工业工程最新文献

{"title":"Organophosphate esters in reservoir water from a metropolitan city in the Guangdong-Hong Kong-Macao Greater Bay Area, China, and their ecological risk","authors":"","doi":"10.1016/j.emcon.2024.100412","DOIUrl":"10.1016/j.emcon.2024.100412","url":null,"abstract":"<div><p>Organophosphate esters (OPEs) are emerging flame retardants widely used in products such as furniture, electronic equipment, construction, and plastics. It has been demonstrated that OPEs are harmful to humans and aquatic organisms, thus posing a threat to ecosystems. Considering that reservoirs are critical sources of drinking water for residents in Southern China, this study quantified nine OPEs in water samples collected from 29 reservoirs and their tributaries. The temporal and spatial distributions of OPEs were analyzed and their ecological risks were assessed. The results showed an extensive presence of OPEs in reservoirs, and the median concentration of Σ₉OPEs was much higher in the dry season (65.3 ng/L) than in the wet season (21.3 ng/L). Triisobutyl phosphate (TiBP) (median: 5.24 ng/L) and tris(2-ethylhexyl) phosphate (TEHP) (median: 10.8 ng/L) dominated in the wet and dry seasons, respectively. Other OPEs varied considerably in concentrations over time, related to their physical and chemical properties, environmental factors (e.g., precipitation and temperature), and varied applications. Furthermore, the significant correlations of individual OPEs suggest their shared utilization, emission sources, and environmental behaviors. Spatially, there was no significant difference (<em>P</em> &gt; 0.05) among the Σ₉OPEs concentrations in water samples from different sites (inlet, reservoir, outlet, and tributary) of the reservoirs. Additionally, the concentrations of OPEs in reservoir water samples could be linked to industrial development, economic conditions, and population density. OPEs in the reservoir pose low ecological risks (RQ &lt; 0.1), except for EDHPP and TEHP, which present median ecological risks (RQ = 0.54 and 0.38, respectively). Future studies could investigate more OPEs and their joint effects with other organic pollutants, as well as survey the chemical reactions and degradation pathways of OPEs in different environmental matrices to assess their potential ecotoxicity more comprehensively.</p></div>","PeriodicalId":11539,"journal":{"name":"Emerging Contaminants","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2405665024001136/pdfft?md5=bc998cdda6085abbe8f7e44f6d5f7959&pid=1-s2.0-S2405665024001136-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142229343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Protein hydrogels for biomedical applications","authors":"Xinyi Wang,&nbsp;Yue Hou,&nbsp;Xiong Lu,&nbsp;Chaoming Xie,&nbsp;Yanan Jiang","doi":"10.1049/bsb2.12084","DOIUrl":"https://doi.org/10.1049/bsb2.12084","url":null,"abstract":"<p>Hydrogels, characterised as highly hydrophilic three-dimensional polymer networks, have gained increasing attention due to their unique physicochemical properties, finding applications in various fields. Natural polymer hydrogels exhibit higher biocompatibility and biodegradability compared to traditional synthetic polymer hydrogels. Proteins, being the principal materials of natural polymer hydrogels, bear numerous modifiable functional groups. The resultant hydrogel possesses responsiveness, adjustable degradability, and underway as an excellent biomaterial. Seven common raw materials used to construct protein hydrogels are introduced. In terms of comparing natural polymer hydrogels with traditional synthetic polymer hydrogels, the authors conduct a detailed analysis and comparison, highlighting the advantages of natural polymer hydrogels in terms of biocompatibility and biodegradability, and summarising their characteristics. The authors also address the limitations of various protein hydrogels and list existing strengthening cross-linking strategies, proposing new insights to overcome the application limits of protein hydrogels. Additionally, the applications of protein hydrogels in drug delivery, biosensing, bio-inks and tissue engineering are discussed. The authors conclude by summarising the current challenges faced by protein hydrogels and prospecting its future development.</p>","PeriodicalId":52235,"journal":{"name":"Biosurface and Biotribology","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/bsb2.12084","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142320572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multi-factor coupled forest fire model based on cellular automata","authors":"","doi":"10.1016/j.jnlssr.2024.06.002","DOIUrl":"10.1016/j.jnlssr.2024.06.002","url":null,"abstract":"<div><p>The risk of forest fires is substantial due to uneven precipitation distributions and abnormal climate change. This study employs cellular automata principles to analyze forest fire behavior, taking into account meteorological elements, combustible material types, and terrain slopes. The Wang Zhengfei model is utilized to compute fire spread speed, and a multifactor coupled forest fire model is developed. Comparisons with experimental data show a mean calculated fire spread speed of 0.69 m/min, which is consistent with the experimental results. Using the forest fire in Anning city, Yunnan Province, as a case study with a mean burned area of 2281 ha, the burned area, rate of change in burned area, and burning area demonstrated an increasing trend, with fluctuating states in the rate of change of the burning area. Employing the controlled variable method to examine forest fire spreading patterns under varying factors such as wind speed, vegetation type, and maximum slope reveals that under wind influence, the fire site adopts an elliptical shape with the downwind direction as the major axis. Quantitatively, when the wind speed increases from 2 m/s to 10 m/s, the burned area expands by a factor of 1.37. The ratio of the combustible material configuration coefficient to the burned area remains consistent across the different vegetation types, and the burned area increases by a factor of 1.92 when the maximum slope increases from 5° to 25°.</p></div>","PeriodicalId":62710,"journal":{"name":"安全科学与韧性(英文)","volume":null,"pages":null},"PeriodicalIF":3.7,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666449624000422/pdfft?md5=258753683f3aa032bf0211fc586ac4f6&pid=1-s2.0-S2666449624000422-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142149343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Flow field characteristics and drag reduction performance of high–low velocity stripes on the biomimetic imbricated fish scale surfaces","authors":"Dengke Chen,&nbsp;XianXian Cui,&nbsp;Huawei Chen","doi":"10.1049/bsb2.12083","DOIUrl":"https://doi.org/10.1049/bsb2.12083","url":null,"abstract":"<p>Improving energy efficiency and cost reduction is a perennial challenge in engineering. Natural biological systems have evolved unique functional surfaces or special physiological functions over centuries to adapt to their complex environments. Among these biological wonders, fish, one of the oldest vertebrate groups, has garnered significant attention due to its exceptional fluid dynamics capabilities. Researchers are actively exploring the potential of fish skin's distinctive structural and material characteristics in reducing resistance. In this study, models of biomimetic imbricated fish scale are established, and the evolution characteristics of the flow field and drag reduction performance on these bionic surfaces are investigated. The results showed a close relationship between the high–low velocity stripes generated and the fluid motion by the imbricated fish scale surface. The stripes' prominence increases with the spacing of the adjacent scales and tilt angle of the fish scale, and the velocity amplitude of the stripes decreases as the exposed length of the imbricated fish scale surface increases. Moreover, the biomimetic imbricated fish scale surface can decrease the velocity gradient and thereby reduce the wall shear stress. The insights gained from the fish skin-inspired imbricated fish surface provide valuable perspectives for an in-depth analysis of fish hydrodynamics and offer fresh inspiration for drag reduction and antifouling strategies in engineering applications.</p>","PeriodicalId":52235,"journal":{"name":"Biosurface and Biotribology","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/bsb2.12083","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142320715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The sound heritage of Kotagede: the evolving soundscape of a living museum","authors":"Christina E. Mediastika, Anugrah S. Sudarsono, Sentagi S. Utami, Teguh Setiawan, James G. Mansell, Revianto B. Santosa, Army Wiratama, Ressy J. Yanti, Laurence Cliffe","doi":"10.1186/s43238-024-00145-0","DOIUrl":"https://doi.org/10.1186/s43238-024-00145-0","url":null,"abstract":"Kotagede, the capital of the ancient Mataram Kingdom and currently an area in the Yogyakarta Province of Indonesia, is known as a ‘real living museum’. It was previously a residential area with many vital premises and heritage buildings that became a tourist area. Its locally established activities enrich the visual and sound environment of the vicinity. However, it has gradually lost its distinguishing sounds. A series of studies aims to improve the possibility of restoring past soundmarks to preserve the intangible heritage and make living museums as rich as possible. This paper reports the initial stage of the series, which focuses on capturing the rich historical sounds of Kotagede. The study was carefully designed to collect comprehensive data on heritage sounds using qualitative methods consisting of an initial focus group discussion (FGD), in-depth interviews, and a final FGD. These methods resulted in a large amount of data that were processed and classified using the descriptive phenomenology approach with the Colaizzi protocol. The study found that Kotagede has various soundmarks grouped into local and outside sounds. The locally rooted sounds can be grouped into eight categories, some of which can be extended as past and present sounds and a few that have persisted from the past to the present. In the subsequent stage, this classification and local leaders' concerns helped the researchers select and prioritise sounds for preservation and tourism purposes. The study emphasises the importance of choosing suitable participants to provide detailed and comprehensive information.","PeriodicalId":33925,"journal":{"name":"Built Heritage","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142199565","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biosynthesis of Diverse Ephedra-Type Alkaloids via a Newly Identified Enzymatic Cascade.","authors":"Peiling Wu, Ding Luo, Yuezhou Wang, Xiaoxu Shang, Binju Wang, Xianming Deng, Jifeng Yuan","doi":"10.34133/bdr.0048","DOIUrl":"10.34133/bdr.0048","url":null,"abstract":"<p><p>Ephedra-type alkaloids represent a large class of natural and synthetic phenylpropanolamine molecules with great pharmaceutical values. However, the existing methods typically rely on chemical approaches to diversify the <i>N</i>-group modification of Ephedra-type alkaloids. Herein, we report a 2-step enzymatic assembly line for creating structurally diverse Ephedra-type alkaloids to replace the conventional chemical modification steps. We first identified a new carboligase from <i>Bacillus subtilis</i> (<i>Bs</i>AlsS, acetolactate synthase) as a robust catalyst to yield different phenylacetylcarbinol (PAC) analogs from diverse aromatic aldehydes with near 100% conversions. Subsequently, we screened imine reductases (IREDs) for the reductive amination of PAC analogs. It was found that IRG02 from <i>Streptomyces albidoflavus</i> had good activities with conversions ranging from 37% to 84% for the reductive alkylamination with diverse amine partners such as allylamine, propargylamine, and cyclopropylamine. Overall, 3 new bio-modifications at the <i>N</i>-group of Ephedra-type alkaloids were established. Taken together, our work lays a foundation for the future implementation of biocatalysis for synthesizing structurally diverse Ephedra-type alkaloids with potential new pharmaceutical applications.</p>","PeriodicalId":56832,"journal":{"name":"生物设计研究(英文)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11371322/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142127504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Characterisation and tanning effects of purified chestnut and sulfited quebracho extracts","authors":"Silvia Conca,&nbsp;Vanessa Gatto,&nbsp;Riccardo Samiolo,&nbsp;Samuele Giovando,&nbsp;Andrea Cassani,&nbsp;Elisa Tarabra,&nbsp;Valentina Beghetto","doi":"10.1186/s42825-024-00171-9","DOIUrl":"10.1186/s42825-024-00171-9","url":null,"abstract":"<div><p>Vegetable tannins are environmentally friendly tanning agents. However, they generally impart a dark colour to the tanned leather and highly contribute to the organic load in wastewaters. In this study, we employed a purification protocol separately on chestnut tannin (CT) and sulfited quebracho tannin (QT) to obtain the purified fractions (PCT and PQT). These samples were characterised by GPC, ¹H NMR, ¹³C NMR, FT-IR, and HPLC–DAD techniques and applied for tanning tests. Through the purification process, non-tannin components and smaller molecules such as gallic acid, glucopyranose, and catechin were effectively removed from CT and QT, which consequently led to the reduced moisture content, pH value, and lighter colour of purified fractions. The crust leathers processed with PCT and PQT showed desirable light shades. Moreover, the organic loads in PCT and PQT tanning wastewater were reduced by 13.5% and 19.1%, respectively, when compared to those in traditional CT and QT tanning wastewater. Additionally, the physical and mechanical characteristics of crust leathers processed with PCT and PQT were comparable to those processed with CT and QT. Thus, purification of vegetable tannins may serve as a feasible strategy for producing light-colored vegetable-tanned leather while minimizing organic pollutant discharge during the vegetable tanning process.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":640,"journal":{"name":"Journal of Leather Science and Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://JLSE.SpringerOpen.com/counter/pdf/10.1186/s42825-024-00171-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142117930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Valorization of wheat bran arabinoxylan: A review on nutritional and materials perspectives","authors":"","doi":"10.1016/j.gaost.2024.05.006","DOIUrl":"10.1016/j.gaost.2024.05.006","url":null,"abstract":"<div><p>Wheat bran, a principal byproduct of flour milling, stands as an abundant source of dietary fiber, yet its economic potential remains under-exploited in current forage applications. Arabinoxylan (AX), constituting the core of dietary fiber, emerges as a versatile compound with multifaceted functionalities. Its nutritional significance, coupled with its role in cereal food processing, has prompted a surge of studies focusing on the valorization of wheat bran AX. Moreover, the hydrolyzed derivative, arabinoxylan oligosaccharides (AXOS), demonstrates prebiotic and antioxidant properties, offering potential avenues to mitigate the risk of chronic diseases. This review summarizes current knowledge on the valorization of wheat bran AX in terms of the processing and nutritional properties of AX. Moreover, multiple novel applications of AX in the materials area, including biodegradable food packaging films, delivery of bioactive substances as nanoparticles, and the manufacture of food emulsifiers, are also highlighted to extend the utilization of AX. This review underscores the immense potential of wheat bran AX, advocating for its exploitation not only as a nutritional asset but also as a primary ingredient in advanced materials. The synthesis of nutritional and materials perspectives accentuates the multifaceted utility of wheat bran AX, thereby paving the way for sustainable valorization pathways. By unraveling the latent potential within AX, this paper advocates for the holistic and sustainable utilization of wheat bran in diverse, value-added applications.</p></div>","PeriodicalId":33614,"journal":{"name":"Grain Oil Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590259824000384/pdfft?md5=9cbaf6391897c0a500e8324968141a8f&pid=1-s2.0-S2590259824000384-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141235352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigating the coking performance of ethylene residue pitch components","authors":"","doi":"10.1016/S1872-5813(24)60453-4","DOIUrl":"10.1016/S1872-5813(24)60453-4","url":null,"abstract":"<div><p>Ethylene residue pitch (ETP, the heavy component in ethylene residue tar) is widely used as a preferred raw material for preparing petroleum-based artificial carbon materials characterized by high carbon content, high aromaticity, and low heteroatom (S, N) content. To investigate the coking properties of ETP, eight components of ETP (four soluble and four insoluble components) were obtained via extraction and separation using methanol, <em>n</em>-butanol, <em>n</em>-hexane, and dimethyl sulfoxide as solvents. The thermal conversion (temperature = 500 °C) and carbonization treatment (temperature =1400 °C) were carried out on each pitch component. The basic physical properties of ETP components were observed using infrared spectroscopy, thermogravimetric analysis, and ¹H-NMR. The microstructure of the petroleum-based pitch coke was studied using polarizing microscopy, X-ray single crystal diffraction (XRD), Raman spectroscopy, and scanning electron microscopy. The aromaticity of the insoluble components in ETP was slightly higher than that of soluble components, and the insoluble components had slightly fewer branching chains than those in soluble components. The microstrength of the ETP coke obtained using insoluble components was higher than that obtained using soluble components, and the true density of ETP coke HS-C was as high as 2.0554 g/cm³.</p></div>","PeriodicalId":15956,"journal":{"name":"燃料化学学报","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142164372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Machine learning optimization strategy of shaped charge liner structure based on jet penetration efficiency","authors":"","doi":"10.1016/j.dt.2024.04.006","DOIUrl":"10.1016/j.dt.2024.04.006","url":null,"abstract":"<div><p>Shaped charge liner (SCL) has been extensively applied in oil recovery and defense industries. Achieving superior penetration capability through optimizing SCL structures presents a substantial challenge due to intricate rate-dependent processes involving detonation-driven liner collapse, high-speed jet stretching, and penetration. This study introduces an innovative optimization strategy for SCL structures that employs jet penetration efficiency as the primary objective function. The strategy combines experimentally validated finite element method with machine learning (FEM-ML). We propose a novel jet penetration efficiency index derived from enhanced cutoff velocity and shape characteristics of the jet via machine learning. This index effectively evaluates the jet penetration performance. Furthermore, a multi-model fusion based on a machine learning optimization method, called XGBOOST-MFO, is put forward to optimize SCL structure over a large input space. The strategy's feasibility is demonstrated through the optimization of copper SCL implemented via the FEM-ML strategy. Finally, this strategy is extended to optimize the structure of the recently emerging CrMnFeCoNi high-entropy alloy conical liners and hemispherical copper liners. Therefore, the strategy can provide helpful guidance for the engineering design of SCL.</p></div>","PeriodicalId":58209,"journal":{"name":"Defence Technology(防务技术)","volume":null,"pages":null},"PeriodicalIF":5.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2214914724000837/pdfft?md5=922e9726df71f2cf513f373554beed0f&pid=1-s2.0-S2214914724000837-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140833493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}