Hai-xin Shang , Jun-qiang Xia , Chun-hong Hu , Mei-rong Zhou , Shan-shan Deng
{"title":"Quantification of backwater effect in Jingjiang Reach due to confluence with Dongting Lake using a machine learning model","authors":"Hai-xin Shang , Jun-qiang Xia , Chun-hong Hu , Mei-rong Zhou , Shan-shan Deng","doi":"10.1016/j.wse.2025.02.002","DOIUrl":"10.1016/j.wse.2025.02.002","url":null,"abstract":"<div><div>The backwater effect caused by tributary inflow can significantly elevate the water level profile upstream of a confluence point. However, the influence of mainstream and confluence discharges on the backwater effect in a river reach remains unclear. In this study, various hydrological data collected from the Jingjiang Reach of the Yangtze River in China were statistically analyzed to determine the backwater degree and range with three representative mainstream discharges. The results indicated that the backwater degree increased with mainstream discharge, and a positive relationship was observed between the runoff ratio and backwater degree at specific representative mainstream discharges. Following the operation of the Three Gorges Project, the backwater effect in the Jingjiang Reach diminished. For instance, mean backwater degrees for low, moderate, and high mainstream discharges were recorded as 0.83 m, 1.61 m, and 2.41 m during the period from 1990 to 2002, whereas these values decreased to 0.30 m, 0.95 m, and 2.08 m from 2009 to 2020. The backwater range extended upstream as mainstream discharge increased from 7 000 m<sup>3</sup>/s to 30 000 m<sup>3</sup>/s. Moreover, a random forest-based machine learning model was used to quantify the backwater effect with varying mainstream and confluence discharges, accounting for the impacts of mainstream discharge, confluence discharge, and channel degradation in the Jingjiang Reach. At the Jianli Hydrological Station, a decrease in mainstream discharge during flood seasons resulted in a 7%–15% increase in monthly mean backwater degree, while an increase in mainstream discharge during dry seasons led to a 1%–15% decrease in monthly mean backwater degree. Furthermore, increasing confluence discharge from Dongting Lake during June to July and September to November resulted in an 11%–42% increase in monthly mean backwater degree. Continuous channel degradation in the Jingjiang Reach contributed to a 6%–19% decrease in monthly mean backwater degree. Under the influence of these factors, the monthly mean backwater degree in 2017 varied from a decrease of 53% to an increase of 37% compared to corresponding values in 1991.</div></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"18 2","pages":"Pages 187-199"},"PeriodicalIF":3.7,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144178470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
燃料化学学报Pub Date : 2025-06-01DOI: 10.1016/S1872-5813(24)60512-8
Yuan LI , Yisong ZHENG , Hao WANG , Honghao WANG , Caishun ZHANG , Shaozheng HU , Jiao HAN , Lei ZHANG , Zhixian GAO
{"title":"The reactivity of CO with different lattice oxygens on Cu doped CeO2(111): A DFT study","authors":"Yuan LI , Yisong ZHENG , Hao WANG , Honghao WANG , Caishun ZHANG , Shaozheng HU , Jiao HAN , Lei ZHANG , Zhixian GAO","doi":"10.1016/S1872-5813(24)60512-8","DOIUrl":"10.1016/S1872-5813(24)60512-8","url":null,"abstract":"<div><div>The adsorption of CO on different lattice oxygen sites in Cu doped CeO<sub>2</sub>(111) was studied by DFT method, and the geometrical structure and electronic properties of adsorption systems were analyzed. The results showed that CO interacted with lattice oxygen on the first layer formed CO<sub>2</sub>. However, when adsorbed on the second layer lattice oxygen, carbonate species were formed with the participation of first layer lattice oxygens, i.e., CO co-adsorbed on first and second layer lattice oxygens. For the second layer adsorption, the absolute CO adsorption energy was big on the Oss nearby Cu. This kind of carbonates was thermodynamically stable, and it was attributed to the facilitation of Cu on CO adsorption, manifested by an electron migration behavior from the C 2<em>p</em> orbitals to the Cu 3<em>d</em> orbitals. However, the absolute CO adsorption energy on the Oss away from Cu was small. Compared to the formation of carbonates, the formation CO<sub>2</sub> had very small absolute adsorption energy, suggesting the formed carbonates on second layer was stable. Further, when CO adsorbed on the systems with a carbonate, the absolute CO adsorption energy was significantly smaller than that of the non-carbonated system, indicating that the formation of carbonates inhibited CO oxidation on Cu/CeO<sub>2</sub>(111). Therefore, the formation of carbonates was unfavorable for CO oxidation reaction on Cu/CeO<sub>2</sub>(111). The results of this study provide theoretical support for the negative effect of CO<sub>2</sub> on ceria-based catalysts.</div></div>","PeriodicalId":15956,"journal":{"name":"燃料化学学报","volume":"53 6","pages":"Pages 906-917"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144331443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kingsley Safo , Norbert Onen Rubangakene , Hussien Noby , Ahmed H. El-Shazly
{"title":"Photocatalytic purification of dye-containing wastewater using a novel embedded hybrid TiO2–slag catalyst heterojunction nanocomposite coupled with statistical models: A sustainable and techno-economic approach","authors":"Kingsley Safo , Norbert Onen Rubangakene , Hussien Noby , Ahmed H. El-Shazly","doi":"10.1016/j.wse.2025.02.003","DOIUrl":"10.1016/j.wse.2025.02.003","url":null,"abstract":"<div><div>The steel industry produces many byproducts, requiring extensive land for storage and causing significant environmental contamination. Industrial effluents discharged into water bodies negatively impact both aquatic ecosystems and human health. To solve this problem, this study synthesized a composite of titanium dioxide (TiO<sub>2</sub>) and steel slag nanocomposites (SSNC) at a 1:2 mass ratio to create a robust photocatalyst for the treatment of synthetic wastewater. The efficacy of this catalyst in degrading various dye pollutants, including methylene blue (MB), was tested under simulated solar light conditions. Comprehensive analyses were conducted to assess the physical and chemical characteristics, crystalline structure, energy gap, and point of zero charge of the composite. The TiO<sub>2</sub>-SSNC composite catalyst exhibited excellent stability, with a point of zero charge at 8.342 and an energy gap of 2.4 eV. The degradation process conformed to pseudo-first-order kinetics. Optimization of operational parameters was achieved through the response surface methodology. Reusability tests demonstrated that the TiO<sub>2</sub>-SSNC composite catalyst effectively degraded up to 93.41% of MB in the suspended mode and 92.03% in the coated mode after five cycles. Additionally, the degradation efficiencies for various dyes were significant, highlighting the potential of the composite for broad applications in industrial wastewater treatment. This study also explored the degradation mechanisms and identified byproducts, establishing a pathway for contaminant breakdown. The cost-benefit analysis revealed a total cost of 0.842 8 USD per cubic meter for each treatment activity, indicating low operational and production costs. These findings underscore the promise of the TiO<sub>2</sub>-SSNC composite as a cost-effective and efficient alternative for wastewater purification.</div></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"18 2","pages":"Pages 151-164"},"PeriodicalIF":3.7,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144178397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sin Ling Chiam , Swee-Yong Pung , Chee Meng Koe , Fei Yee Yeoh
{"title":"Immobilization of MnO2 nanoflowers on coils using direct heating method for organic pollutant remediation","authors":"Sin Ling Chiam , Swee-Yong Pung , Chee Meng Koe , Fei Yee Yeoh","doi":"10.1016/j.wse.2024.09.001","DOIUrl":"10.1016/j.wse.2024.09.001","url":null,"abstract":"<div><div>The immobilization of catalysts on supporting substrates for the removal of organic pollutants is a crucial strategy for mitigating catalyst loss during wastewater treatment. This study presented a rapid and cost-effective direct heating method for synthesizing MnO<sub>2</sub> nanoflowers on coil substrates for the removal of organic pollutants. Traditional methods often require high power, expensive equipment, and long synthesis times. In contrast, the direct heating approach successfully synthesized MnO<sub>2</sub> nanoflowers in just 10 min with a heating power of approximately 40 W·h after the heating power and duration were optimized. These nanoflowers effectively degraded 99% Rhodamine B in 60 min with consistent repeatability. The catalytic mechanisms are attributed to crystal defects in MnO<sub>2</sub>, which generate electrons to produce H<sub>2</sub>O<sub>2</sub>. Mn<sup>2+</sup> ions in the acidic solution further dissociate H<sub>2</sub>O<sub>2</sub> molecules into hydroxyl radicals (·OH). The high efficiency of this synthesis method and the excellent reusability of MnO<sub>2</sub> nanoflowers highlight their potential as a promising solution for the development of supporting MnO<sub>2</sub> catalysts for organic dye removal applications.</div></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"18 2","pages":"Pages 165-176"},"PeriodicalIF":3.7,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144178398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigation of structural features of asphaltenes used for carbon materials synthesis by arc plasma treatment","authors":"Andrey Grinko , Evgenia Leushina , Yuliya Petrova , Pavel Povalyaev , Alexander Pak , Arina Goncharova , Vasily Kaichev , Valentina Egorova , Kirill Cherednichenko , Dmitry Zelentsov , Tatiana Cheshkova","doi":"10.1016/j.ptlrs.2024.10.003","DOIUrl":"10.1016/j.ptlrs.2024.10.003","url":null,"abstract":"<div><div>This study presents analysis of asphaltenes isolated from two crude oils: naphthenic-aromatic biodegraded oil and paraffin-naphthenic oil, which have been used as precursors for carbon materials synthesis. The aim of this study is to investigate the interrelationship between the initial structure of asphaltene and the properties of carbon materials. Based on number of spectroscopic and other data, it can be found out that the asphaltenes from napthenic-aromatic biodegraded oil contain less paraffin and more cyclic fragments (aromatic and aliphatic), that are larger and more densely stacked. The asphaltenes of paraffin-naphthenic oil contain a larger number of labile bonds and heteroatoms. Both the asphaltenes contain sulfur enclosed in thiophene and sulfide fragments, nitrogen and oxygen, which are incorporated in different units with different thermal stability. Carbon materials are obtained from both asphaltenes via plasma of an electric arc discharge. The asphaltenes undergo graphitization as a result of plasma treatment, the general trend is an elimination of functional groups and N, S, O. The yields of the carbon materials are almost equal for two studied asphaltenes, giving graphite-like materials as the major product in both cases. The carbon material obtained from the napthenic-aromatic asphaltenes is less thermally stable, the yield of nano-structures and nanofibers are higher compared to the asphaltenes from paraffinic oil, with trace metals remaining during the synthesis process. The carbon material from paraffin-naphthenic oil is amorphous with low heteroatoms content.</div></div>","PeriodicalId":19756,"journal":{"name":"Petroleum Research","volume":"10 2","pages":"Pages 352-369"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144314512","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qingxiu Zeng , Peng Sun , Xingchao Jiang , Heng Zhang , Qifei Fang , Lei Jiang
{"title":"Early oil charging from Sinian shales in Ordovician carbonates of the Tabei Uplift, Tarim Basin: Evidence from biomarkers","authors":"Qingxiu Zeng , Peng Sun , Xingchao Jiang , Heng Zhang , Qifei Fang , Lei Jiang","doi":"10.1016/j.ptlrs.2024.11.001","DOIUrl":"10.1016/j.ptlrs.2024.11.001","url":null,"abstract":"<div><div>Despite over 40 years of exploration focusing on the deep to ultra-deep Ordovician carbonates as major hydrocarbon targets in the Tarim Basin, the identification of their source rocks remains elusive. Based on biomarkers, carbon and sulfur isotopes of hydrocarbons, the primary source for the Ordovician petroleum system has been attributed mainly to the lower Cambrian shales, although some oils were likely contributed from the Lower Ordovician source rocks. However, the current understanding of the evolution of the Ordovician petroleum system remains rudimentary, largely due to the complex interplay of multi-source (i.e., the widespread Precambrian shales) hydrocarbon inputs, diagenetic alterations, and tectonic processes over geological time. This study systematically investigates the molecular geochemistry of reservoir bitumen within the Ordovician carbonates from Tabei uplift, coupled with bitumen from the Sinian units at the western edge of the Tarim Basin. Our results indicate that the ion chromatography-mass spectrometry spectra and the saturated to aromatic hydrocarbons ratio of Ordovician reservoir bitumen closely resemble those of Sinian bitumen, as well as the published data of Sinian shales. This coupling linkage is revealed by cross-plots and ternary phase diagrams of various biomarker parameters, which can effectively distinguish the Sinian sources from other sources, i.e., the Lower Cambrian and Ordovician, for the Ordovician reservoir bitumen. Specifically, the ∑n-C<sub>21</sub><sup>-</sup>/∑n-C<sub>22</sub><sup>+</sup>, Pr/Ph, G/C<sub>31</sub>H22S, C<sub>23</sub>/C<sub>21</sub>TT ratios are effective indexes to differentiate these source rocks. By compiling the published organic geochemistry data of oils, it appears to infer that approximately 8.1% of the present-day oils produced from the Ordovician carbonates likely contain some proportion of Sinian-sourced oils. The recognition of Sinian sourced oils contributing to the paleo- and present-day Ordovician petroleum system offers valuable insights for the exploration of deep-ultra deep carbonates in the Tarim Basin, emphasizing the need to consider Precambrian shales as a significant hydrocarbon source.</div></div>","PeriodicalId":19756,"journal":{"name":"Petroleum Research","volume":"10 2","pages":"Pages 234-246"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144314627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"High-resolution sequence stratigraphy of the Ponta do Mel Formation, Potiguar Basin, Brazil: Insights into shallow-marine carbonate reservoir zonation and characterisation","authors":"A.J.C. Magalhães , A.H. Melo , G.J.S. Terra , D.G.C. Fragoso , U.M. Soares , F.P. Lima-Filho","doi":"10.1016/j.ptlrs.2024.12.002","DOIUrl":"10.1016/j.ptlrs.2024.12.002","url":null,"abstract":"<div><div>This comprehensive study establishes a novel high-resolution sequence stratigraphic framework for a shallow, warm, land-tied carbonate-rimmed shelf represented by the Ponta do Mel Formation. Integration of cores and cuttings with seismic and well-log data provides the detailed subsurface stratigraphic framework encompassing two fourth-order genetic sequences. The high-resolution approach unveiled the step-by-step depositional and diagenetic evolution of the Ponta do Mel Formation at the fourth-order systems tracts scale and established the reservoir zonation. In each zone, the lateral contact between high-energy outer shelf and shelf rim potential reservoirs and low-energy inner shelf deposits constitutes critical reservoir heterogeneities that may affect production planning and development projects. Moreover, the reservoir scale enabled discussion on the controls on deposition, high-resolution sequence architecture, diagenesis, and insight into the zonation and characterisation of similar oil and gas reservoirs worldwide.</div></div>","PeriodicalId":19756,"journal":{"name":"Petroleum Research","volume":"10 2","pages":"Pages 304-319"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144314641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Oleg V. Anikin, Vadim K. Derevyanko, Alexander V. Bolotov, Ilgiz F. Minkhanov, Mikhail A. Varfolomeev, Emilia A. Konstantinovich, Valeria A. Kadysheva
{"title":"Gas enhanced oil recovery methods for offshore oilfields: Features, implementation, operational status","authors":"Oleg V. Anikin, Vadim K. Derevyanko, Alexander V. Bolotov, Ilgiz F. Minkhanov, Mikhail A. Varfolomeev, Emilia A. Konstantinovich, Valeria A. Kadysheva","doi":"10.1016/j.ptlrs.2024.12.003","DOIUrl":"10.1016/j.ptlrs.2024.12.003","url":null,"abstract":"<div><div>Nowadays, enhanced oil recovery (EOR) methods have been evaluated both for onshore and offshore oilfields. However, the conditions for using EOR methods in offshore fields are more complex due to the unique features of the infrastructure, transportation facilities and geological conditions. The experience gained from offshore gas EOR (gEOR) pilot projects has shown effective methods for increasing oil production at a later stage of field development. The technical knowledge base gained has been analyzed in this paper, which includes an analysis of the advantages and disadvantages of offshore projects and operational experience with gas and water-gas flooding in offshore environments. A history of implemented EOR projects in offshore oil fields from 1970 to the present and an evaluation of the application of different injection methods with hydrocarbon gas, CO<sub>2</sub> and nitrogen is presented sequentially.</div></div>","PeriodicalId":19756,"journal":{"name":"Petroleum Research","volume":"10 2","pages":"Pages 404-415"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144314515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
燃料化学学报Pub Date : 2025-06-01DOI: 10.1016/S1872-5813(25)60538-X
Yuhua WANG , Hongguang LI , Liang DING , Yongli KOU , Wenbo QI , Ning ZHAO
{"title":"Research progress of catalysts for synthesis of glycerol carbonate form glycerol and urea","authors":"Yuhua WANG , Hongguang LI , Liang DING , Yongli KOU , Wenbo QI , Ning ZHAO","doi":"10.1016/S1872-5813(25)60538-X","DOIUrl":"10.1016/S1872-5813(25)60538-X","url":null,"abstract":"<div><div>Transformation of urea and glycerol to glycerol carbonate is an environmental friendly and economical process. Catalysts play an indispensable role in the process. Although many catalysts have been developed, the performance of the catalysts still cannot meet the needs of industrialization. In this paper, research progress of the homogeneous and heterogeneous catalysts of the reaction over the past 20 years were reviewed systematically. According to the types and active centers of catalysts, the catalysts were classified systematically and analyzed in detail. The typical reaction mechanisms were also summarized. The research and development direction of catalysts is made more explicit through systematic classification and mechanism analysis. The article reveals more novel catalysts have been designed and used for the reaction, such as mixed metal oxides with special structures, solid wastes and non-metallic materials. This work summarized the current state of research and prospected possible routes for design of novel catalysts. It is hoped that this review can provide some references for developing efficient catalysts.</div></div>","PeriodicalId":15956,"journal":{"name":"燃料化学学报","volume":"53 6","pages":"Pages 964-982"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144330786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}