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Detection and Elimination of Product Inhibition

有机合成与工艺文献分享 2025-07-22 11:19
文章摘要
本文研究了有机合成过程中产品抑制现象的检测与消除。背景涉及有机合成中常见的产品抑制问题，特别是胺类化合物在反应过程中对转化率的负面影响。研究目的是通过添加二叔丁基碳酸酯（Boc试剂）来解决这一问题，使还原反应生成的胺立即转化为Boc衍生物。结论表明这种方法不仅有效消除了产品抑制现象，还扩展了底物适用范围，使得酯类底物可以替代酰胺使用。
Detection and Elimination of Product Inhibition
查看文献： Detection and Elimination of Product Inhibition from the Asymmetric Catalytic Hydrogenation of Enamines
查看期刊： Organic Letters
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