{"title":"Corrigendum to \"Hyaluronic acid coating on the surface of curcumin-loaded ZIF-8 nanoparticles for improved breast cancer therapy: An in vitro and in vivo study\" [Colloid. Surf. B Biointerfaces 203 (2021) 111759 /COLSUB-D-20-01957].","authors":"Shaoxuan Yu, Shanyu Wang, Zhike Xie, Shuyan Yu, Ling Li, Haifang Xiao, Yuanda Song","doi":"10.1016/j.colsurfb.2025.114894","DOIUrl":"10.1016/j.colsurfb.2025.114894","url":null,"abstract":"","PeriodicalId":279,"journal":{"name":"Colloids and Surfaces B: Biointerfaces","volume":" ","pages":"114894"},"PeriodicalIF":5.6,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144525763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaomei Wan, Xinran Xiang, Susu Tang, Dinghua Yu, He Huang, Yi Hu
{"title":"Corrigendum to \"Immobilization of Candida antarctica lipase B on MWNTs modified by ionic liquids with different functional groups\" [Colloids Surf. B Biointerfaces 160 (2017) 416-422].","authors":"Xiaomei Wan, Xinran Xiang, Susu Tang, Dinghua Yu, He Huang, Yi Hu","doi":"10.1016/j.colsurfb.2025.114921","DOIUrl":"10.1016/j.colsurfb.2025.114921","url":null,"abstract":"","PeriodicalId":279,"journal":{"name":"Colloids and Surfaces B: Biointerfaces","volume":" ","pages":"114921"},"PeriodicalIF":5.6,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144551546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Hydrophobic deep eutectic solvent-based ferrofluid for the multi-residue analysis of pyrethroid insecticides in agricultural products: Facile pretreatment and MS-friendly detection.","authors":"Yuxin Liu, Chenjie Ma, Mantang Chen, Jufang Hao, Wei Liu, Jingjing Yu","doi":"10.1016/j.chroma.2025.466262","DOIUrl":"10.1016/j.chroma.2025.466262","url":null,"abstract":"<p><p>Pyrethroid insecticides (PYs) overuse poses ecological and health risks, leading to tightened restrictions on maximum residue limits (MRLs) by regulatory bodies like the European Union and China's National Food Safety Standards. It is important to develop multi-residue analytical methods for PYs residues. In present work, oleic acid-coated Fe<sub>3</sub>O<sub>4</sub> nanoparticles (Fe<sub>3</sub>O<sub>4</sub>-OA) were dispersed in hydrophobic deep eutectic solvents (HDES) to prepare ferrofluids (FFs), with the HDES synthesized from coumarin and thymol at a 1:2 molar ratio. And the HDES-FF was subsequently utilized as a vortex-assisted liquid-phase microextraction sorbent for the enrichment of 16 PYs, combined with GC-MS/MS analysis. HDES-FF could effectively enrich PYs within merely 3.5 min according to π-π stacking interactions and hydrophobic effects, while Fe<sub>3</sub>O<sub>4</sub>-OA nanoparticles were responsible for magnetic separation. It could successfully solve the problem of separation difficulty after liquid-liquid microextraction based on DES. Simultaneously, thermogravimetric analysis confirmed that the HDES could decompose at injection port of GC-MS/MS instrument, and mass spectrometry signals of the decomposed HDES could not be collected by adjusting the solvent delay time. Thus, it could effectively protect the ion source from contamination, making DES compatible with GC-MS methods. The detection limit (LOD) of the proposed method is 0.41-7.91 ng/mL, with the recoveries of 83.33-106.02 %. The intra-day and inter-day relative standard deviations (RSDs) are less than 4.20 % and 6.94 %, respectively. The method successfully detected 16 PYs in various real fruit and vegetable samples.</p>","PeriodicalId":347,"journal":{"name":"Journal of Chromatography A","volume":"1759 ","pages":"466262"},"PeriodicalIF":4.0,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144797853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Microplastic Diversity as a Potential Driver of Soil Denitrification Shifts.","authors":"Tian-Gui Cai,Da Lin,Bang Ni,Tian-Lun Zhang,Yi-Fei Wang,Dong Zhu","doi":"10.1021/acs.est.5c04981","DOIUrl":"https://doi.org/10.1021/acs.est.5c04981","url":null,"abstract":"Microplastics (MPs) are raising significant global concerns due to their environmental impacts. While most studies have focused on the effects of individual MP types, MPs in natural environments typically coexist as multiple types, and their combined effects remain poorly understood. In this study, we conducted a microcosm experiment with four levels of MP diversity (0, 1, 3, and 5 types) to investigate the effects of MP diversity on soil ecosystem functions using metagenomic sequencing. Our results revealed that increasing MP diversity significantly raised soil pH and organic carbon content while reducing available nitrogen. Notably, bacterial alpha diversity (Shannon and Invsimpson indices) increased significantly with higher MP diversity. Moreover, increasing MP diversity markedly shifted bacterial life-history strategies to adapt to the altered environment. Importantly, the abundance of nitrogen-related functional genes also increased with MP diversity. In particular, the abundance of denitrifying genes, predominantly driven by Rhodocyclaceae, was notably enhanced, resulting in a reduction of soil available nitrogen. Collectively, these findings offer valuable insights into the impact of MP diversity on soil function─especially within the nitrogen cycle─and have important implications for soil management strategies under MP stress.","PeriodicalId":36,"journal":{"name":"环境科学与技术","volume":"25 1","pages":""},"PeriodicalIF":9.028,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145003218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
环境科学与技术Pub Date : 2025-09-06DOI: 10.1021/acs.est.5c09511
Ziyue Jiang,Yongtao Li,Ziyu Tang,Dingkun Yuan,Fawei Lin
{"title":"Strong Metal-Support Interactions in Catalytic Oxidation of VOCs: Mechanistic Insights, Support Engineering Strategies, and Emerging Catalyst Design Paradigms.","authors":"Ziyue Jiang,Yongtao Li,Ziyu Tang,Dingkun Yuan,Fawei Lin","doi":"10.1021/acs.est.5c09511","DOIUrl":"https://doi.org/10.1021/acs.est.5c09511","url":null,"abstract":"Volatile organic compounds (VOCs) significantly impact air quality as photochemical smog precursors and health hazards. Catalytic oxidation is a leading VOC abatement method but suffers from catalyst deactivation due to metal sintering and competitive adsorption in complex mixtures. Strong metal-support interactions (SMSIs) provide atomic level control of interfacial electronic and geometric structures. SMSI enables bidirectional charge transfer, d band center modulation, oxygen vacancy generation, and tunable encapsulation that together promote O2 activation, lower barriers, and impart thermal and chemical robustness. This review synthesizes mechanistic insights and recent progress in SMSI-enabled VOC oxidation, integrating in situ and operando probes with kinetics. Reactivity and selectivity across aromatics, alkanes, oxygenates, and chlorinated species are rationalized by SMSI-mediated tuning of adsorption and intermediate evolution. Practical levers include control of particle size and dispersion, core-shell architectures, metal loading, and support acidity or basicity. Emerging directions include single atom catalysts, high entropy alloys, and nonmetal supports. Key challenges concern the dynamic evolution of SMSI under realistic feeds and the scalable, reproducible synthesis of interfaces. Future developments combining in situ characterization with data-driven catalyst design hold promise for achieving durable, high-performance VOC abatement with reduced precious metal usage.","PeriodicalId":36,"journal":{"name":"环境科学与技术","volume":"16 1","pages":""},"PeriodicalIF":9.028,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145003217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yi Xiao,Xiya Zhang,Junyu Zhou,Fei Yuan,Lei Wu,Zheng Liu,Xiaojuan Wang,Jingxian Yu,Shiqing Li
{"title":"Recyclable Cu-Catalyzed N-Methylation and C5-Methylthiomethylation of Isatins with DMSO.","authors":"Yi Xiao,Xiya Zhang,Junyu Zhou,Fei Yuan,Lei Wu,Zheng Liu,Xiaojuan Wang,Jingxian Yu,Shiqing Li","doi":"10.1021/acs.joc.5c01815","DOIUrl":"https://doi.org/10.1021/acs.joc.5c01815","url":null,"abstract":"An unprecedented recyclable system of copper-catalyzed C-C/N coupling of isatins and DMSO without any oxidant and acidic/basic additive has been unlocked. The NH-isatins occur tandem N-methylation and C5-methylthiomethylation in order, while N-substituted isatins proceed C5-methylthiomethylation only. DMSO serves as Me and MeSCH2 sources as well as the solvent. DCE is essential for providing a radical initiator and halogen cation pool. In this protocol, two vital ionic liquids (ILs), reactive methyl(methylene)-sulfonium and inert trimethylsulfonium, are generated in situ to promote homogeneous-to-heterogeneous phase transition. The ILs accumulate in the lower layer to drag the copper catalyst but push the product, enabling separating the catalyst and product through simple decantation. The lower layer can be recycled as a catalyst for at least six cycles. The systematic and comprehensive control experiments, ESI-MS, and DFT calculations indicate that site selectivity is controlled by atomic charge distribution and steric factors; and the interaction between ILs and Cu salts can reduce the reaction energy barrier.","PeriodicalId":57,"journal":{"name":"Journal of Organic Chemistry","volume":"40 1","pages":""},"PeriodicalIF":4.354,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145003254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}