=1-s2.0-S1359029424000359-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141481100","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Molecular dynamics simulations as support for experimental studies on surfactant interfacial layers 分子动力学模拟为表面活性剂界面层实验研究提供支持

IF 7.9 2区化学

Current Opinion in Colloid & Interface Science Pub Date : 2024-05-28 DOI: 10.1016/j.cocis.2024.101816

Matej Kanduč , Joshua Reed , Alexander Schlaich , Emanuel Schneck

{"title":"Molecular dynamics simulations as support for experimental studies on surfactant interfacial layers","authors":"Matej Kanduč , Joshua Reed , Alexander Schlaich , Emanuel Schneck","doi":"10.1016/j.cocis.2024.101816","DOIUrl":"https://doi.org/10.1016/j.cocis.2024.101816","url":null,"abstract":"<div><p>Surfactants play an increasingly important role across diverse scientific and industrial domains. Gaining a deeper understanding of their molecular behavior at various interfaces is thus becoming ever more essential. Despite considerable advances in experimental techniques, challenges in capturing the detailed molecular-level behavior of surfactants at interfaces persist. In this work, we discuss the potential of combining various experimental methods with atomistic molecular dynamics (MD) simulations in studies of surfactant interfacial layers. MD simulations have emerged as a powerful tool that provides detailed insights into molecular structures and dynamic properties, some of which are inaccessible through experimental means alone. By re-examining existing MD simulation data and directly comparing them with experiments, we illustrate how MD simulations can be used to validate and support thermodynamic models and interpret spectroscopy and scattering data. While combining scattering experiments on Langmuir layers of insoluble surfactants with simulations seems to be well-established by now, we emphasize the growing capability of scattering techniques to also investigate the more disordered Gibbs layers of soluble surfactants. Here, MD simulations can now connect the pressure and adsorption isotherms with the equation of state. In light of the ongoing parallel developments of computational and experimental methods, their synergistic use can be expected to drive future progress in surfactant research.</p></div>","PeriodicalId":293,"journal":{"name":"Current Opinion in Colloid & Interface Science","volume":"72 ","pages":"Article 101816"},"PeriodicalIF":7.9,"publicationDate":"2024-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1359029424000347/pdfft?md5=367aaf6b1fdd28a169d0b3ff1fe7fded&pid=1-s2.0-S1359029424000347-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141481101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Foam-assisted oil recovery: A physics-based perspective 泡沫辅助采油：基于物理学的视角

IF 8.9 2区化学

Current Opinion in Colloid & Interface Science Pub Date : 2024-05-17 DOI: 10.1016/j.cocis.2024.101809

Hernán A. Ritacco

引用次数: 0

Foams/bubbles stabilized with polymer particles 用聚合物颗粒稳定的泡沫/气泡

IF 8.9 2区化学

Current Opinion in Colloid & Interface Science Pub Date : 2024-05-16 DOI: 10.1016/j.cocis.2024.101808

Syuji Fujii

引用次数: 0

Interfacial properties of (super)spreading trisiloxane surfactants 超）扩展三硅氧烷表面活性剂的界面特性