A R Seiler, E J Schleff, O M Gamsky, A Y Stark, S P Yanoviak
{"title":"Effects of simulated squirrel branch landings on ants and other arboreal arthropods.","authors":"A R Seiler, E J Schleff, O M Gamsky, A Y Stark, S P Yanoviak","doi":"10.1007/s00114-025-01993-1","DOIUrl":"10.1007/s00114-025-01993-1","url":null,"abstract":"<p><p>Wind, rain, and the activities of vertebrates frequently dislodge arthropods from tree surfaces, resulting in arthropod \"rain\" beneath trees. The probability of falling likely differs among taxa based on their adhesive capacities and ability to anticipate disturbance. We quantified the motion of red oak (Quercus rubra Linnaeus [Fagales: Fagaceae]) leaves, and the composition of arthropods dislodged from woody vegetation, following disturbance mimicking branch landings by eastern gray squirrels (Sciurus carolinensis Gmelin [Rodentia: Sciuridae]). Simulated squirrel landings caused terminal leaves on red oak branches to move rapidly (up to 100 cm s<sup>-1</sup>) upward and inward toward the tree trunk during the first 50 ms, and dislodged 30% of the arthropods present on a branch. The composition of fallen arthropods was similar to those that remained on the branches, but the proportion dislodged differed among taxa. We used a small catapult to test the effect of leaf movement on the adhesive capabilities of workers of the carpenter ant Camponotus pennsylvanicus DeGeer (Hymenoptera: Formicidae). Arboreal ants presumably anticipate disturbance; thus, they were either \"warned\" or \"unwarned\" before each launch. Most ants (98%) were dislodged by the catapult. Warning did not affect the average (± SE) initial velocity (126.0 ± 72.0 cm s<sup>-1</sup>) or maximum height (22.8 ± 9.3 cm) of launched ants. However, both variables were positively associated with ant mass. The results illustrate the limited ability of many arboreal arthropods to avoid the consequences of a common natural hazard and improve our understanding of the challenges imposed by an arboreal lifestyle.</p>","PeriodicalId":794,"journal":{"name":"The Science of Nature","volume":"112 3","pages":"42"},"PeriodicalIF":2.1,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144155489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Quantitative Analysis of Alkylphenols In Environmental Samples With Metagenomic Impact Assessments","authors":"Ajay Kumar, Ashwini Kumar, Ashok Kumar Malik, Avneesh Kumar, Vajinder Kumar, Baljinder Singh","doi":"10.1007/s11270-025-08145-1","DOIUrl":"10.1007/s11270-025-08145-1","url":null,"abstract":"<div><p>A simple and accurate quantitative method was used for four endocrine disruptors: 4-tert butyl phenol (4-TBP), 4-tert amyl phenol (4-TAP), 4-cumyl phenol (4-CP), and 3-tert butyl phenol (3-TBP) using solid-phase microextraction (SPME) coupled with high-performance liquid chromatography (HPLC) and ultraviolet (UV) detection in river water, domestic water, domestic wastewater, sludge, and soil samples. Carbowax templated resin (50 µm) fiber was employed to extract the analytes from aqueous samples. The limits of detection (LOD) for 4-TBP, 4-TAP, 4-CP, and 3-TBP were 1.33, 0.78, 0.89, and 0.17 ng/mL, respectively. To assess the alkylphenol content introduced into water from domestic use (household activities of Patiala city), concentrations were measured in both household water and wastewater generated from domestic activities in Patiala, India. To assess the alkylphenol content introduced into water from domestic activities in Patiala, Punjab, India, concentrations were measured in both the tube-well water supplied to households and the domestic wastewater generated from these activities. Additionally, metagenomic analysis using 16S rRNA gene sequencing was conducted on soil samples and domestic wastewater sludge to evaluate the impact of alkylphenols on the microbial community. The 16S rRNA gene sequencing analysis revealed a rich microbial community, with 20 phyla detected. Despite this diversity, only seven phyla accounted for more than 90% of the total bacterial population in each sample, with Proteobacteria being the most prevalent phylum across both sample types.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144140230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Junjie Yang, Jun Xie, Junxian Qin, Jin Shang, Hiromi Yamashita, Daiqi Ye and Yun Hu
{"title":"MOF-derived Ni–Cu bimetallic interface synergy modified TiO2 for efficient photocatalytic conversion of CO2 to formate in ammonia nitrogen wastewater†","authors":"Junjie Yang, Jun Xie, Junxian Qin, Jin Shang, Hiromi Yamashita, Daiqi Ye and Yun Hu","doi":"10.1039/D5EN00297D","DOIUrl":"10.1039/D5EN00297D","url":null,"abstract":"<p >To address the critical challenges in photocatalytic CO<small><sub>2</sub></small> reduction systems, including rapid recombination of photogenerated electron–hole pairs, indiscriminate product distribution, and oxidative degradation of liquid-phase intermediates, we designed a ZIF-8-derived Ni–Cu bimetallic modified TiO<small><sub>2</sub></small> (NiCu-GC-TiO<small><sub>2</sub></small>) photocatalyst for synergistic formate synthesis from CO<small><sub>2</sub></small> and ammonia nitrogen wastewater The research results indicate that Ni–Cu forms a highly dispersed interface through N bridges, significantly enhancing charge separation efficiency. In the NH<small><sub>3</sub></small>-N system at pH = 10, the formate yield reached 116.2 μmol L<small><sup>−1</sup></small> (99.4% selectivity), which was 9.4 times higher than that of TiO<small><sub>2</sub></small>. Ammonia nitrogen serves as an oxidative substrate that accelerates hole consumption while inhibiting formate oxidation. Isotope experiments confirmed that formate protons originate entirely from ammonia nitrogen, and the protons released from ammonia nitrogen oxidation drive the directed conversion of CO<small><sub>2</sub></small> to formate. The system can directly utilize HCO<small><sub>3</sub></small><small><sup>−</sup></small> as a carbon source, compatible with industrial carbon capture processes. Cycling tests and flow-phase experiments demonstrated excellent material stability and practical applicability. This research provides a novel strategy for synergistic mechanisms between photocatalytic CO<small><sub>2</sub></small> reduction and wastewater treatment, which contributes to both environmental sustainability and energy utilization.</p>","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":" 7","pages":" 3503-3513"},"PeriodicalIF":5.8,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144145448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Diana Ramírez-Mejía , Yves Zinngrebe , Erle C. Ellis , Peter H. Verburg
{"title":"Land-use spillovers from environmental policy interventions","authors":"Diana Ramírez-Mejía , Yves Zinngrebe , Erle C. Ellis , Peter H. Verburg","doi":"10.1016/j.gloenvcha.2025.103013","DOIUrl":"10.1016/j.gloenvcha.2025.103013","url":null,"abstract":"<div><div>Environmental policy interventions are crucial for addressing biodiversity loss and climate change, yet their effectiveness can be compromised by land-use spillovers, where efforts to reduce impacts in one place displace them elsewhere. Despite growing recognition of spillovers, they remain unevenly defined, inconsistently measured, and poorly integrated into policy evaluation and accountability frameworks. This systematic review synthesizes current research on land-use spillovers triggered by environmental policies, including carbon pricing, protected areas, supply chain interventions, and payments for ecosystem services. We identify three dominant pathways: leakage, indirect land use change (iLUC), and positive spillovers, emerging under common conditions such as weak enforcement, market integration, limited livelihood alternatives, and accessible frontier lands. These conditions are shaped by broader institutional, economic, demographic, and biophysical drivers, yet are rarely integrated into policy design and evaluation. While methods to evaluate spillover effects range from global scale ex ante models to local ex post spatial and econometric analyses, few studies bridge scales or connect findings to international policy frameworks such as the Convention on Biological Diversity (CBD) or the United Nations Framework Convention on Climate Change (UNFCCC). Cases are concentrated in climate-linked interventions and in South America, leaving important geographic and sectoral blind spots. This limits their relevance for designing policies that minimize displaced impacts and foster more durable outcomes. Advancing spillover research will require common frameworks, more consistent methodologies, and multi-scale tools that can enhance comparability, attribution, and integration into environmental governance.</div></div>","PeriodicalId":328,"journal":{"name":"Global Environmental Change","volume":"92 ","pages":"Article 103013"},"PeriodicalIF":8.6,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144155007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fabricio A. Santos, Rafaela S. Andre, Augusto D. Alvarenga, Ana Laura M. M. Alves and Daniel S. Correa
{"title":"Micro- and nanoplastics in the environment: a comprehensive review on detection techniques","authors":"Fabricio A. Santos, Rafaela S. Andre, Augusto D. Alvarenga, Ana Laura M. M. Alves and Daniel S. Correa","doi":"10.1039/D4EN00319E","DOIUrl":"10.1039/D4EN00319E","url":null,"abstract":"<p >Microplastics and nanoplastics (MNPs), which arise from the fragmentation of larger plastic debris or are intentionally produced on smaller scales, can persist in the environment for long periods. Considering that these particles are ubiquitous environmental pollutants, concerns arise regarding their potential adverse impacts on ecosystems and human health, which is the reason why their identification is becoming of paramount importance nowadays. In this review, we present an updated survey of the main techniques currently employed to identify MNPs, focusing on the well-established FT-IR and Raman spectroscopy techniques, which are recognized as the gold standards in the analysis of these materials. We also explore new approaches to detect MNPs, including electroanalytical techniques, microfluidic systems, and various mass spectrometry techniques. Furthermore, other techniques, such as fluorescence spectroscopy, laser-induced breakdown spectroscopy (LIBS) and others, which help to complement the chemical and structural analysis of MNPs, are also evaluated. Combining these different approaches offers a comprehensive and detailed evaluation of micro- and nanoplastic materials across various environments, thereby supporting the implementation of target strategies to help mitigate the impacts of these emerging pollutants on both the environment and human health.</p>","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":" 7","pages":" 3442-3467"},"PeriodicalIF":5.8,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144145482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Attributing deforestation-driven biodiversity decline in the Gran Chaco to agricultural commodity supply chains","authors":"Isabel Carpenter , Tobias Kuemmerle , Alfredo Romero-Muñoz , Sebastián Aguiar , Ignacio Gasparri , Michael J. Lathuillière , Sofía Nanni , Vivian Ribero , Matthias Baumann","doi":"10.1016/j.gloenvcha.2025.103011","DOIUrl":"10.1016/j.gloenvcha.2025.103011","url":null,"abstract":"<div><div>Agricultural expansion is one of the principal drivers of biodiversity loss globally. Attributing biodiversity loss to domestically consumed versus internationally traded agricultural production is vital to make supply chains more transparent and sustainable. However, such an attribution is challenging due to the complexity of agricultural supply chains and the lack of tools and data. Here, we attributed biodiversity decline in the Gran Chaco, specifically the Argentinian and Paraguayan Chaco, to both soy and beef agricultural commodities and the domestic and foreign demand for these. We integrated three sources of multitemporal data at a subnational scale (data on mammal diversity, land use change and commodity trade) to first differentiate pasture- versus cropland-driven biodiversity decline and second, to assess the share of the decline associated with domestically consumed and internationally traded Argentinian and Paraguayan soy and Paraguayan beef. In doing so, we provided four novel insights. First, pasture expansion had a greater relative biodiversity impact than cropland expansion. Second, the biodiversity decline associated with domestic and international consumption depended on both the quantity of imports and the precise location of production and sourcing. Third, domestic consumption of commodities in Argentina and Paraguay was associated with a much greater risk of driving decline in biodiversity than agricultural exports from these nations. Fourth, considering only one facet of biodiversity risks underestimating the decline in biodiversity linked to agricultural expansion and commodity supply chains. By connecting agriculturally driven biodiversity decline in the Gran Chaco to commodity supply chains, we highlight the importance of increasing the transparency of supply chains to make them more sustainable. Doing so will be critical to prevent further biodiversity loss in not only the Gran Chaco but also the other dry forests of the world.</div></div>","PeriodicalId":328,"journal":{"name":"Global Environmental Change","volume":"92 ","pages":"Article 103011"},"PeriodicalIF":8.6,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144138983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zohaib Kaleem, Hafsah Shahbaz, Sharafat Ali, Anmol Albert, Di He, Rana Muhammad Amir Gulzar, Muhammad Asad Ullah Asad, Weijun Zhou, Kangni Zhang and Zaid Ulhassan
{"title":"Melatonin and nanocopper synergistically regulate cadmium toxicity in Brassica napus: evidences from photosynthesis phenomics, oxidative metabolism, and multiple defense responses†","authors":"Zohaib Kaleem, Hafsah Shahbaz, Sharafat Ali, Anmol Albert, Di He, Rana Muhammad Amir Gulzar, Muhammad Asad Ullah Asad, Weijun Zhou, Kangni Zhang and Zaid Ulhassan","doi":"10.1039/D5EN00012B","DOIUrl":"10.1039/D5EN00012B","url":null,"abstract":"<p >Cadmium (Cd) toxicity severely impedes plant growth and yield. Melatonin (MEL) and copper oxide nanoparticles (CuO NPs) have independently been demonstrated to enhance plant growth and mitigate heavy metal stress. However, their combined effect in managing Cd toxicity in oilseed crops remains largely unexplored. Thus, we evaluated the efficacy of 10 μM MEL and/or 3 mg L<small><sup>−1</sup></small> CuO NPs to regulate the tolerance of <em>Brassica napus</em> cultivars (ZD 635 and ZD 622) to Cd toxicity. Results revealed that CuO NPs and/or MEL considerably lowered Cd toxicity by minimizing the accumulation of Cd (44–53%), malondialdehyde (29–37%), H<small><sub>2</sub></small>O<small><sub>2</sub></small> (28–35%) and O<small><sub>2</sub></small>˙<small><sup>−</sup></small> (26–34%) and improving the photosynthesis phenomics (pigments, gas exchanges, PSII and Chl a fluorescence), resulting in higher biomass, membrane integrity and lower oxidative stress. Moreover, CuO NPs and/or MEL significantly boosted the antioxidant enzyme activity and production of total phenolics, total flavonoids, proline and phytohormones (SA, ABA, MEL and JA) in Cd-treated plants, revealing the key roles of CuO NPs and/or MEL in improving plant defense. Additionally, the potential protective roles of CuO NPs and/or MEL significantly recovered the Cd-induced cellular damages, as observed by the improvements in the leaf ultrastructure (chloroplast, mitochondria, and thylakoid membranes), stomatal aperture and guard cells. It was evident that the combined application of CuO NPs and MEL was more effective in alleviating the accumulation and toxicity of Cd in <em>B. napus</em> tissues than the separate treatments. Cd bioaccumulation, photosynthesis and antioxidant defense responses can serve as ideal indicators for oilseed crops grown in Cd-contaminated soils.</p>","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":" 7","pages":" 3714-3730"},"PeriodicalIF":5.8,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144145458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yiming Li, Yucong Ye, Xiaoyi Zhu, Zongli Yao, Yan Li, Zhen Sun, Na Rihan, Yunlong Zhao and Qifang Lai
{"title":"Ion transport and metabolic regulation induced by nanoplastic toxicity in gill of Litopenaeus vannamei using proteomics†","authors":"Yiming Li, Yucong Ye, Xiaoyi Zhu, Zongli Yao, Yan Li, Zhen Sun, Na Rihan, Yunlong Zhao and Qifang Lai","doi":"10.1039/D5EN00040H","DOIUrl":"10.1039/D5EN00040H","url":null,"abstract":"<p >Polystyrene nanoplastic (PS-NP) pollution has become a global environmental problem, and its potential toxicity to aquatic organisms has led to widespread concern. In this study, a 28-day chronic nanoplastic exposure (0, 0.1, 1, 5, and 10 mg L<small><sup>−1</sup></small>) experiment was established to investigate the effects of ion transport and metabolic regulation in Pacific white shrimp <em>Litopenaeus vannamei</em>. The results showed that the ion content in gill tissues decreased and the ATPase activities significantly decreased with the increase in PS-NP concentration. PS-NP exposure destroyed the gill tissue structure, disrupted the activity of ion transport enzymes, and affected the glutathione metabolism. The blood urea nitrogen, glutamate, and proline contents first increased and then decreased with the increase in PS-NP concentration. The expression of nitric oxide synthase and thioredoxin genes involved in energy metabolism decreased. The urea nitrogen content was negatively correlated with the ion transport module, and the proline content was positively correlated with the ion transport module and gene expression. Proteomic analysis results showed that PS-NP exposure mainly affected the amino acid biosynthesis and mTOR signaling pathway. These results suggested that PS-NP exposure negatively affected the physiological state of <em>L. vannamei</em> by interfering with the urea cycle and glutathione metabolism <em>via</em> inhibition of ion transport.</p>","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":" 7","pages":" 3592-3608"},"PeriodicalIF":5.8,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144145740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Amir Detho, Asif Ali Memon, Nejib Ghazouani, Abdelkader Mabrouk, Ahmed Babeker Elhag, Aeslina Abdul Kadir, Mohd Arif Rosli
{"title":"Bioenergy Potential of Crop Residues: A Proximate and Mineral Composition Assessment","authors":"Amir Detho, Asif Ali Memon, Nejib Ghazouani, Abdelkader Mabrouk, Ahmed Babeker Elhag, Aeslina Abdul Kadir, Mohd Arif Rosli","doi":"10.1007/s11270-025-08161-1","DOIUrl":"10.1007/s11270-025-08161-1","url":null,"abstract":"<div><p>This study presents an experimental approach to determine the proximate and mineral composition of selected agricultural crop wastes, focusing on sugarcane and banana residues. Representative samples were collected and subjected to proximate analysis to measure key components, including moisture content, volatile matter, fixed carbon, and ash content. To further assess the mineral composition, AAS was utilized to quantify essential elements such as calcium oxide, magnesium oxide, and potassium oxide. The results revealed that banana crop waste had a higher moisture content (8.2%) than sugarcane crop waste (5.95%), whereas sugarcane waste exhibited greater volatile matter (77.99% vs. 63.89%) and fixed carbon (10.89% vs. 10.49%). The ash content of banana crop waste was notably higher at 17.99%, compared to 7.75% for sugarcane waste. Furthermore, the higher heating values (HHV) for sugarcane and banana wastes were recorded at 19.45 MJ/kg and 13.23 MJ/kg, respectively, aligning closely with reported literature values. This study offers key insights into the energy potential and mineral composition of agricultural residues, reinforcing their viability for bioenergy applications and mineral recovery. Future research could explore advanced pretreatment methods to enhance the bioenergy yield and optimize mineral extraction processes for industrial applications. It provides a foundation for optimizing waste-to-energy technologies for developing countries.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144140229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Health Risk of Mercury and Cadmium and Their Migrations in a Soil- Maize System of the Karst Mining Area","authors":"Xiuyuan Yang, Wenmin Luo, Zhifei Cheng, Guiting Mou, Xianliang Wu, Huijuan Liu","doi":"10.1007/s11270-025-08168-8","DOIUrl":"10.1007/s11270-025-08168-8","url":null,"abstract":"<div><p>Mining activities have caused serious heavy metal and metalloids contamination in agricultural soils, while the differences in contamination characteristics and ecological impacts of metalloid within soil-crop systems between mining and non-mining areas in karst regions remain poorly understood. Therefore, this study investigated the contents, speciation, and ecological risks of mercury (Hg) and cadmium (Cd), and explored their occurrence characteristics and risk levels in soils and maize from mining and non-mining areas in the karst environment of Guizhou Province, China. Results showed that Cd concentrations in soils from mining areas were significantly higher than those in control areas (<i>p</i> < 0.01), while Hg concentrations showed no significant difference. Medium contamination and ecological risk were identified in 44.44% of mining-area soils, primarily driven by Hg contamination. However, the risk assessment code indicated a higher bioavailability risk for Cd compared to Hg, with 22.22% of soils in the mining area exhibiting medium risk. In maize, the concentrations of Cd and Hg followed the order: roots > leaves > stems > corns. The enrichment and translocation capacities of Cd and Hg in mining-area maize were significantly greater than that of in controls. Hg and Cd speciation in soil significantly influenced their content in maize. Potential carcinogenic health risks from Cd and Hg exposure were found in mining-area maize and control areas, especially in children. Our results suggested that there was a relatively higher potential health risk caused by Cd and Hg in soil and maize, and it was necessary to pay attention to the effect of exposure by the more hazardous substances on the other local crops. Our suggestion is that several measures, including phytoremediation, biochar, advanced nanomaterial technologies, etc., are urgently needed to alleviate the heavy metal and metalloid pollution in soil and some crops according to local environmental conditions. This study provides important insights and basic data to inform strategies for mitigating heavy metal pollution of agricultural soils in karst mining areas.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 8","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144135306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}