{"title":"Use of Construction and Demolition Waste for the Treatment of Dye-Contaminated Water Toward Circular economy","authors":"Nathalia Souza Domingues, Érica Leonor Romão, Débora Souza Alvim, Jessica Pelinsom Marques, Valeria Guimarães Silvestre Rodrigues, Mariana Consiglio Kasemodel","doi":"10.1007/s11270-024-07421-w","DOIUrl":"https://doi.org/10.1007/s11270-024-07421-w","url":null,"abstract":"<p>The use of construction and demolition waste (CDW) for the treatment of dye-contaminated water can be an effective way to minimize environmental impacts. This study evaluates its adoption as a potential adsorbent for methylene blue (MB) in aqueous solution. Cement mortar, roof tiles, and tiles were disintegrated and sieved for physicochemical characterization (pH, potential redox – Eh, electrical conductivity – CE, cationic exchange capacity—CEC, point of zero charge – PZC, specific surface area – SSA, pore distribution, functional groups, and elemental composition). The effect of initial concentration, pH, granulometric fraction and time were evaluated in adsorption and desorption studies. The results of adsorption studies were analyzed using nonlinear kinetic models and equilibrium data were analyzed by Langmuir, Freundlich, Sips, and Temkin isotherm models. The CDW evaluated has alkaline pH (pH 8.4 – 11.6) with high EC (680.5 – 1054.5 µS cm<sup>−1</sup>), reductive environment (-223 – -66 mV), low CEC (0.45 – 1.40 cmol<sub>c</sub> kg<sup>−1</sup>), SSA (1.83 – 11.06 m<sup>2</sup> g<sup>−1</sup>), and basic PZC (8.3 – 10.0). Initial concentration, pH and adsorbent particle size affected the removal efficiency and desorption rate. Roof tiles showed higher MB removal efficiency (84.5%), followed by cement mortar (61.1%) and tiles (41.6%), and the materials displayed the following maximum adsorption capacities (q<sub>m</sub>): tiles (13.983 mg g<sup>−1</sup>) > roof tiles (8.389 mg g<sup>−1</sup>) > cement mortar (1.305 mg g<sup>−1</sup>). Pseudo-first order model best described the chemical kinetics. Freundlich isotherm best described the adsorption process of MB onto tiles and Sips model best described the process onto roof tiles and cement mortar. Therefore, the materials can be used for removing MB from aqueous solutions.</p>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":null,"pages":null},"PeriodicalIF":2.52,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142200349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Hollow Co3O4 nanospheres modified with RuCl3 as peroxidase mimics for sensitive determination of sulfide ions at neutral pH","authors":"Daqing Chen, Minghui Li, Wanzhu Wang, Danhua Ge, Xiaojun Chen","doi":"10.1039/d4en00569d","DOIUrl":"https://doi.org/10.1039/d4en00569d","url":null,"abstract":"Developing high-performance nanozymes at neutral pH is extremely necessary for the application of biological and water environmental systems. RuCl3 modified hollow Co3O4 nanospheres (Ru3+-Co3O4 HNSs) were utilized to establish a colorimetric sensor for selective determination of sulfide ions (S2-). The hollow Co3O4 nanospheres after doping of Ru3+ provide large surface area and more active sites, thereby boosting the electron transport and the affinity to the substrates. Specifically, the as-prepared Ru3+-Co3O4 HNSs exhibited remarkable peroxidase-like (POD-like) activity, which can catalyze colorless 3,3′,5,5′-tetramethylbenzidine (TMB) to blue oxTMB at neutral pH condition. Furthermore, the Ru3+-Co3O4-based colorimetric sensor achieved a wide linear range (0.5-20 μM) and a low detection limit (0.051 μM) for S2- ions concentration, as well as good selectivity, reproducibility and practicability in sewage water. This research aims to boost the accuracy of S2- detection and shed light on application prospects in the water environmental fields.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":null,"pages":null},"PeriodicalIF":8.131,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142138420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jiahao Liu, Dan Zhang, Linfeng Bao, Tingyong Mao, Linbo Zhao, Chan Liu, Guanjun Huang, Yun long Zhai
{"title":"Plant nanobiotechnology: a new strategy to enhance crop photosynthesis","authors":"Jiahao Liu, Dan Zhang, Linfeng Bao, Tingyong Mao, Linbo Zhao, Chan Liu, Guanjun Huang, Yun long Zhai","doi":"10.1039/d4en00520a","DOIUrl":"https://doi.org/10.1039/d4en00520a","url":null,"abstract":"In crops, photosynthesis is the basis of biomass accumulation and yield formation. With the ever-increasing global population and the increased need to meet the food demand, the ability to increase crop yield has become a pressing concern, especially considering that crop production has been threatened by increased biotic and abiotic stress. Previous studies have evaluated photosynthetic system structure and population photosynthesis based on agronomic and molecular biology. However, these methods require a long study period and a high cost. Therefore, identifying a fast, simple, and cheap strategy to improve plant photosynthesis is crucial for future crop production. Plant nanobiotechnology, as a new interdisciplinary field, provides remarkable insight into plant stress tolerance, chemical delivery, and transgenes. In this review, to provide new insights for future plant nanobiotechnological studies, we examine previous studies on photosynthesis and enhancing photosynthesis through plant nanobiotechnology and suggest possible strategies for increasing photosynthesis.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":null,"pages":null},"PeriodicalIF":8.131,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142138419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anastasiia S. Kuzenkova, Tatiana V. Plakhova, Roman D. Svetogorov, Elizaveta S. Kulikova, Alexander L. Trigub, Vasily O. Yapaskurt, Alexander V. Egorov, Andrey S. Toropov, Alexey A. Averin, Maria D. Shaulskaya, Dmitry M. Tsymbarenko, Anna Yu. Romanchuk, Stepan N. Kalmykov
{"title":"Neglected solid phase pentavalent plutonium carbonate in the environment","authors":"Anastasiia S. Kuzenkova, Tatiana V. Plakhova, Roman D. Svetogorov, Elizaveta S. Kulikova, Alexander L. Trigub, Vasily O. Yapaskurt, Alexander V. Egorov, Andrey S. Toropov, Alexey A. Averin, Maria D. Shaulskaya, Dmitry M. Tsymbarenko, Anna Yu. Romanchuk, Stepan N. Kalmykov","doi":"10.1039/d4en00283k","DOIUrl":"https://doi.org/10.1039/d4en00283k","url":null,"abstract":"KPuO<small><sub>2</sub></small>CO<small><sub>3</sub></small> solid phase precipitation from hexavalent plutonium (Pu(<small>VI</small>)) solution is discussed herein. The kinetic process of Pu(<small>V</small>)/potassium carbonate formation is widely investigated under constant control of Pu concentration in different oxidation states, redox potentials, and pH values. Synchrotron-based X-ray diffraction, X-ray absorption spectroscopy, high-resolution transmission electron microscopy, and scanning electron microscopy with energy-dispersive X-ray spectroscopy are employed for solid phase analysis. The crystal structure of KPuO<small><sub>2</sub></small>CO<small><sub>3</sub></small> is specified <em>via</em> the Rietveld method and extended X-ray absorption fine structure fitting. The stability area of Pu(<small>V</small>) potassium carbonate is discussed and a moderated Pourbaix diagram is presented.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":null,"pages":null},"PeriodicalIF":8.131,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142138421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jiangmian Wei, Yanjun Chen, Mingxin Zhu, Jiayang Liu, Jun Wang
{"title":"Enzymatic Decolorization of Dye Wastewater and its Effect on Respiration of Activated Sludge","authors":"Jiangmian Wei, Yanjun Chen, Mingxin Zhu, Jiayang Liu, Jun Wang","doi":"10.1007/s11270-024-07478-7","DOIUrl":"https://doi.org/10.1007/s11270-024-07478-7","url":null,"abstract":"<p>This study investigated the decolorization and detoxification of a dye originating from a feather-dyeing house using the laccase enzyme. Efficient decolorization was achieved under a wide range of environmental conditions, including pH, temperature, enzyme loading, and dye concentration. The decolorization rate reached up to 98% within 10 min when the mediator acetosyringone was present. Decolorization was attributed to the degradation of the dye by laccase, as analyzed using liquid chromatography-mass spectrometry (LC–MS). At least three dominant intermediates (m/z 167.993, 194.475, 118.040) were identified, deriving from the original dye (m/z 521.044). Compared to the non-decolorized dye solution, the decolorized dye ones at various concentrations exhibited lower toxicity towards aerobic activated sludge (AS). This was evident from the significantly higher respiratory intensity of AS, with an O₂ uptake of 35 mg for the decolorized solution versus 11 mg for the non-decolorized solution after 12 h at a 100 mg/L dye concentration. The results suggest that laccase-catalyzed decolorization could serve as an effective pretreatment method for traditional activated sludge (AS)-based processes, thereby enhancing the overall treatment performance of dye wastewater.</p>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":null,"pages":null},"PeriodicalIF":2.52,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142200351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Siddhant S. Kalyankar, Varsha Antanitta S, Fuhar Dixit, Karl Zimmermann, Balasubramanian Kandasubramanian
{"title":"Composite Materials For Adsorption of Rare Earth Metal Ions","authors":"Siddhant S. Kalyankar, Varsha Antanitta S, Fuhar Dixit, Karl Zimmermann, Balasubramanian Kandasubramanian","doi":"10.1007/s11270-024-07453-2","DOIUrl":"https://doi.org/10.1007/s11270-024-07453-2","url":null,"abstract":"<p>Rare earth elements (REEs) are vital across numerous sectors, from nuclear and architecture to electronics and medicine, due to their unique properties. Meeting the growing demand for REEs necessitates innovative recovery methods from waste and recycling. This review explores the adsorption of REEs using polymer composites, including biopolymers, synthetic polymers, and conducting polymers. These composites demonstrate remarkable adsorption capacity and selectivity for REEs. This review explored several natural and synthetic polymers, composites, and nanocomposites as adsorbents, focusing on chemical structures, kinetics, adsorption capacity, processes, and polarity for REE uptake from aqueous solutions. Notably, benzyl phosphate-based polymers achieve the highest adsorption capacity at 301 mg/g, while polypyrrole sawdust exhibits the lowest at 6 mg/g. Nanocomposites, however, excel with adsorption capacities exceeding 900 mg/g. This review underscores the critical importance of REE recovery and recycling for a sustainable and clean global environment.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>\u0000","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":null,"pages":null},"PeriodicalIF":2.52,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142200353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Biosorption of Hexavalent Chromium Over Modified Terrestrial Moss: Experimental, Kinetic, and Isotherm Studies","authors":"Feride Ulu","doi":"10.1007/s11270-024-07479-6","DOIUrl":"https://doi.org/10.1007/s11270-024-07479-6","url":null,"abstract":"<p>In this research, activated carbon was prepared from terrestrial moss and utilized as a low-cost adsorbent to remove hexavalent chromium [Cr(VI)] from aqueous solution. The study examined important biosorption factors including initial pH (1–3), contact time (0.5–24 h), initial Cr(VI) concentration (20–400 mg/L), and biosorbent dosage (0.05–0.4 g) to assess their impact on the efficiency of modified terrestrial moss (MAC) in eliminating Cr(VI) from water. The biosorbent capacity was evaluated using different kinetic models and isotherms. The highest removal efficiency of Cr(VI) onto MAC was ascertained as 97.8% at an initial solution pH of 1, MAC dose of 0.2 g, initial Cr(VI) concentration of 50 mg. L<sup>−1</sup>, and contact time of 15 h. The FTIR analysis revealed the interactions of certain functional groups in the adsorption of chromium ions. The biosorption occurred through the anionic adsorption mechanism and followed the pseudo-second order kinetic model. The experimental data was best fitted with Freundlich isotherm. Furthermore, the thermodynamic studies suggest that the biosorption process is both spontaneous and exothermic. The positive entropy change implied the randomness at the solid–liquid interface. In light of these compelling results, the study recommends the consideration of MAC as an efficient and practical solution for the removal of Cr (VI) from aqueous environments.</p>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":null,"pages":null},"PeriodicalIF":2.52,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142200348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Vanessa Takeshita, Ana Cristina Preisler, Gustavo Vinicios Munhoz-Garcia, Lucas Bragança, Camila Werk de Pinácio, Halley Caixeta Oliveira, Valdemar Luiz Tornisielo, Brian Cintra Cardoso, Eduardo F.B. Ramalho, Rodrigo Floriano Pimpinato, Amanda M. Dinonísio, Waldiceu A. Verri, Leonardo Fernandes Fraceto
{"title":"A multi-technique approach for nanoherbicide tracking: uptake and translocation pathways of metribuzin nanocarrier in weed plants","authors":"Vanessa Takeshita, Ana Cristina Preisler, Gustavo Vinicios Munhoz-Garcia, Lucas Bragança, Camila Werk de Pinácio, Halley Caixeta Oliveira, Valdemar Luiz Tornisielo, Brian Cintra Cardoso, Eduardo F.B. Ramalho, Rodrigo Floriano Pimpinato, Amanda M. Dinonísio, Waldiceu A. Verri, Leonardo Fernandes Fraceto","doi":"10.1039/d4en00240g","DOIUrl":"https://doi.org/10.1039/d4en00240g","url":null,"abstract":"Understanding the strategies of delivering active ingredients with nanoparticles to plant species is crucial to implement a safe-by-design approach for pesticides. Here, we used metribuzin (MTZ) as a study model to understand the plant uptake and distribution pathways of polymeric nanocarriers. We investigated the weed-control efficacy, uptake, internalization, and distribution of the (nano)herbicide MTZ in <em>Amaranthus viridis</em> (C4 species) and <em>Bidens pilosa </em>(C3 species), after soil and foliar application. Radiolabeled herbicide and fluorescent probes were used as complementary tools to track both MTZ and nanoparticles in plants. The weed-control results indicated significant dose reductions with MTZ nanoencapsulation (from ½ to 10-fold doses). Root uptake was an efficient pathway for <em>A. viridis</em> and for <em>B. pilosa</em> entry of nanoMTZ was preferentially by stomata and was internalized in leaf mesophyll cells. No differences in herbicide uptake were observed in the soil, and nanoMTZ distribution was 1.3-1.5 lower than MTZ. After foliar application, nanoMTZ was absorbed 2.5 times more than MTZ in <em>A. viridis</em> and was similar in <em>B. pilosa</em>. NP was concentrated in the vascular cells after soil application and in the stomata entrance after foliar application. For <em>B. pilosa</em>, the internalization in the leaf mesophyll was more evident than in <em>A. viridis</em>. Our findings indicated that consideration of the target weed species and application mode will increase the efficacy of control using nanoformulations.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":null,"pages":null},"PeriodicalIF":8.131,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142123860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Douglas D. Kane, Nathan F. Manning, Stephen J. Jacquemin, Laura T. Johnson
{"title":"A Tale of Two Tributaries: Source Delineation of Chloride in a Distressed Watershed (Grand Lake St. Marys, Ohio)","authors":"Douglas D. Kane, Nathan F. Manning, Stephen J. Jacquemin, Laura T. Johnson","doi":"10.1007/s11270-024-07455-0","DOIUrl":"https://doi.org/10.1007/s11270-024-07455-0","url":null,"abstract":"<p>Various sources of pollution have been assigned as contributing to the Freshwater Salinization Syndrome (FSS), by which water bodies are undergoing concurrent salinization and alkalinization. In many urban areas that receive substantial snowfall, road salt application has been ascribed as the main source of chloride driving the FSS. In rural areas, however, inorganic (e.g. chemical) and organic (e.g. manure) fertilizer applications have been found to be the most important sources of chloride. Herein, we compared daily mean concentrations of chloride over the past decade of time between Coldwater Creek and Chickasaw Creek, two tributaries of Grand Lake St. Marys, the largest reservoir in Ohio. We also used Weighted Regressions on Time, Discharge, and Season (WRTDS) analyses to visualize trends in chloride data and compared chloride vs. nitrate levels to delineate likely sources of chloride for the two streams. We found that road salt application increased over time in both subwatersheds and that 37% and 25% of the chloride could be apportioned to road salt as a source in Coldwater Creek and Chickasaw Creek, respectively. Additionally, in Coldwater Creek, 37% of the chloride was apportioned to animal or septic sources, while 25% was apportioned to inorganic fertilizers, in comparison with 30% and 42% for Chickasaw Creek. Monitoring and assessing salinized streams for both chemical and biological water quality is important, particularly since the FSS has become increasingly linked to declines in water quality (e.g. harmful algal blooms, including recent upticks in <i>Prymnesium parvum</i> blooms) and is expected to be exacerbated with global climate change (e.g. increased precipitation causing increased runoff of chloride from the land).</p>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":null,"pages":null},"PeriodicalIF":2.52,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142200355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Impact of Open Dumping Site on Groundwater Quality in Silchar City, Assam, India","authors":"Mausam Kumar Paul, Mithra Dey, Chandra Sharma","doi":"10.1007/s11270-024-07434-5","DOIUrl":"https://doi.org/10.1007/s11270-024-07434-5","url":null,"abstract":"<p>Solid waste management is a burning issue that requires special attention and consideration in developing countries. In most cities and towns, it has become a public health concern due to uncontrolled dumping that has caused degradation of the natural environment. Therefore, the present study assessed the impact of dump yards on the surrounding environment by conducting physicochemical and biological analysis of groundwater and leachate samples and comparing it with control sites located at Silchar town of Assam, India. The result demonstrated that a large number of organic materials and inorganic salt leached to the surrounding environment by the decomposition of waste at open dumping site which significantly pollutes the groundwater sources of nearby areas. The sample site S5 recorded the highest value of WQI (100.78). Contamination of Total Coliform and <i>E. Coli</i> bacteria were recorded in the range of 96–2116 CFU/100 ml and 0–2466 CFU/100 ml respectively in sample sites. However, in control sites, coliform bacteria were found in the range of 8–43 CFU/100 ml and <i>E. coli</i> bacteria was found to be absent in all the control sites. The mean concentrations of Pb (8.94 mg L<sup>−1</sup>), Mn (19.12 mg L<sup>−1</sup>) and Ni (6.38 mg L<sup>−1</sup>) in the dump yards were found above the maximum permissible limit of EPA US, 1986; however, the concentrations of Cu (4.05 mg L<sup>−1</sup>) and Cd (0.45 mg L<sup>−1</sup>) were within the permissible limit. Hence, there is a need for proper scientific planning and management of waste disposal for the protection of our surrounding environment.</p>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":null,"pages":null},"PeriodicalIF":2.52,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142200357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}