{"title":"支持VOCs动态监测的高光谱成像技术:一种突破性的高时空分辨率检测方法。","authors":"Yikai Li, Chengzhi Xing*, Jian Chen, Peiyuan Jiao, Chao Liu, Jiale Fang and Cheng Liu*, ","doi":"10.1021/acs.analchem.5c00837","DOIUrl":null,"url":null,"abstract":"<p >Volatile organic compounds (VOCs) and their secondary pollutants pose significant risks to both the environment and human health. In response to air pollution control policies, the emissions of conventional pollutants, such as NO<sub>2</sub> and SO<sub>2</sub>, have been preliminarily controlled. As a result, the reduction of VOC emissions has become a key measure for further improving air quality. Industrial activities are the primary anthropogenic source of VOCs, highlighting the urgent need for effective methods to detect VOC plume concentrations and monitor their dispersion and transport. This study proposes a hyperspectral rapid imaging system (HRIS), which achieves innovative advancements in noise removal, signal enhancement, and chromatic aberration correction. These breakthroughs enable, for the first time, high spatiotemporal resolution and synchronous observation of multiple VOC components, with final imaging results available within minutes. In two experimental setups, the system successfully measured the concentrations and emission fluxes of formaldehyde (HCHO), nitrobenzene (C<sub>6</sub>H<sub>5</sub>NO<sub>2</sub>), benzoic acid (CH<sub>3</sub>C<sub>6</sub>H<sub>3</sub>O<sub>2</sub>), nitrogen dioxide (NO<sub>2</sub>), and sulfur dioxide (SO<sub>2</sub>), with the highest emission flux recorded at 0.45 ± 0.13 kg/h. The application of HRIS facilitates the development of dynamic VOC emission inventories, providing critical data to support the design of future emission reduction strategies.</p>","PeriodicalId":27,"journal":{"name":"Analytical Chemistry","volume":"97 26","pages":"13840–13849"},"PeriodicalIF":6.7000,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hyperspectral Imaging Technology Empowering Dynamic Monitoring of VOCs: A Breakthrough High-Spatial-Temporal Resolution Detection Method\",\"authors\":\"Yikai Li, Chengzhi Xing*, Jian Chen, Peiyuan Jiao, Chao Liu, Jiale Fang and Cheng Liu*, \",\"doi\":\"10.1021/acs.analchem.5c00837\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Volatile organic compounds (VOCs) and their secondary pollutants pose significant risks to both the environment and human health. In response to air pollution control policies, the emissions of conventional pollutants, such as NO<sub>2</sub> and SO<sub>2</sub>, have been preliminarily controlled. As a result, the reduction of VOC emissions has become a key measure for further improving air quality. Industrial activities are the primary anthropogenic source of VOCs, highlighting the urgent need for effective methods to detect VOC plume concentrations and monitor their dispersion and transport. This study proposes a hyperspectral rapid imaging system (HRIS), which achieves innovative advancements in noise removal, signal enhancement, and chromatic aberration correction. These breakthroughs enable, for the first time, high spatiotemporal resolution and synchronous observation of multiple VOC components, with final imaging results available within minutes. In two experimental setups, the system successfully measured the concentrations and emission fluxes of formaldehyde (HCHO), nitrobenzene (C<sub>6</sub>H<sub>5</sub>NO<sub>2</sub>), benzoic acid (CH<sub>3</sub>C<sub>6</sub>H<sub>3</sub>O<sub>2</sub>), nitrogen dioxide (NO<sub>2</sub>), and sulfur dioxide (SO<sub>2</sub>), with the highest emission flux recorded at 0.45 ± 0.13 kg/h. The application of HRIS facilitates the development of dynamic VOC emission inventories, providing critical data to support the design of future emission reduction strategies.</p>\",\"PeriodicalId\":27,\"journal\":{\"name\":\"Analytical Chemistry\",\"volume\":\"97 26\",\"pages\":\"13840–13849\"},\"PeriodicalIF\":6.7000,\"publicationDate\":\"2025-06-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.analchem.5c00837\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.analchem.5c00837","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Hyperspectral Imaging Technology Empowering Dynamic Monitoring of VOCs: A Breakthrough High-Spatial-Temporal Resolution Detection Method
Volatile organic compounds (VOCs) and their secondary pollutants pose significant risks to both the environment and human health. In response to air pollution control policies, the emissions of conventional pollutants, such as NO2 and SO2, have been preliminarily controlled. As a result, the reduction of VOC emissions has become a key measure for further improving air quality. Industrial activities are the primary anthropogenic source of VOCs, highlighting the urgent need for effective methods to detect VOC plume concentrations and monitor their dispersion and transport. This study proposes a hyperspectral rapid imaging system (HRIS), which achieves innovative advancements in noise removal, signal enhancement, and chromatic aberration correction. These breakthroughs enable, for the first time, high spatiotemporal resolution and synchronous observation of multiple VOC components, with final imaging results available within minutes. In two experimental setups, the system successfully measured the concentrations and emission fluxes of formaldehyde (HCHO), nitrobenzene (C6H5NO2), benzoic acid (CH3C6H3O2), nitrogen dioxide (NO2), and sulfur dioxide (SO2), with the highest emission flux recorded at 0.45 ± 0.13 kg/h. The application of HRIS facilitates the development of dynamic VOC emission inventories, providing critical data to support the design of future emission reduction strategies.
期刊介绍:
Analytical Chemistry, a peer-reviewed research journal, focuses on disseminating new and original knowledge across all branches of analytical chemistry. Fundamental articles may explore general principles of chemical measurement science and need not directly address existing or potential analytical methodology. They can be entirely theoretical or report experimental results. Contributions may cover various phases of analytical operations, including sampling, bioanalysis, electrochemistry, mass spectrometry, microscale and nanoscale systems, environmental analysis, separations, spectroscopy, chemical reactions and selectivity, instrumentation, imaging, surface analysis, and data processing. Papers discussing known analytical methods should present a significant, original application of the method, a notable improvement, or results on an important analyte.