磺酸离子液体的x射线光电子能谱：探讨烷基取代基对阴离子电子环境的影响

IF 1.5 4区物理与天体物理 Q2 SPECTROSCOPY

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2025-08-12 DOI:10.1016/j.elspec.2025.147562

Xin Li, Li Wei, Shuang Men

{"title":"磺酸离子液体的x射线光电子能谱：探讨烷基取代基对阴离子电子环境的影响","authors":"Xin Li, Li Wei, Shuang Men","doi":"10.1016/j.elspec.2025.147562","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, five sulfonium ionic liquids are analysed by X-ray photoelectron spectroscopy. The surface purity and C 1s fitting model are discussed in details. The influence of alkyl chain length on the aliphatic carbon binding energy is illustrated by comparing ethyl- and butyl-based cations. The impact of the cation on the electronic environment of the anion-based components is demonstrated. It is found that the cation-anion interactions can be significantly affected by the structure of the cation.</div></div>","PeriodicalId":15726,"journal":{"name":"Journal of Electron Spectroscopy and Related Phenomena","volume":"282 ","pages":"Article 147562"},"PeriodicalIF":1.5000,"publicationDate":"2025-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"X-ray photoelectron spectroscopy of sulfonium ionic liquids: Probing the impact of alkyl substituent on the electronic environment of the anion\",\"authors\":\"Xin Li, Li Wei, Shuang Men\",\"doi\":\"10.1016/j.elspec.2025.147562\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this study, five sulfonium ionic liquids are analysed by X-ray photoelectron spectroscopy. The surface purity and C 1s fitting model are discussed in details. The influence of alkyl chain length on the aliphatic carbon binding energy is illustrated by comparing ethyl- and butyl-based cations. The impact of the cation on the electronic environment of the anion-based components is demonstrated. It is found that the cation-anion interactions can be significantly affected by the structure of the cation.</div></div>\",\"PeriodicalId\":15726,\"journal\":{\"name\":\"Journal of Electron Spectroscopy and Related Phenomena\",\"volume\":\"282 \",\"pages\":\"Article 147562\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2025-08-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Electron Spectroscopy and Related Phenomena\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0368204825000490\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"SPECTROSCOPY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electron Spectroscopy and Related Phenomena","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0368204825000490","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"SPECTROSCOPY","Score":null,"Total":0}

引用次数: 0

摘要

本文用x射线光电子能谱对5种磺胺离子液体进行了分析。详细讨论了表面纯度和c1s拟合模型。通过比较乙基和丁基阳离子，说明烷基链长对脂肪碳结合能的影响。证明了阳离子对阴离子基元件电子环境的影响。研究发现，阳离子的结构对阳离子-阴离子相互作用有显著影响。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

X-ray photoelectron spectroscopy of sulfonium ionic liquids: Probing the impact of alkyl substituent on the electronic environment of the anion

In this study, five sulfonium ionic liquids are analysed by X-ray photoelectron spectroscopy. The surface purity and C 1s fitting model are discussed in details. The influence of alkyl chain length on the aliphatic carbon binding energy is illustrated by comparing ethyl- and butyl-based cations. The impact of the cation on the electronic environment of the anion-based components is demonstrated. It is found that the cation-anion interactions can be significantly affected by the structure of the cation.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Electron Spectroscopy and Related Phenomena 物理-光谱学

CiteScore

3.30

自引率

5.30%

发文量

审稿时长

60 days

期刊介绍： The Journal of Electron Spectroscopy and Related Phenomena publishes experimental, theoretical and applied work in the field of electron spectroscopy and electronic structure, involving techniques which use high energy photons (>10 eV) or electrons as probes or detected particles in the investigation.