{"title":"刺激反应共价有机框架的最新进展：从机制到应用","authors":"Shen Xu, Shengqiang Xue, Le Yu and Qichun Zhang","doi":"10.1039/D5TC02640G","DOIUrl":null,"url":null,"abstract":"<p >Stimuli-responsive covalent organic frameworks (COFs) represent an emerging class of adaptive materials that synergize dynamic behavior with inherent porosity. This integration facilitates multi-stimuli responsiveness and confers substantial application potential across diverse domains. Herein, we systematically review stimuli-responsive behaviors and related mechanisms of smart COFs under physical, chemical, and combinatorial stimuli. Contemporary advances in material design are critically evaluated to correlate structural motifs with application performance in next-generation devices. Current research challenges and future development perspectives are analyzed to advance molecular engineering strategies. This work aims to establish foundational design principles for extending stimuli-responsive COF functionality to unexplored application scenarios.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 39","pages":" 19949-19982"},"PeriodicalIF":5.1000,"publicationDate":"2025-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent advances in stimuli-responsive covalent organic frameworks: from mechanisms to applications\",\"authors\":\"Shen Xu, Shengqiang Xue, Le Yu and Qichun Zhang\",\"doi\":\"10.1039/D5TC02640G\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Stimuli-responsive covalent organic frameworks (COFs) represent an emerging class of adaptive materials that synergize dynamic behavior with inherent porosity. This integration facilitates multi-stimuli responsiveness and confers substantial application potential across diverse domains. Herein, we systematically review stimuli-responsive behaviors and related mechanisms of smart COFs under physical, chemical, and combinatorial stimuli. Contemporary advances in material design are critically evaluated to correlate structural motifs with application performance in next-generation devices. Current research challenges and future development perspectives are analyzed to advance molecular engineering strategies. This work aims to establish foundational design principles for extending stimuli-responsive COF functionality to unexplored application scenarios.</p>\",\"PeriodicalId\":84,\"journal\":{\"name\":\"Journal of Materials Chemistry C\",\"volume\":\" 39\",\"pages\":\" 19949-19982\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2025-08-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Chemistry C\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/tc/d5tc02640g\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry C","FirstCategoryId":"1","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/tc/d5tc02640g","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Recent advances in stimuli-responsive covalent organic frameworks: from mechanisms to applications
Stimuli-responsive covalent organic frameworks (COFs) represent an emerging class of adaptive materials that synergize dynamic behavior with inherent porosity. This integration facilitates multi-stimuli responsiveness and confers substantial application potential across diverse domains. Herein, we systematically review stimuli-responsive behaviors and related mechanisms of smart COFs under physical, chemical, and combinatorial stimuli. Contemporary advances in material design are critically evaluated to correlate structural motifs with application performance in next-generation devices. Current research challenges and future development perspectives are analyzed to advance molecular engineering strategies. This work aims to establish foundational design principles for extending stimuli-responsive COF functionality to unexplored application scenarios.
期刊介绍：
The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study:
Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability.
Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine.
Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices.
Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive.
Bioelectronics
Conductors
Detectors
Dielectrics
Displays
Ferroelectrics
Lasers
LEDs
Lighting
Liquid crystals
Memory
Metamaterials
Multiferroics
Photonics
Photovoltaics
Semiconductors
Sensors
Single molecule conductors
Spintronics
Superconductors
Thermoelectrics
Topological insulators
Transistors
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