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Research progress on metal-support interactions over Ni-based catalysts for CH4-CO2 reforming reaction ni基催化剂上金属-载体相互作用对CH4-CO2重整反应的研究进展
燃料化学学报 Pub Date : 2025-04-01 DOI: 10.1016/S1872-5813(24)60500-1
Kai SUN, Jianfei JIANG, Zixuan LIU, Shiqi GENG, Zhenmin LIU, Jiaqian YANG, Shasha LI
{"title":"Research progress on metal-support interactions over Ni-based catalysts for CH4-CO2 reforming reaction","authors":"Kai SUN,&nbsp;Jianfei JIANG,&nbsp;Zixuan LIU,&nbsp;Shiqi GENG,&nbsp;Zhenmin LIU,&nbsp;Jiaqian YANG,&nbsp;Shasha LI","doi":"10.1016/S1872-5813(24)60500-1","DOIUrl":"10.1016/S1872-5813(24)60500-1","url":null,"abstract":"<div><div>With ongoing global warming and increasing energy demands, the CH<sub>4</sub>-CO<sub>2</sub> reforming reaction (dry reforming of methane, DRM) has garnered significant attention as a promising carbon capture and utilization technology. Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process. The impact of metal-support interaction (MSI), on Ni-based catalyst performance has been extensively researched and debated recently. This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions. From the perspective of MSI, the effects of different carriers (metal oxides, carbon materials and molecular sieves, etc.) are introduced on the dispersion and surface structure of Ni active metal particles, and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail. Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH<sub>4</sub>-CO<sub>2</sub> reforming, advancing cleaner energy technologies.</div></div>","PeriodicalId":15956,"journal":{"name":"燃料化学学报","volume":"53 4","pages":"Pages 434-451"},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geochemical differences in natural gas of Sinian Dengying Formation on the east and west sides of the Deyang-Anyue rift trough and their genesis, Sichuan Basin, SW China 四川盆地德阳—安岳裂谷东西两侧震旦系灯影组天然气地球化学差异及其成因
IF 7
Petroleum Exploration and Development Pub Date : 2025-04-01 DOI: 10.1016/S1876-3804(25)60576-3
Zezhang SONG , Shigui JIN , Bing LUO , Qingyong LUO , Xingwang TIAN , Dailin YANG , Ziyu ZHANG , Wenjin ZHANG , Luya WU , Jiali TAO , Jiahuan HE , Wenzheng LI , Bingfei GE , Guan WANG , Jiawei GAO
{"title":"Geochemical differences in natural gas of Sinian Dengying Formation on the east and west sides of the Deyang-Anyue rift trough and their genesis, Sichuan Basin, SW China","authors":"Zezhang SONG ,&nbsp;Shigui JIN ,&nbsp;Bing LUO ,&nbsp;Qingyong LUO ,&nbsp;Xingwang TIAN ,&nbsp;Dailin YANG ,&nbsp;Ziyu ZHANG ,&nbsp;Wenjin ZHANG ,&nbsp;Luya WU ,&nbsp;Jiali TAO ,&nbsp;Jiahuan HE ,&nbsp;Wenzheng LI ,&nbsp;Bingfei GE ,&nbsp;Guan WANG ,&nbsp;Jiawei GAO","doi":"10.1016/S1876-3804(25)60576-3","DOIUrl":"10.1016/S1876-3804(25)60576-3","url":null,"abstract":"<div><div>Taking the natural gas reservoirs of the Sinian Dengying Formation on the east and west sides (Gaoshiti-Moxi area and north slope of central Sichuan paleo-uplift on the east; Weiyuan and Well Datan-1 block on the west) of the Deyang-Anyue rift trough in the Sichuan Basin, China, as the research object, the geochemical parameters (component, isotopic composition) of natural gas from the Dengying Formation in different areas are compared, and then the differences in geochemical characteristics of Dengying natural gas on the east and west sides of the Deyang-Anyue rift trough and their genesis are clarified. First, the Dengying gas reservoirs on both sides of the rift trough are predominantly composed of oil-cracking gas with high maturity, which is typical dry gas. Second, severely modified by thermochemical sulfate reduction (TSR) reaction, the Dengying gas reservoirs on the east side exhibit high H<sub>2</sub>S and CO<sub>2</sub> contents, with an elevated δ<sup>13</sup>C<sub>2</sub> value (average value higher than −29‰). The Dengying gas reservoirs in the Weiyuan area are less affected by TSR modification, though the δ<sup>13</sup>C<sub>1</sub> values are slightly greater than that of the reservoirs on the east side with partial reversal of carbon isotope composition, likely due to the water-soluble gas precipitation and accumulation mechanism. The Dengying gas reservoir of Well Datan-1 shows no influence from TSR. Third, the Dengying gas reservoirs reflect high helium contents (significantly higher than that on the east side) in the Weiyuan and Datan-1 areas on the west side, which is supposed to attribute to the widespread granites in basement and efficient vertical transport along faults. Fourth, controlled by the paleo-salinity of water medium in the depositional period of the source rock, the δ<sup>2</sup>H<sub>CH4</sub> values of the Dengying gas reservoirs on the west side are slightly lighter than those on the east side. Fifth, the Dengying natural gas in the Datan-1 area is contributed by the source rocks of the Sinian Doushantuo Formation and the third member of the Dengying Formation, in addition to the Cambrian Qiongzhusi Formation.</div></div>","PeriodicalId":67426,"journal":{"name":"Petroleum Exploration and Development","volume":"52 2","pages":"Pages 422-434"},"PeriodicalIF":7.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143873786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative study on the oblique water-entry of high-speed projectile based on rigid-body and elastic-plastic body model 基于刚体和弹塑性模型的高速弹丸斜入水比较研究
IF 5
Defence Technology(防务技术) Pub Date : 2025-04-01 DOI: 10.1016/j.dt.2024.11.007
Xiangyan Liu , Xiaowei Cai , Zhengui Huang , Yu Hou , Jian Qin , Zhihua Chen
{"title":"Comparative study on the oblique water-entry of high-speed projectile based on rigid-body and elastic-plastic body model","authors":"Xiangyan Liu ,&nbsp;Xiaowei Cai ,&nbsp;Zhengui Huang ,&nbsp;Yu Hou ,&nbsp;Jian Qin ,&nbsp;Zhihua Chen","doi":"10.1016/j.dt.2024.11.007","DOIUrl":"10.1016/j.dt.2024.11.007","url":null,"abstract":"<div><div>To examine the similarities and differences in the evolution of cavity, wetting and dynamics of a high-speed, oblique water-entry projectile with different positive angles of attack, a comparative analysis has been conducted based on the numerical results of two mathematical models, the rigid-body model and fluid-structure interaction model. In addition, the applicable scope of the above two methods, and the structural response characteristics of the projectile have also been investigated. Our results demonstrate that: (1) The impact loads and angular motion of the projectile of the rigid-body method are more likely to exhibit periodic variations due to the periodic tail slap, its range of positive angles of attack is about <em>α</em> &lt; 2°. (2) When the projectile undergone significant wetting, a strong coupling effect is observed among wetting, structural deformation, and projectile motion. With the applied projectile shape, it is observed that, when the projectile bends, the final wetting position is that of Part B (cylinder of body). With the occurrence of this phenomenon, the projectile ballistics become completely unstable. (3) The force exerted on the lower surface of the projectile induced by wetting is the primary reason of the destabilization of the projectile trajectory and structural deformation failure. Bending deformation is most likely to appear at the junction of Part C (cone of body) and Part D (tail). The safe angles of attack of the projectile stability are found to be about <em>α</em> ≤ 2°.</div></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"46 ","pages":"Pages 133-155"},"PeriodicalIF":5.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143829802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A fast-running engineering tool for assessing structural vulnerability to blast loading 一种快速运行的工程工具,用于评估结构对爆炸载荷的脆弱性
IF 5
Defence Technology(防务技术) Pub Date : 2025-04-01 DOI: 10.1016/j.dt.2024.12.009
Carlo Crispino, Salvatore Annunziata, Alberto Contini, Luca Lomazzi, Andrea Manes
{"title":"A fast-running engineering tool for assessing structural vulnerability to blast loading","authors":"Carlo Crispino,&nbsp;Salvatore Annunziata,&nbsp;Alberto Contini,&nbsp;Luca Lomazzi,&nbsp;Andrea Manes","doi":"10.1016/j.dt.2024.12.009","DOIUrl":"10.1016/j.dt.2024.12.009","url":null,"abstract":"<div><div>Assessing the vulnerability of a platform is crucial in its design. In fact, the results obtained from vulnerability analyses provide valuable information, leading to precise design choices or corrective solutions that enhance the platform's chances of surviving different scenarios. Such scenarios can involve various types of threats that can affect the platform's survivability. Among such, blast waves impacting the platform's structure represent critical conditions that have not yet been studied in detail. That is, frameworks for vulnerability assessment that can deal with blast loading have not been presented yet. In this context, this work presents a fast-running engineering tool that can quantify the risk that a structure fails when it is subjected to blast loading from the detonation of high explosive-driven threats detonating at various distances from the structure itself. The tool has been implemented in an in-house software that calculates vulnerability to various impacting objects, and its capabilities have been shown through a simplified, yet realistic, case study. The novelty of this research lies in the development of an integrated computational environment capable of calculating the platform's vulnerability to blast waves, without the need for running expensive finite element simulations. In fact, the proposed tool is fully based on analytical models integrated with a probabilistic approach for vulnerability calculation.</div></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"46 ","pages":"Pages 244-254"},"PeriodicalIF":5.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143829806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interface geometry modification to trap plasticized flash for improved joint strength of dissimilar rotary friction welds 改进界面几何形状以捕获塑化闪光以提高不同类型旋转摩擦焊缝的接合强度
IF 5
Defence Technology(防务技术) Pub Date : 2025-04-01 DOI: 10.1016/j.dt.2024.12.010
Neeraj Kumar Mishra , S.G.K. Manikandan , Suresh Meshram , Amber Shrivastava
{"title":"Interface geometry modification to trap plasticized flash for improved joint strength of dissimilar rotary friction welds","authors":"Neeraj Kumar Mishra ,&nbsp;S.G.K. Manikandan ,&nbsp;Suresh Meshram ,&nbsp;Amber Shrivastava","doi":"10.1016/j.dt.2024.12.010","DOIUrl":"10.1016/j.dt.2024.12.010","url":null,"abstract":"<div><div>Rotary friction welding is a highly effective solid-state technique for joining dissimilar materials, which offers the potential for significant weight reduction without compromising strength. Traditionally, during rotary friction welding, the severely deformed material, or flash, is expelled from the interface and machined away to achieve the desired joint geometry. However, this work introduces a novel approach: trapping the flash within the joint to improve joint properties. The study investigates two different interface geometry combinations—flat-flat and flat-taper interfaces. Previous research shows that Ni interlayer between steel and titanium can enhance the joint strength. This study builds on the existing knowledge (effect of Ni interlayer) by examining the influence of interface geometry to further improve the dissimilar joint performance. The experimental results, including tensile testing and microstructural characterization, highlight the superior performance of the flat-taper interface. The modified geometry minimizes flash loss, providing a cavity that retains both the flash and the Ni interlayer within the joint. This retention promotes dynamic recrystallization, resulting in refined grain structures near the interface. Moreover, the trapped Ni interlayer effectively prevents the formation of brittle Fe-Ti intermetallic compounds at the dissimilar material interface. The findings reveal that the flat-taper interface improved joint strength by an impressive 105% compared to the flat-flat interface. This innovative geometry modification demonstrates the potential to enhance mechanical properties of dissimilar joints through better flash and interlayer management.</div></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":"46 ","pages":"Pages 71-78"},"PeriodicalIF":5.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143829989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Equivalent force model of deformation induced by oil and gas reservoir development and its volume boundary element method solution 油气藏开发变形等效力模型及其体积边界元法求解
IF 7
Petroleum Exploration and Development Pub Date : 2025-04-01 DOI: 10.1016/S1876-3804(25)60581-7
Xuehao PEI , Yuetian LIU , Liang XUE
{"title":"Equivalent force model of deformation induced by oil and gas reservoir development and its volume boundary element method solution","authors":"Xuehao PEI ,&nbsp;Yuetian LIU ,&nbsp;Liang XUE","doi":"10.1016/S1876-3804(25)60581-7","DOIUrl":"10.1016/S1876-3804(25)60581-7","url":null,"abstract":"<div><div>To address the issue that traditional finite element methods cannot fully consider the semi-infinite earth strata and have lower solution accuracy, a new equivalent force model for induced deformation during oil and gas reservoir development is derived from the perspective of semi-infinite strata. A brand-new volume boundary element numerical method solution has been developed and verified and tested. The influences of internal flow and flow boundary of the reservoir on strata deformation are equivalent to the impacts on strata deformation when external forces act at the interior and boundary of the reservoir, respectively. Calculation methods for the flow equivalent force and boundary equivalent force are provided. The deformation solution at any point in the strata can be obtained through the convolution of flow equivalent forces, boundary equivalent forces and Green's functions. After discretization, the deformation solution at any point in the strata can be obtained by multiplying the grid boundary equivalent forces, grid flow equivalent forces with their corresponding grid boundary sources and grid volume sources respectively, and then summing them up. This numerical method is termed the Volumetric Boundary Element Method (VBEM). Compared with traditional commercial simulators, VBEM fully considers the effects of reservoir flow boundaries, pore pressure gradient fields within the reservoir, and fluid mass changes within pores on formation deformation. It eliminates the need for meshing outside the reservoir, achieves significantly improved solution accuracy, and provides a new technical framework for simulating deformation induced by reservoir development.</div></div>","PeriodicalId":67426,"journal":{"name":"Petroleum Exploration and Development","volume":"52 2","pages":"Pages 485-495"},"PeriodicalIF":7.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143873248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of research on perovskite oxygen carrier for chemical looping reforming of methane 甲烷化学环化重整用钙钛矿氧载体的研究进展
燃料化学学报 Pub Date : 2025-04-01 DOI: 10.1016/S1872-5813(24)60498-6
Jinli REN , Genning ZHANG , Qiuwan SHEN , Xinhai LI , Yanqiu DU , Binjian CHEN , Min YAN
{"title":"A review of research on perovskite oxygen carrier for chemical looping reforming of methane","authors":"Jinli REN ,&nbsp;Genning ZHANG ,&nbsp;Qiuwan SHEN ,&nbsp;Xinhai LI ,&nbsp;Yanqiu DU ,&nbsp;Binjian CHEN ,&nbsp;Min YAN","doi":"10.1016/S1872-5813(24)60498-6","DOIUrl":"10.1016/S1872-5813(24)60498-6","url":null,"abstract":"<div><div>The chemical looping reforming of methane can simultaneously produce synthesis gas and high-purity hydrogen, and efficiently capture CO<sub>2</sub> during the hydrogen production process, which is of great significance for achieving the “dual carbon” goal. The selection of high-performance and low-cost oxygen carriers is crucial for the chemical looping reforming of methane. Due to its abundant oxygen vacancies and good thermal stability, the perovskite oxygen carriers have become a research hotspot as the oxygen carriers required for the chemical looping reforming of methane. In this review, the chemical looping reforming of methane including chemical looping steam methane reforming, chemical looping dry reforming of methane and chemical looping partial oxidation reforming of methane was first introduced. Then, the latest research progress on the Fe based, Ni based and Mn based perovskite type oxygen carriers as well as the supported perovskite oxygen carriers was summarized. Moreover, the pore structure, surface morphology, redox performance, and reaction mechanism of different metal-based perovskite oxygen carriers were analyzed and compared. Finally, the challenges and development prospects faced by perovskite oxygen carriers were summarized.</div></div>","PeriodicalId":15956,"journal":{"name":"燃料化学学报","volume":"53 4","pages":"Pages 419-433"},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of SAPO-35 molecular sieves with different structure-directing agents and their catalytic performance in the conversion of methanol to olefins 不同结构导向剂的SAPO-35分子筛的合成及其催化甲醇制烯烃的性能
燃料化学学报 Pub Date : 2025-04-01 DOI: 10.1016/S1872-5813(24)60488-3
Ni LIANG, Lei KANG, Yujia WANG, Haiyan WANG, Yingzhi BAI, Qiao HAN, Na SUN
{"title":"Synthesis of SAPO-35 molecular sieves with different structure-directing agents and their catalytic performance in the conversion of methanol to olefins","authors":"Ni LIANG,&nbsp;Lei KANG,&nbsp;Yujia WANG,&nbsp;Haiyan WANG,&nbsp;Yingzhi BAI,&nbsp;Qiao HAN,&nbsp;Na SUN","doi":"10.1016/S1872-5813(24)60488-3","DOIUrl":"10.1016/S1872-5813(24)60488-3","url":null,"abstract":"<div><div>A series of SAPO-35 molecular sieves with different SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratios were synthesized by hydrothermal method using hexamethylene imine (HMI) and <em>N</em>-methylpiperidine (NMP) as the structure-directing agent (SDA). The synthesized SAPO-35 molecular sieves were characterized by XRD, SEM, FT-IR, NH<sub>3</sub>-TPD, XRF and N<sub>2</sub> sorption and their catalytic performance in the conversion of methanol to olefins (MTO) was comparatively investigated. The results indicated that the crystallinity and acid density of the SAPO-35 molecular sieves increase first and then decrease with the increase of the SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratio in the initial gel; in particular, the SAPO-35-0.3(HMI) sample with a SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratio of 0.3 displays a high crystallinity, large surface area and suitable acid distribution as a catalyst in MTO. Compared with the SAPO-35-HMI sample synthesized with HMI as SDA, the SAPO-35-NMP sample having the same SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratio but synthesized using new NMP as SDA exhibits much better catalytic stability and higher selectivity to light olefins in MTO; the selectivity to ethene + propene reaches 81.3%, where ethene accounts for more than 50%, far surpassing propene.</div></div>","PeriodicalId":15956,"journal":{"name":"燃料化学学报","volume":"53 4","pages":"Pages 515-526"},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of Fe/SAPO-34 catalyst and its performance in CO hydrogenation to light olefins Fe/SAPO-34催化剂的制备及其CO加氢制轻烯烃的性能
燃料化学学报 Pub Date : 2025-04-01 DOI: 10.1016/S1872-5813(24)60505-0
Liuliu LI , Mingwei ZHANG , Yingjun WANG , Kegong FANG
{"title":"Preparation of Fe/SAPO-34 catalyst and its performance in CO hydrogenation to light olefins","authors":"Liuliu LI ,&nbsp;Mingwei ZHANG ,&nbsp;Yingjun WANG ,&nbsp;Kegong FANG","doi":"10.1016/S1872-5813(24)60505-0","DOIUrl":"10.1016/S1872-5813(24)60505-0","url":null,"abstract":"<div><div>Fischer-Tropsch synthesis is an important route to synthesize light olefins from syngas. However, precise control of the product selectivity and enhancing carbon utilization efficiency remains a challenge. Herein, a series of Fe/SAPO-34 catalysts with different Fe contents were prepared using negative pressure impregnation method, and their performance in CO hydrogenation reaction was evaluated. Combined N<sub>2</sub> adsorption/desorption, XRD, SEM, NH<sub>3</sub>-TPD, and CO-TPD characterizations, the structure-performance relationship of the Fe/SAPO-34 catalysts was clarified. The results showed that with the increase of Fe loading, the strength and quantity of the acidity of the catalysts decreased sequentially, while the CO non-dissociation activation ability was weakened and the CO dissociation activation ability was enhanced, resulting in an increasing and decreasing trend in the selectivity of light olefins and oxygenates, respectively. Under a mild reaction conditions of <em>t</em>=200°C, <em>p</em>=2.0 MPa, GHSV=3300 h<sup>–1</sup>, in the carbon products containing CO<sub>2</sub>, the selectivity of light olefins and oxygenates over 5%Fe/SAPO-34 catalyst was 16.2% and 52.6%, respectively; while that over 25%Fe/SAPO-34 catalyst was 31.9% and 16.9%, respectively. A reasonable reaction mechanism was proposed based on the <em>in situ</em> IR characterization. This study provides a new way for the research and development of catalyst for light olefins synthesis with enhanced carbon utilization efficiency, showing promising application prospects.</div></div>","PeriodicalId":15956,"journal":{"name":"燃料化学学报","volume":"53 4","pages":"Pages 504-514"},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858898","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rapid screening and optimization of CO2 enhanced oil recovery operations in unconventional reservoirs: A case study 非常规油藏CO2提高采收率的快速筛选与优化:一个案例研究
IF 4.2
Petroleum Pub Date : 2025-04-01 DOI: 10.1016/j.petlm.2025.03.001
Shuqin Wen , Bing Wei , Junyu You , Yujiao He , Qihang Ye , Jun Lu
{"title":"Rapid screening and optimization of CO2 enhanced oil recovery operations in unconventional reservoirs: A case study","authors":"Shuqin Wen ,&nbsp;Bing Wei ,&nbsp;Junyu You ,&nbsp;Yujiao He ,&nbsp;Qihang Ye ,&nbsp;Jun Lu","doi":"10.1016/j.petlm.2025.03.001","DOIUrl":"10.1016/j.petlm.2025.03.001","url":null,"abstract":"<div><div>CO<sub>2</sub> injection not only effectively enhances oil recovery (EOR) but also facilitates CO<sub>2</sub> utilization and storage. Rapid screening and optimization of CO<sub>2</sub>-EOR operations is urgently needed for unconventional reservoirs. However, it remains challenging due to a limited understanding of fluid flow in multiscale porous media and the problem complexity invoked by numerous factors. This work developed a new interpretable machine learning (ML) framework to specifically address this issue. Three different methods, namely random forest (RF), support vector regression (SVR), and artificial neural network (ANN), were used to establish proxy models using the data from a specific unconventional reservoir, and the RF model demonstrated a preferable performance. To enhance the interpretability of the established models, the multiway feature importance analysis and Shapley Additive Explanations (SHAP) were proposed to quantify the contribution of individual features to the model output. Based on the results of model interpretability, the genetic algorithm (GA) was coupled with RF (RF-GA model) to optimize the CO<sub>2</sub>-EOR process. The proposed framework was validated by comparing the GA-RF predictions with simulation results under different reservoir conditions, which yielded a minimum relative error of 0.34% and an average relative error of 5.3%. The developed interpretable ML method was capable of rapidly screening suitable CO<sub>2</sub>-EOR strategies based on reservoir conditions and provided a practical example for field applications.</div></div>","PeriodicalId":37433,"journal":{"name":"Petroleum","volume":"11 2","pages":"Pages 188-200"},"PeriodicalIF":4.2,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143883062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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