Sustainable Chemistry for Climate Action最新文献_第5页

Adsorbent technologies and applications for carbon capture, and direct air capture in environmental perspective and sustainable climate action 在环境和可持续气候行动中碳捕获和直接空气捕获的吸附技术和应用

Sustainable Chemistry for Climate Action Pub Date : 2023-01-01 DOI: 10.1016/j.scca.2023.100029

Olusola Olaitan Ayeleru , Helen Uchenna Modekwe , Oluwatayo Racheal Onisuru , Chinemerem Ruth Ohoro , Christianah Aarinola Akinnawo , Peter Apata Olubambi

{"title":"Adsorbent technologies and applications for carbon capture, and direct air capture in environmental perspective and sustainable climate action","authors":"Olusola Olaitan Ayeleru , Helen Uchenna Modekwe , Oluwatayo Racheal Onisuru , Chinemerem Ruth Ohoro , Christianah Aarinola Akinnawo , Peter Apata Olubambi","doi":"10.1016/j.scca.2023.100029","DOIUrl":"https://doi.org/10.1016/j.scca.2023.100029","url":null,"abstract":"<div>The contribution of greenhouse gas and anthropogenic CO2 to climate change is an undeniably issue that needs urgent attention from the environmental point of view. Global warming, a consequence of continued CO2 emissions will gradually result in ecosystem disruption and drought. With the increasing problem of greenhouse gas (GHG) and the established environmentally unfriendly consequences associated with it, carbon capture and storage (CCS) was proposed as a measure to successfully reduce carbon footprints and a process of choice in proffering solutions to this challenge. To meet the Paris agreement's target of maintaining the global temperature rise below 2 °C necessitates the capture and removal of up to 20 Gt CO2 per annum by the end of the century. However, going by the current global CO2 capture and storage capacity of 0.0385 Gt CO2/annum (including the current direct air capture (DAC) capacity of 9,000 tons CO2/annum), it will take close to 21,000 years to achieve this set goal. Hence, the need to adopt sustainable low-temperature sorbent technology with efficient adsorption capabilities that will meet up with the bourgeoning operating cost and energy demand for DAC technology. In this review, sustainable and emerging adsorbent materials and technologies employed in carbon capture and storage were highlighted. Also, economic, and environmental benefits and public perception of carbon capture technology were enumerated.</div>","PeriodicalId":101195,"journal":{"name":"Sustainable Chemistry for Climate Action","volume":"3 ","pages":"Article 100029"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49718044","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

CO2 captured by silicoaluminophosphate (SAPO) zeotypes 硅铝磷酸盐（SAPO）沸石捕获的CO2

Sustainable Chemistry for Climate Action Pub Date : 2023-01-01 DOI: 10.1016/j.scca.2023.100022

Haopeng Su , Yan Yan , Jia-Nan Zhang , Wenfu Yan

引用次数: 1

Green synthesis of silver nanoparticles for ultrafiltration membrane surface modification and antimicrobial activity 绿色合成纳米银用于超滤膜表面改性及抗菌活性研究

Sustainable Chemistry for Climate Action Pub Date : 2023-01-01 DOI: 10.1016/j.scca.2023.100031

Hansnath Tiwari , Kulbhushan Samal , Sachin Rameshrao Geed , Sounak Bera , Chandan Das , Kaustubha Mohanty

{"title":"Green synthesis of silver nanoparticles for ultrafiltration membrane surface modification and antimicrobial activity","authors":"Hansnath Tiwari , Kulbhushan Samal , Sachin Rameshrao Geed , Sounak Bera , Chandan Das , Kaustubha Mohanty","doi":"10.1016/j.scca.2023.100031","DOIUrl":"https://doi.org/10.1016/j.scca.2023.100031","url":null,"abstract":"<div>This study presents the application of biosynthesized silver nanoparticles (AgNPs) for modifying the surface of ultrafiltration membranes to confer antimicrobial properties. The AgNPs were synthesized using leaf extract of the medicinal plant Mimusops elengi L, and their characterization was carried out using UV spectroscopy, FTIR, XRD, FESEM, HRTEM, and AFM analyses. The optimal conditions for the synthesis of AgNPs were determined to be 240 min of reaction time, pH 9.5, 1:1 (v/v) ratio of initial concentration of precursor to bio-extract, and 323 K temperature. The synthesized AgNPs were found to be spherical with an average size of 20 nm and crystalline in nature. The AgNPs were then deposited on flat sheet polyether sulfone (PES) membranes (MWCO 30 kDa) using the dip coating technique. The deposition of AgNPs on the membrane surface was confirmed using FESEM and EDX analysis. The resulting AgNPs-incorporated membrane demonstrated effective antibacterial activity against E.coli. These findings highlight the potential of biosynthesized AgNPs for developing functionalized ultrafiltration membranes with antimicrobial properties.</div>","PeriodicalId":101195,"journal":{"name":"Sustainable Chemistry for Climate Action","volume":"3 ","pages":"Article 100031"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49718057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Green approach for chemical production from waste cooking oils 废弃食用油生产化工产品的绿色途径

Sustainable Chemistry for Climate Action Pub Date : 2023-01-01 DOI: 10.1016/j.scca.2023.100017

Jonathan Harris, Anh N. Phan

引用次数: 0

The prospects of hydrogen in achieving net zero emissions by 2050: A critical review 氢在2050年实现净零排放的前景:一项重要审查

Sustainable Chemistry for Climate Action Pub Date : 2023-01-01 DOI: 10.1016/j.scca.2023.100024

Somtochukwu Godfrey Nnabuife , Eni Oko , Boyu Kuang , Abdulrauf Bello , Azikiwe Peter Onwualu , Sherry Oyagha , James Whidborne

{"title":"The prospects of hydrogen in achieving net zero emissions by 2050: A critical review","authors":"Somtochukwu Godfrey Nnabuife , Eni Oko , Boyu Kuang , Abdulrauf Bello , Azikiwe Peter Onwualu , Sherry Oyagha , James Whidborne","doi":"10.1016/j.scca.2023.100024","DOIUrl":"https://doi.org/10.1016/j.scca.2023.100024","url":null,"abstract":"<div>Hydrogen (H2) usage was 90 tnes (Mt) in 2020, almost entirely for industrial and refining uses and generated almost completely from fossil fuels, leading to nearly 900 Mt of carbon dioxide emissions. However, there has been significant growth of H2 in recent years. Electrolysers' total capacity, which are required to generate H2 from electricity, has multiplied in the past years, reaching more than 300 MW through 2021. Approximately 350 projects reportedly under construction could push total capacity to 54 GW by the year 2030. Some other 40 projects totalling output of more than 35 GW are in the planning phase. If each of these projects is completed, global H2 production from electrolysers could exceed 8 Mt by 2030. It's an opportunity to take advantage of H2S prospects to be a crucial component of a clean, safe, and cost-effective sustainable future. This paper assesses the situation regarding H2 at the moment and provides recommendations for its potential future advancement. The study reveals that clean H2 is experiencing significant, unparalleled commercial and political force, with the amount of laws and projects all over the globe growing quickly. The paper concludes that in order to make H2 more widely employed, it is crucial to significantly increase innovations and reduce costs. The practical and implementable suggestions provided to industries and governments will allow them to fully capitalise on this growing momentum.</div>","PeriodicalId":101195,"journal":{"name":"Sustainable Chemistry for Climate Action","volume":"2 ","pages":"Article 100024"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49732816","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 5

The promise of N-heterocyclic carbenes to capture and valorize carbon dioxide n -杂环碳化合物捕获二氧化碳并使其增值的前景

Sustainable Chemistry for Climate Action Pub Date : 2023-01-01 DOI: 10.1016/j.scca.2023.100018

Pierre Stiernet , Bo Pang , Daniel Taton , Jiayin Yuan

{"title":"The promise of N-heterocyclic carbenes to capture and valorize carbon dioxide","authors":"Pierre Stiernet , Bo Pang , Daniel Taton , Jiayin Yuan","doi":"10.1016/j.scca.2023.100018","DOIUrl":"https://doi.org/10.1016/j.scca.2023.100018","url":null,"abstract":"<div>With increasing environmental concerns due to the anthropologic emissions of greenhouse gasses, especially carbon dioxide (CO2), the development of new technologies to capture the latter is of great public value. While amino-containing materials excel in capturing CO2, they generally suffer from a few limitations, namely, the high energy penalty for desorption and the obstacle to directly convert CO2 into valuable resources. In this context, molecular or polymeric compounds based on N-heterocyclic carbenes (NHCs) have emerged as versatile alternatives to efficiently sequester CO2. NHCs are among the most investigated reactive species in chemistry: not only have they been intensively used as ligands for transition metal catalysts but also they exhibit a rich chemistry, either as true reagents or as organic catalysts. However, their air- and moisture-sensitivity represents a limitation to their use in synthesis. As reviewed thereafter, NHCs can selectively react with CO2 forming stable adducts, in the form of zwitterionic betaine-type species, providing CO2 directly-on-site for further fixation. Advances in the use of NHCs in this field are illustrated in this paper with a special emphasis on integration of NHCs in materials enabling heterogeneous utilizations in capture and catalysis.</div>","PeriodicalId":101195,"journal":{"name":"Sustainable Chemistry for Climate Action","volume":"2 ","pages":"Article 100018"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49732903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

The impact of Direct Air Capture during the last two decades: A bibliometric analysis of the scientific research, part I 近二十年来直接空气捕获的影响:科学研究的文献计量学分析，第一部分

Sustainable Chemistry for Climate Action Pub Date : 2022-01-01 DOI: 10.1016/j.scca.2022.100009

Daniel Casaban, Sean Ritchie, Elena Tsalaporta

{"title":"The impact of Direct Air Capture during the last two decades: A bibliometric analysis of the scientific research, part I","authors":"Daniel Casaban, Sean Ritchie, Elena Tsalaporta","doi":"10.1016/j.scca.2022.100009","DOIUrl":"10.1016/j.scca.2022.100009","url":null,"abstract":"<div>The controversy about meeting the expected capture demands from carbon dioxide removals such as Direct Air Capture (DAC) are debatable. In the past, the vast investment in renewable technology is allowing today's rapid deployment. Why is this not currently happening in the CO2 capture area? This bibliometric analysis which focused on the use of solid sorbents in the CO2 capture field between 2001 and 2021, aims to answer these questions. The study reviewed three capture methods: post-combustion, pre-combustion and DAC, with particular emphasis on the latter. To understand the evolution of DAC, this novel approach highlights which authors and countries have been investigating the use of solid sorbents. The outcomes of this research showed that, during the first decade, there was a minor interest in funding and investigating solid sorbents for DAC solutions. It was only at the end of the second period when the use of these materials in the topic emerged to the surface. Acting as an example, the United States, China and the United Kingdom spent more financial help to investigate the use of sorbents. However, all of today's CO2 capture plants are working for enhanced oil recovery. In the Republic of Ireland, there are a few articles exploring the use of these materials to uptake CO2. It is possible that certain articles were not considered by the software. Upcoming analysis will answer this question and include all the existing materials in the wide spectrum of solid sorbents at the CO2 capture field.</div>","PeriodicalId":101195,"journal":{"name":"Sustainable Chemistry for Climate Action","volume":"1 ","pages":"Article 100009"},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772826922000086/pdfft?md5=74cd551e8a08ea392c86ebd08542327e&pid=1-s2.0-S2772826922000086-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81430543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3

Conceptual design of an autonomous catalytic generator based on bioethanol steam reforming over the ferrite catalyst 基于生物乙醇蒸汽在铁氧体催化剂上重整的自主催化发生器的概念设计

Sustainable Chemistry for Climate Action Pub Date : 2022-01-01 DOI: 10.1016/j.scca.2022.100010

L.Y. Dolgikh, A.A. Zhokh, A.I. Trypolskyi, I.L. Stolyarchuk, Y.I. Pyatnitsky, P.E. Strizhak

引用次数: 0

Developments in the investigation of nitrogen and oxygen stable isotopes in atmospheric nitrate 大气硝酸盐中氮氧稳定同位素的研究进展

Sustainable Chemistry for Climate Action Pub Date : 2022-01-01 DOI: 10.1016/j.scca.2022.100003

Shah Saud , Shah Fahad , Shah Hassan

{"title":"Developments in the investigation of nitrogen and oxygen stable isotopes in atmospheric nitrate","authors":"Shah Saud , Shah Fahad , Shah Hassan","doi":"10.1016/j.scca.2022.100003","DOIUrl":"10.1016/j.scca.2022.100003","url":null,"abstract":"<div>Under the influence of human activities and the rapid development of industry and agriculture, atmospheric nitrate (NO−3) pollution is becoming increasingly serious and has become an environmental problem worldwide. The stable isotopic composition of atmospheric NO−3 (δ15N, δ18O, and Δ17O) can provide a strong basis for understanding the atmospheric nitrogen cycle to effectively control atmospheric NOx pollution. In this work, the δ15N values associated with different sources of atmospheric NO−3, the seasonal variation characteristics of δ15N-NO−3, and the main influencing factors are reviewed. The δ18O and Δ17O values of different oxidants in the atmosphere and the spatiotemporal distribution characteristics and possible influencing factors of the δ18O and Δ17O values of atmospheric NO−3 are summarised. In addition, key advances in NO−3 isotopic analysis technique is reviewed. Based on previous work, it is suggested that more attention should be given to the oxidative formation mechanism of NO−3 (spatio-temporal differences in the isotopic compositions of different types of oxidants), the δ15N composition of different NOx sources, and the processes of formation, transport, depositional/chemical loss ofatmospheric NO−3 with the help of observation and chemical models.</div>","PeriodicalId":101195,"journal":{"name":"Sustainable Chemistry for Climate Action","volume":"1 ","pages":"Article 100003"},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772826922000037/pdfft?md5=4bb129345f1c205adfd23c6f8f124594&pid=1-s2.0-S2772826922000037-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83792997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 4

A new way to make oxalic acid from CO2 and alkali formates: Using the active carbonite intermediate 以CO2和碱甲酸酯为原料制备草酸的新方法:利用活性碳中间体

Sustainable Chemistry for Climate Action Pub Date : 2022-01-01 DOI: 10.1016/j.scca.2022.100001

Eric Schuler , Michele Morana , N. Raveendran Shiju , Gert-Jan M. Gruter

{"title":"A new way to make oxalic acid from CO2 and alkali formates: Using the active carbonite intermediate","authors":"Eric Schuler , Michele Morana , N. Raveendran Shiju , Gert-Jan M. Gruter","doi":"10.1016/j.scca.2022.100001","DOIUrl":"https://doi.org/10.1016/j.scca.2022.100001","url":null,"abstract":"<div>Conversion of CO2 to valuable chemicals such as polymers via the electrochemical reduction of CO2 to formate followed by the formate to oxalate coupling reaction (FOCR) is an interesting concept to replace fossil feedstocks with renewable ones. Yet, the activation of CO2 is challenging and energy-intensive and today the production of one oxalate molecule first requires the reduction of two CO2 molecules. Recently we confirmed the crucial role of the reactive carbonite intermediate in the FOCR. Due to its high reactivity, this intermediate might also be a strong enough nucleophile to react with CO2 directly. If this is the case, we can form oxalate directly from CO2 and formate and avoid the need for double electrochemical CO2 reduction in oxalate production. In this work, we successfully established the conversion of CO2 (with a theoretical yield of 52%) to oxalate (via the reaction with carbonite), as well as to formate and carbonate. The direct reaction of the reactive carbonite intermediate with CO2 was the dominant pathway for CO2 incorporation in oxalate. For enhancing the CO2 incorporation in oxalate, we found a reaction temperature of 200°C, stoichiometric amounts of the base, and the presence of CO2 in the supercritical state most suitable. The residence time is strongly depending on the reactor type but should be kept to a minimum to avoid carbonate formation. The presence of high amounts of hydride and supercritical CO2 appeared to also cause the formation of carbonates as a side-product. The carbonate formation increased with higher temperatures and longer reaction times, which suggests a consecutive decomposition of oxalate formed in the reaction.</div>","PeriodicalId":101195,"journal":{"name":"Sustainable Chemistry for Climate Action","volume":"1 ","pages":"Article 100001"},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772826922000013/pdfft?md5=235bb51faf7c1bded18cf51e9ee6f096&pid=1-s2.0-S2772826922000013-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136850567","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3