支持VOCs动态监测的高光谱成像技术:一种突破性的高时空分辨率检测方法。

IF 6.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL
Yikai Li, Chengzhi Xing*, Jian Chen, Peiyuan Jiao, Chao Liu, Jiale Fang and Cheng Liu*, 
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引用次数: 0

摘要

挥发性有机化合物(VOCs)及其二次污染物对环境和人类健康构成重大风险。根据大气污染治理政策,NO2、SO2等常规污染物的排放得到初步控制。因此,减少挥发性有机化合物的排放已成为进一步改善空气质素的重要措施。工业活动是挥发性有机化合物的主要人为来源,因此迫切需要有效的方法来检测挥发性有机化合物羽流浓度并监测其扩散和运输。本研究提出了一种高光谱快速成像系统(HRIS),该系统在去噪、信号增强和色差校正方面取得了创新进展。这些突破首次实现了对多个VOC组分的高时空分辨率和同步观测,并在几分钟内获得最终成像结果。在两个实验装置中,该系统成功测量了甲醛(HCHO)、硝基苯(C6H5NO2)、苯甲酸(CH3C6H3O2)、二氧化氮(NO2)和二氧化硫(SO2)的浓度和排放通量,最大排放通量为0.45±0.13 kg/h。HRIS的应用有助于开发动态VOC排放清单,为未来减排策略的设计提供关键数据支持。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Hyperspectral Imaging Technology Empowering Dynamic Monitoring of VOCs: A Breakthrough High-Spatial-Temporal Resolution Detection Method

Hyperspectral Imaging Technology Empowering Dynamic Monitoring of VOCs: A Breakthrough High-Spatial-Temporal Resolution Detection Method

Volatile organic compounds (VOCs) and their secondary pollutants pose significant risks to both the environment and human health. In response to air pollution control policies, the emissions of conventional pollutants, such as NO2 and SO2, have been preliminarily controlled. As a result, the reduction of VOC emissions has become a key measure for further improving air quality. Industrial activities are the primary anthropogenic source of VOCs, highlighting the urgent need for effective methods to detect VOC plume concentrations and monitor their dispersion and transport. This study proposes a hyperspectral rapid imaging system (HRIS), which achieves innovative advancements in noise removal, signal enhancement, and chromatic aberration correction. These breakthroughs enable, for the first time, high spatiotemporal resolution and synchronous observation of multiple VOC components, with final imaging results available within minutes. In two experimental setups, the system successfully measured the concentrations and emission fluxes of formaldehyde (HCHO), nitrobenzene (C6H5NO2), benzoic acid (CH3C6H3O2), nitrogen dioxide (NO2), and sulfur dioxide (SO2), with the highest emission flux recorded at 0.45 ± 0.13 kg/h. The application of HRIS facilitates the development of dynamic VOC emission inventories, providing critical data to support the design of future emission reduction strategies.

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来源期刊
Analytical Chemistry
Analytical Chemistry 化学-分析化学
CiteScore
12.10
自引率
12.20%
发文量
1949
审稿时长
1.4 months
期刊介绍: Analytical Chemistry, a peer-reviewed research journal, focuses on disseminating new and original knowledge across all branches of analytical chemistry. Fundamental articles may explore general principles of chemical measurement science and need not directly address existing or potential analytical methodology. They can be entirely theoretical or report experimental results. Contributions may cover various phases of analytical operations, including sampling, bioanalysis, electrochemistry, mass spectrometry, microscale and nanoscale systems, environmental analysis, separations, spectroscopy, chemical reactions and selectivity, instrumentation, imaging, surface analysis, and data processing. Papers discussing known analytical methods should present a significant, original application of the method, a notable improvement, or results on an important analyte.
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