{"title":"在铟镓锌氧化物前后通道中掺杂氟,提高了晶体管抗氢稳定性","authors":"Changjun No, Chang-Yun Na, Sung M. Cho","doi":"10.1016/j.mssp.2025.110147","DOIUrl":null,"url":null,"abstract":"<div><div>The impact of fluorine (F) doping on the hydrogen stability of indium-gallium-zinc oxide (IGZO) thin-film transistors (TFTs) was systematically investigated. Enhanced hydrogen resistance was achieved by independently introducing F into both the front and back channels of IGZO. The role of F was elucidated by analyzing changes in device characteristics under directional hydrogen exposure, depending on the specific F-doping location. F atoms in IGZO preferentially attract and immobilize incoming hydrogen, effectively mitigating its adverse impact on electrical performance. Notably, even F doping confined to the back channel—remote from the conductive front channel—yielded substantial improvements in stability, while additional doping in the front channel provided further enhancement. These findings experimentally demonstrate that dual-side F-doping in IGZO significantly enhances the hydrogen tolerance of TFTs.</div></div>","PeriodicalId":18240,"journal":{"name":"Materials Science in Semiconductor Processing","volume":"202 ","pages":"Article 110147"},"PeriodicalIF":4.6000,"publicationDate":"2025-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Improved transistor stability against hydrogen by fluorine doping in indium-gallium-zinc-oxide front and back channels\",\"authors\":\"Changjun No, Chang-Yun Na, Sung M. Cho\",\"doi\":\"10.1016/j.mssp.2025.110147\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The impact of fluorine (F) doping on the hydrogen stability of indium-gallium-zinc oxide (IGZO) thin-film transistors (TFTs) was systematically investigated. Enhanced hydrogen resistance was achieved by independently introducing F into both the front and back channels of IGZO. The role of F was elucidated by analyzing changes in device characteristics under directional hydrogen exposure, depending on the specific F-doping location. F atoms in IGZO preferentially attract and immobilize incoming hydrogen, effectively mitigating its adverse impact on electrical performance. Notably, even F doping confined to the back channel—remote from the conductive front channel—yielded substantial improvements in stability, while additional doping in the front channel provided further enhancement. These findings experimentally demonstrate that dual-side F-doping in IGZO significantly enhances the hydrogen tolerance of TFTs.</div></div>\",\"PeriodicalId\":18240,\"journal\":{\"name\":\"Materials Science in Semiconductor Processing\",\"volume\":\"202 \",\"pages\":\"Article 110147\"},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2025-10-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Science in Semiconductor Processing\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1369800125008856\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science in Semiconductor Processing","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1369800125008856","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
Improved transistor stability against hydrogen by fluorine doping in indium-gallium-zinc-oxide front and back channels
The impact of fluorine (F) doping on the hydrogen stability of indium-gallium-zinc oxide (IGZO) thin-film transistors (TFTs) was systematically investigated. Enhanced hydrogen resistance was achieved by independently introducing F into both the front and back channels of IGZO. The role of F was elucidated by analyzing changes in device characteristics under directional hydrogen exposure, depending on the specific F-doping location. F atoms in IGZO preferentially attract and immobilize incoming hydrogen, effectively mitigating its adverse impact on electrical performance. Notably, even F doping confined to the back channel—remote from the conductive front channel—yielded substantial improvements in stability, while additional doping in the front channel provided further enhancement. These findings experimentally demonstrate that dual-side F-doping in IGZO significantly enhances the hydrogen tolerance of TFTs.
期刊介绍:
Materials Science in Semiconductor Processing provides a unique forum for the discussion of novel processing, applications and theoretical studies of functional materials and devices for (opto)electronics, sensors, detectors, biotechnology and green energy.
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Coverage will include: advanced lithography for submicron devices; etching and related topics; ion implantation; damage evolution and related issues; plasma and thermal CVD; rapid thermal processing; advanced metallization and interconnect schemes; thin dielectric layers, oxidation; sol-gel processing; chemical bath and (electro)chemical deposition; compound semiconductor processing; new non-oxide materials and their applications; (macro)molecular and hybrid materials; molecular dynamics, ab-initio methods, Monte Carlo, etc.; new materials and processes for discrete and integrated circuits; magnetic materials and spintronics; heterostructures and quantum devices; engineering of the electrical and optical properties of semiconductors; crystal growth mechanisms; reliability, defect density, intrinsic impurities and defects.