Pub Date : 2024-09-14 DOI: 10.1007/s11424-024-4048-5

Wenqiang Yang, Wenyuan Wu, Greg Reid

引用次数: 0

Lanthanide ion-doped upconversion nanoparticles for low-energy super-resolution applications 用于低能超分辨率应用的掺镧离子上转换纳米粒子

3区医学

ACS Medicinal Chemistry Letters Pub Date : 2024-09-14 DOI: 10.1038/s41377-024-01547-6

Simone Lamon, Haoyi Yu, Qiming Zhang, Min Gu

{"title":"Lanthanide ion-doped upconversion nanoparticles for low-energy super-resolution applications","authors":"Simone Lamon, Haoyi Yu, Qiming Zhang, Min Gu","doi":"10.1038/s41377-024-01547-6","DOIUrl":"https://doi.org/10.1038/s41377-024-01547-6","url":null,"abstract":"Energy-intensive technologies and high-precision research require energy-efficient techniques and materials. Lens-based optical microscopy technology is useful for low-energy applications in the life sciences and other fields of technology, but standard techniques cannot achieve applications at the nanoscale because of light diffraction. Far-field super-resolution techniques have broken beyond the light diffraction limit, enabling 3D applications down to the molecular scale and striving to reduce energy use. Typically targeted super-resolution techniques have achieved high resolution, but the high light intensity needed to outperform competing optical transitions in nanomaterials may result in photo-damage and high energy consumption. Great efforts have been made in the development of nanomaterials to improve the resolution and efficiency of these techniques toward low-energy super-resolution applications. Lanthanide ion-doped upconversion nanoparticles that exhibit multiple long-lived excited energy states and emit upconversion luminescence have enabled the development of targeted super-resolution techniques that need low-intensity light. The use of lanthanide ion-doped upconversion nanoparticles in these techniques for emerging low-energy super-resolution applications will have a significant impact on life sciences and other areas of technology. In this review, we describe the dynamics of lanthanide ion-doped upconversion nanoparticles for super-resolution under low-intensity light and their use in targeted super-resolution techniques. We highlight low-energy super-resolution applications of lanthanide ion-doped upconversion nanoparticles, as well as the related research directions and challenges. Our aim is to analyze targeted super-resolution techniques using lanthanide ion-doped upconversion nanoparticles, emphasizing fundamental mechanisms governing transitions in lanthanide ions to surpass the diffraction limit with low-intensity light, and exploring their implications for low-energy nanoscale applications.","PeriodicalId":20,"journal":{"name":"ACS Medicinal Chemistry Letters","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142231520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments 用于明亮环境中先进光存储应用的深阱紫外线持久荧光粉

3区医学

ACS Medicinal Chemistry Letters Pub Date : 2024-09-14 DOI: 10.1038/s41377-024-01533-y

Xulong Lv, Yanjie Liang, Yi Zhang, Dongxun Chen, Xihui Shan, Xiao-Jun Wang

{"title":"Deep-trap ultraviolet persistent phosphor for advanced optical storage application in bright environments","authors":"Xulong Lv, Yanjie Liang, Yi Zhang, Dongxun Chen, Xihui Shan, Xiao-Jun Wang","doi":"10.1038/s41377-024-01533-y","DOIUrl":"https://doi.org/10.1038/s41377-024-01533-y","url":null,"abstract":"Extensive research has been conducted on visible-light and longer-wavelength infrared-light storage phosphors, which are utilized as promising rewritable memory media for optical information storage applications in dark environments. However, storage phosphors emitting in the deep ultraviolet spectral region (200–300 nm) are relatively lacking. Here, we report an appealing deep-trap ultraviolet storage phosphor, ScBO3:Bi3+, which exhibits an ultra-narrowband light emission centered at 299 nm with a full width at half maximum (FWHM) of 0.21 eV and excellent X-ray energy storage capabilities. When persistently stimulated by longer-wavelength white/NIR light or heated at elevated temperatures, ScBO3:Bi3+ phosphor exhibits intense and long-lasting ultraviolet luminescence due to the interplay between defect levels and external stimulus, while the natural decay in the dark at room temperature is extremely weak after X-ray irradiation. The impact of the spectral distribution and illuminance of ambient light and ambient temperature on ultraviolet light emission has been studied by comprehensive experimental and theoretical investigations, which elucidate that both O vacancy and Sc interstitial serve as deep electron traps for enhanced and prolonged ultraviolet luminescence upon continuous optical or thermal stimulation. Based on the unique spectral features and trap distribution in ScBO3:Bi3+ phosphor, controllable optical information read-out is demonstrated via external light or heat manipulation, highlighting the great potential of ScBO3:Bi3+ phosphor for advanced optical storage application in bright environments.","PeriodicalId":20,"journal":{"name":"ACS Medicinal Chemistry Letters","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142231522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Spatio-temporal breather dynamics in microcomb soliton crystals 微梳状孤子晶体中的时空呼吸动力学

3区医学

ACS Medicinal Chemistry Letters Pub Date : 2024-09-12 DOI: 10.1038/s41377-024-01573-4

Futai Hu, Abhinav Kumar Vinod, Wenting Wang, Hsiao-Hsuan Chin, James F. McMillan, Ziyu Zhan, Yuan Meng, Mali Gong, Chee Wei Wong

{"title":"Spatio-temporal breather dynamics in microcomb soliton crystals","authors":"Futai Hu, Abhinav Kumar Vinod, Wenting Wang, Hsiao-Hsuan Chin, James F. McMillan, Ziyu Zhan, Yuan Meng, Mali Gong, Chee Wei Wong","doi":"10.1038/s41377-024-01573-4","DOIUrl":"https://doi.org/10.1038/s41377-024-01573-4","url":null,"abstract":"Solitons, the distinct balance between nonlinearity and dispersion, provide a route toward ultrafast electromagnetic pulse shaping, high-harmonic generation, real-time image processing, and RF photonic communications. Here we uniquely explore and observe the spatio-temporal breather dynamics of optical soliton crystals in frequency microcombs, examining spatial breathers, chaos transitions, and dynamical deterministic switching – in nonlinear measurements and theory. To understand the breather solitons, we describe their dynamical routes and two example transitional maps of the ensemble spatial breathers, with and without chaos initiation. We elucidate the physical mechanisms of the breather dynamics in the soliton crystal microcombs, in the interaction plane limit cycles and in the domain-wall understanding with parity symmetry breaking from third-order dispersion. We present maps of the accessible nonlinear regions, the breather frequency dependences on third-order dispersion and avoided-mode crossing strengths, and the transition between the collective breather spatio-temporal states. Our range of measurements matches well with our first-principles theory and nonlinear modeling. To image these soliton ensembles and their breathers, we further constructed panoramic temporal imaging for simultaneous fast- and slow-axis two-dimensional mapping of the breathers. In the phase-differential sampling, we present two-dimensional evolution maps of soliton crystal breathers, including with defects, in both stable breathers and breathers with drift. Our fundamental studies contribute to the understanding of nonlinear dynamics in soliton crystal complexes, their spatio-temporal dependences, and their stability-existence zones.","PeriodicalId":20,"journal":{"name":"ACS Medicinal Chemistry Letters","volume":"9 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142170785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A simple and rapid simultaneous measurement strategy for optical rotatory dispersion and circular dichroism 简单快速的光学旋转色散和圆二色性同步测量策略

3区医学

ACS Medicinal Chemistry Letters Pub Date : 2024-09-11 DOI: 10.1038/s41377-024-01595-y

Junjie Du

引用次数: 0

Coulomb focusing in attosecond angular streaking 阿秒角条纹中的库仑聚焦

3区医学

ACS Medicinal Chemistry Letters Pub Date : 2024-09-11 DOI: 10.1038/s41377-024-01600-4

Xiaokai Li, Xiwang Liu, Chuncheng Wang, Shuai Ben, Shengpeng Zhou, Yizhang Yang, Xiaohong Song, Jing Chen, Weifeng Yang, Dajun Ding

{"title":"Coulomb focusing in attosecond angular streaking","authors":"Xiaokai Li, Xiwang Liu, Chuncheng Wang, Shuai Ben, Shengpeng Zhou, Yizhang Yang, Xiaohong Song, Jing Chen, Weifeng Yang, Dajun Ding","doi":"10.1038/s41377-024-01600-4","DOIUrl":"https://doi.org/10.1038/s41377-024-01600-4","url":null,"abstract":"Angular streaking technique employs a close-to-circularly polarized laser pulse to build a mapping between the instant of maximum ionization and the most probable emission angle in the photoelectron momentum distribution, thereby enabling the probe of laser-induced electron dynamics in atoms and molecules with attosecond temporal resolution. Here, through the jointed experimental observations and improved Coulomb-corrected strong-field approximation statistical simulations, we identify that electrons emitted at different initial ionization times converge to the most probable emission angle due to the previously-unexpected Coulomb focusing triggered by the nonadiabatic laser-induced electron tunneling. We reveal that the Coulomb focusing induces the observed nonintuitive energy-dependent trend in the angular streaking measurements on the nonadiabatic tunneling, and that tunneling dynamics under the classically forbidden barrier can leave fingerprints on the resulting signals. Our findings have significant implications for the decoding of the intricate tunneling dynamics with attosecond angular streaking.","PeriodicalId":20,"journal":{"name":"ACS Medicinal Chemistry Letters","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Deep learning as a highly efficient tool for digital signal processing design 深度学习是数字信号处理设计的高效工具

3区医学

ACS Medicinal Chemistry Letters Pub Date : 2024-09-11 DOI: 10.1038/s41377-024-01599-8

Andrey Pryamikov

引用次数: 0

High efficiency and dynamic modulation of nonlinear metasurfaces 非线性元表面的高效率和动态调制

3区医学

ACS Medicinal Chemistry Letters Pub Date : 2024-09-10 DOI: 10.1038/s41377-024-01592-1

Ruizhe Zhao, Lingling Huang

引用次数: 0

New insights into plasmonic hot-electron dynamics 对等离子体热电子动力学的新认识

3区医学

ACS Medicinal Chemistry Letters Pub Date : 2024-09-10 DOI: 10.1038/s41377-024-01594-z

Dangyuan Lei, Dong Su, Stefan A. Maier

引用次数: 0

Broadband infrared imaging governed by guided-mode resonance in dielectric metasurfaces 介电元表面导模共振控制的宽带红外成像

3区医学

ACS Medicinal Chemistry Letters Pub Date : 2024-09-10 DOI: 10.1038/s41377-024-01535-w

Ze Zheng, Daria Smirnova, Gabriel Sanderson, Ying Cuifeng, Demosthenes C. Koutsogeorgis, Lujun Huang, Zixi Liu, Rupert Oulton, Arman Yousefi, Andrey E. Miroshnichenko, Dragomir N. Neshev, Mary O’Neill, Mohsen Rahmani, Lei Xu

{"title":"Broadband infrared imaging governed by guided-mode resonance in dielectric metasurfaces","authors":"Ze Zheng, Daria Smirnova, Gabriel Sanderson, Ying Cuifeng, Demosthenes C. Koutsogeorgis, Lujun Huang, Zixi Liu, Rupert Oulton, Arman Yousefi, Andrey E. Miroshnichenko, Dragomir N. Neshev, Mary O’Neill, Mohsen Rahmani, Lei Xu","doi":"10.1038/s41377-024-01535-w","DOIUrl":"https://doi.org/10.1038/s41377-024-01535-w","url":null,"abstract":"Nonlinear metasurfaces have experienced rapid growth recently due to their potential in various applications, including infrared imaging and spectroscopy. However, due to the low conversion efficiencies of metasurfaces, several strategies have been adopted to enhance their performances, including employing resonances at signal or nonlinear emission wavelengths. This strategy results in a narrow operational band of the nonlinear metasurfaces, which has bottlenecked many applications, including nonlinear holography, image encoding, and nonlinear metalenses. Here, we overcome this issue by introducing a new nonlinear imaging platform utilizing a pump beam to enhance signal conversion through four-wave mixing (FWM), whereby the metasurface is resonant at the pump wavelength rather than the signal or nonlinear emissions. As a result, we demonstrate broadband nonlinear imaging for arbitrary objects using metasurfaces. A silicon disk-on-slab metasurface is introduced with an excitable guided-mode resonance at the pump wavelength. This enabled direct conversion of a broad IR image ranging from >1000 to 4000 nm into visible. Importantly, adopting FWM substantially reduces the dependence on high-power signal inputs or resonant features at the signal beam of nonlinear imaging by utilizing the quadratic relationship between the pump beam intensity and the signal conversion efficiency. Our results, therefore, unlock the potential for broadband infrared imaging capabilities with metasurfaces, making a promising advancement for next-generation all-optical infrared imaging techniques with chip-scale photonic devices.","PeriodicalId":20,"journal":{"name":"ACS Medicinal Chemistry Letters","volume":"52 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142160420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

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