{"title":"硫增强的铸币金属(111)表面动力学:台阶边缘与阶地作为金属-硫复合体形成的位置","authors":"Da‐Jiang Liu, J. Evans","doi":"10.1116/6.0001408","DOIUrl":null,"url":null,"abstract":"The propensity of trace amounts of sulfur adsorbed on coinage metal(111) surfaces to dramatically enhance surface dynamics has been demonstrated by STM observations of accelerated 2D island decay for Cu and Ag. It is generally accepted that this enhancement is due to the formation of adsorbed metal-sulfur complexes which facilitate surface mass transport of the metal. These complexes were originally proposed to form on terraces following extraction of metal atoms from step edges and subsequent combination with sulfur on the terraces. However, even when Th is is the au tho r’s pe er re vie we d, ac ce pte d m an us cri pt. H ow ev er , th e o nli ne ve rsi on of re co rd w ill be di ffe re nt fro m thi s v er sio n o nc e i t h as be en co py ed ite d a nd ty pe se t. PL EA SE C IT E TH IS A RT IC LE A S DO I: 10 .11 16 /6. 00 01 40 8","PeriodicalId":17490,"journal":{"name":"Journal of Vacuum Science & Technology A","volume":"42 1","pages":""},"PeriodicalIF":2.4000,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sulfur-enhanced dynamics of coinage metal(111) surfaces: Step edges versus terraces as locations for metal-sulfur complex formation\",\"authors\":\"Da‐Jiang Liu, J. Evans\",\"doi\":\"10.1116/6.0001408\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The propensity of trace amounts of sulfur adsorbed on coinage metal(111) surfaces to dramatically enhance surface dynamics has been demonstrated by STM observations of accelerated 2D island decay for Cu and Ag. It is generally accepted that this enhancement is due to the formation of adsorbed metal-sulfur complexes which facilitate surface mass transport of the metal. These complexes were originally proposed to form on terraces following extraction of metal atoms from step edges and subsequent combination with sulfur on the terraces. However, even when Th is is the au tho r’s pe er re vie we d, ac ce pte d m an us cri pt. H ow ev er , th e o nli ne ve rsi on of re co rd w ill be di ffe re nt fro m thi s v er sio n o nc e i t h as be en co py ed ite d a nd ty pe se t. PL EA SE C IT E TH IS A RT IC LE A S DO I: 10 .11 16 /6. 00 01 40 8\",\"PeriodicalId\":17490,\"journal\":{\"name\":\"Journal of Vacuum Science & Technology A\",\"volume\":\"42 1\",\"pages\":\"\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2022-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Vacuum Science & Technology A\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1116/6.0001408\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, COATINGS & FILMS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Vacuum Science & Technology A","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1116/6.0001408","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
引用次数: 0
摘要
微量硫吸附在铸币金属(111)表面的倾向显著增强表面动力学已经被STM观测到加速了Cu和Ag的二维岛衰变。人们普遍认为,这种增强是由于形成了吸附的金属-硫配合物,促进了金属的表面质量运输。这些配合物最初被认为是在台阶边缘提取金属原子并随后与台阶上的硫结合后形成的。然而,即使当届非盟tho r pe er再保险vie我们d, ac ce pte d m一个我们中国国际广播电台pt。H噢ev, Th e o nli ne ve rsi的再保险公司rd就di ffe再保险nt来回m thi s v er sio n o数控e i t H en . py ed尽管d和泰pe se t。EA se PL C, e Th是RT IC LE我:10厚16/6。00 01 40 8
Sulfur-enhanced dynamics of coinage metal(111) surfaces: Step edges versus terraces as locations for metal-sulfur complex formation
The propensity of trace amounts of sulfur adsorbed on coinage metal(111) surfaces to dramatically enhance surface dynamics has been demonstrated by STM observations of accelerated 2D island decay for Cu and Ag. It is generally accepted that this enhancement is due to the formation of adsorbed metal-sulfur complexes which facilitate surface mass transport of the metal. These complexes were originally proposed to form on terraces following extraction of metal atoms from step edges and subsequent combination with sulfur on the terraces. However, even when Th is is the au tho r’s pe er re vie we d, ac ce pte d m an us cri pt. H ow ev er , th e o nli ne ve rsi on of re co rd w ill be di ffe re nt fro m thi s v er sio n o nc e i t h as be en co py ed ite d a nd ty pe se t. PL EA SE C IT E TH IS A RT IC LE A S DO I: 10 .11 16 /6. 00 01 40 8
期刊介绍:
Journal of Vacuum Science & Technology A publishes reports of original research, letters, and review articles that focus on fundamental scientific understanding of interfaces, surfaces, plasmas and thin films and on using this understanding to advance the state-of-the-art in various technological applications.