N. Ajmal, Visakh Mohanan, Rani Pavithran, S. Rani, Ananthan D. Thampi, E. Sneha
{"title":"以油酸二辛酯铵离子液体为添加剂的导电米糠油基润滑剂的润滑性能评价","authors":"N. Ajmal, Visakh Mohanan, Rani Pavithran, S. Rani, Ananthan D. Thampi, E. Sneha","doi":"10.1002/aocs.12938","DOIUrl":null,"url":null,"abstract":"<p>The growing environmental consciousness and research into green lubricant technology in various industries has drawn a lot of attention to vegetable oils. The major negative aspect of vegetable oil is its poor oxidation stability. Recent research in ionic liquids (ILs) showed its potential as a base fluid and additive for lubricant applications. These are organic salts that dissolve at temperatures below 100°C. Among the potential characteristics of ILs are their non-volatility, high oxidation stability, non-flammability, and high conductivity to heat and electricity. The present study synthesized a protic ionic liquid named dioctyl ammonium oleate (DAO). The optimum DAO percentage in rice bran oil (RBO) was then optimized based on the tribological properties. The electrical conductivity and basic lubricant properties, such as physicochemical, oxidation stability, corrosion stability, thermal properties, and extreme pressure capability of the optimized RBO-DAO blend were evaluated and compared with RBO. The developed RBO-DAO blend shows the potential to be used as a base fluid for electrical conductive lubricants due to its significantly enhanced electrical conductivity, better oxidation stability, and superior tribological properties. The optimum DAO weight percentage in RBO is 2 wt%. The results show the potential of electrical conductive lubricant developed to enhance the performance of electrical equipment, reduce static electricity in industrial machinery, and prevent lubricant degradation in the presence of electric current. The components of electric vehicles, such as bearings, pads, seals, and gear, also require electrical conductive lubricants to avoid premature failure and electromagnetic interference problems. The developed lubricant can be considered a potential alternative in various industries such as automotive, renewable systems, medical devices, robotics, high-speed machining, and so forth.</p>","PeriodicalId":17182,"journal":{"name":"Journal of the American Oil Chemists Society","volume":"102 5","pages":"903-912"},"PeriodicalIF":1.9000,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Lubricant property evaluation of electrical conductive rice bran oil-based lubricant with dioctyl ammonium oleate ionic liquid as an additive\",\"authors\":\"N. Ajmal, Visakh Mohanan, Rani Pavithran, S. Rani, Ananthan D. Thampi, E. Sneha\",\"doi\":\"10.1002/aocs.12938\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The growing environmental consciousness and research into green lubricant technology in various industries has drawn a lot of attention to vegetable oils. The major negative aspect of vegetable oil is its poor oxidation stability. Recent research in ionic liquids (ILs) showed its potential as a base fluid and additive for lubricant applications. These are organic salts that dissolve at temperatures below 100°C. Among the potential characteristics of ILs are their non-volatility, high oxidation stability, non-flammability, and high conductivity to heat and electricity. The present study synthesized a protic ionic liquid named dioctyl ammonium oleate (DAO). The optimum DAO percentage in rice bran oil (RBO) was then optimized based on the tribological properties. The electrical conductivity and basic lubricant properties, such as physicochemical, oxidation stability, corrosion stability, thermal properties, and extreme pressure capability of the optimized RBO-DAO blend were evaluated and compared with RBO. The developed RBO-DAO blend shows the potential to be used as a base fluid for electrical conductive lubricants due to its significantly enhanced electrical conductivity, better oxidation stability, and superior tribological properties. The optimum DAO weight percentage in RBO is 2 wt%. The results show the potential of electrical conductive lubricant developed to enhance the performance of electrical equipment, reduce static electricity in industrial machinery, and prevent lubricant degradation in the presence of electric current. The components of electric vehicles, such as bearings, pads, seals, and gear, also require electrical conductive lubricants to avoid premature failure and electromagnetic interference problems. The developed lubricant can be considered a potential alternative in various industries such as automotive, renewable systems, medical devices, robotics, high-speed machining, and so forth.</p>\",\"PeriodicalId\":17182,\"journal\":{\"name\":\"Journal of the American Oil Chemists Society\",\"volume\":\"102 5\",\"pages\":\"903-912\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2025-01-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the American Oil Chemists Society\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/aocs.12938\",\"RegionNum\":4,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Oil Chemists Society","FirstCategoryId":"97","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aocs.12938","RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Lubricant property evaluation of electrical conductive rice bran oil-based lubricant with dioctyl ammonium oleate ionic liquid as an additive
The growing environmental consciousness and research into green lubricant technology in various industries has drawn a lot of attention to vegetable oils. The major negative aspect of vegetable oil is its poor oxidation stability. Recent research in ionic liquids (ILs) showed its potential as a base fluid and additive for lubricant applications. These are organic salts that dissolve at temperatures below 100°C. Among the potential characteristics of ILs are their non-volatility, high oxidation stability, non-flammability, and high conductivity to heat and electricity. The present study synthesized a protic ionic liquid named dioctyl ammonium oleate (DAO). The optimum DAO percentage in rice bran oil (RBO) was then optimized based on the tribological properties. The electrical conductivity and basic lubricant properties, such as physicochemical, oxidation stability, corrosion stability, thermal properties, and extreme pressure capability of the optimized RBO-DAO blend were evaluated and compared with RBO. The developed RBO-DAO blend shows the potential to be used as a base fluid for electrical conductive lubricants due to its significantly enhanced electrical conductivity, better oxidation stability, and superior tribological properties. The optimum DAO weight percentage in RBO is 2 wt%. The results show the potential of electrical conductive lubricant developed to enhance the performance of electrical equipment, reduce static electricity in industrial machinery, and prevent lubricant degradation in the presence of electric current. The components of electric vehicles, such as bearings, pads, seals, and gear, also require electrical conductive lubricants to avoid premature failure and electromagnetic interference problems. The developed lubricant can be considered a potential alternative in various industries such as automotive, renewable systems, medical devices, robotics, high-speed machining, and so forth.
期刊介绍:
The Journal of the American Oil Chemists’ Society (JAOCS) is an international peer-reviewed journal that publishes significant original scientific research and technological advances on fats, oils, oilseed proteins, and related materials through original research articles, invited reviews, short communications, and letters to the editor. We seek to publish reports that will significantly advance scientific understanding through hypothesis driven research, innovations, and important new information pertaining to analysis, properties, processing, products, and applications of these food and industrial resources. Breakthroughs in food science and technology, biotechnology (including genomics, biomechanisms, biocatalysis and bioprocessing), and industrial products and applications are particularly appropriate.
JAOCS also considers reports on the lipid composition of new, unique, and traditional sources of lipids that definitively address a research hypothesis and advances scientific understanding. However, the genus and species of the source must be verified by appropriate means of classification. In addition, the GPS location of the harvested materials and seed or vegetative samples should be deposited in an accredited germplasm repository. Compositional data suitable for Original Research Articles must embody replicated estimate of tissue constituents, such as oil, protein, carbohydrate, fatty acid, phospholipid, tocopherol, sterol, and carotenoid compositions. Other components unique to the specific plant or animal source may be reported. Furthermore, lipid composition papers should incorporate elements of yeartoyear, environmental, and/ or cultivar variations through use of appropriate statistical analyses.