Denver Strong, Danrui Ni, Xianghan Xu and R. J. Cava
{"title":"(TiZrHf)95Sc5多晶的异常电阻率和超导性","authors":"Denver Strong, Danrui Ni, Xianghan Xu and R. J. Cava","doi":"10.1039/D5TC00672D","DOIUrl":null,"url":null,"abstract":"<p >Three polymorphs of (TiZrHf)<small><sub>95</sub></small>Sc<small><sub>5</sub></small>, one of which is glassy, are identified. The materials are the result of splat cooling arc melted samples. The temperature-dependent resistivities of the body centered cubic and amorphous materials are anomalous. Low temperature resistivity and heat capacity measurements indicate that superconducting transitions are present when the material has either a body centered cubic (<em>T</em><small><sub>C</sub></small> ∼ 1.5 K) or hexagonal close packed (<em>T</em><small><sub>C</sub></small> ∼ 0.8 K) crystal structure and the superconductivity of the amorphous phase below 0.65 K cannot be ruled out. We include evidence of a robust critical field in the body centered cubic material.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 30","pages":" 15390-15397"},"PeriodicalIF":5.1000,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/tc/d5tc00672d?page=search","citationCount":"0","resultStr":"{\"title\":\"Anomalous resistivity and superconductivity in the polymorphs of (TiZrHf)95Sc5\",\"authors\":\"Denver Strong, Danrui Ni, Xianghan Xu and R. J. Cava\",\"doi\":\"10.1039/D5TC00672D\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Three polymorphs of (TiZrHf)<small><sub>95</sub></small>Sc<small><sub>5</sub></small>, one of which is glassy, are identified. The materials are the result of splat cooling arc melted samples. The temperature-dependent resistivities of the body centered cubic and amorphous materials are anomalous. Low temperature resistivity and heat capacity measurements indicate that superconducting transitions are present when the material has either a body centered cubic (<em>T</em><small><sub>C</sub></small> ∼ 1.5 K) or hexagonal close packed (<em>T</em><small><sub>C</sub></small> ∼ 0.8 K) crystal structure and the superconductivity of the amorphous phase below 0.65 K cannot be ruled out. We include evidence of a robust critical field in the body centered cubic material.</p>\",\"PeriodicalId\":84,\"journal\":{\"name\":\"Journal of Materials Chemistry C\",\"volume\":\" 30\",\"pages\":\" 15390-15397\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2025-06-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2025/tc/d5tc00672d?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Chemistry C\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/tc/d5tc00672d\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry C","FirstCategoryId":"1","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/tc/d5tc00672d","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Anomalous resistivity and superconductivity in the polymorphs of (TiZrHf)95Sc5
Three polymorphs of (TiZrHf)95Sc5, one of which is glassy, are identified. The materials are the result of splat cooling arc melted samples. The temperature-dependent resistivities of the body centered cubic and amorphous materials are anomalous. Low temperature resistivity and heat capacity measurements indicate that superconducting transitions are present when the material has either a body centered cubic (TC ∼ 1.5 K) or hexagonal close packed (TC ∼ 0.8 K) crystal structure and the superconductivity of the amorphous phase below 0.65 K cannot be ruled out. We include evidence of a robust critical field in the body centered cubic material.
期刊介绍:
The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study:
Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability.
Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine.
Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices.
Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive.
Bioelectronics
Conductors
Detectors
Dielectrics
Displays
Ferroelectrics
Lasers
LEDs
Lighting
Liquid crystals
Memory
Metamaterials
Multiferroics
Photonics
Photovoltaics
Semiconductors
Sensors
Single molecule conductors
Spintronics
Superconductors
Thermoelectrics
Topological insulators
Transistors