Sotaro Kusumoto, Shunya Masuda, Ryo Suzuki, Masaru Tachibana, Masaya Shimabukuro, Mamiko Kobayashi, Naoki Ogiwara, Sayaka Uchida, Tomoya Fukui, Yuta Tsuji, Masaya Okamura, Shiro Hikichi, Yang Kim and Yoshihiro Koide
{"title":"柔性有机-无机杂化晶体的锡（iv）氯化物和萘二亚胺：探索弹性，机械变色，和光热转换†","authors":"Sotaro Kusumoto, Shunya Masuda, Ryo Suzuki, Masaru Tachibana, Masaya Shimabukuro, Mamiko Kobayashi, Naoki Ogiwara, Sayaka Uchida, Tomoya Fukui, Yuta Tsuji, Masaya Okamura, Shiro Hikichi, Yang Kim and Yoshihiro Koide","doi":"10.1039/D5TC00891C","DOIUrl":null,"url":null,"abstract":"<p >Organic–inorganic hybrid metal halides (OIMHs) are emerging functional materials with diverse applications. However, the exploration of mechanically soft OIMHs remains limited. This study introduces tin(<small>IV</small>) OIMH crystals (<strong>1</strong> and <strong>1w</strong>), incorporating a naphthalenediimide (NDI)-based organic cation (<strong>3pmNDI</strong>), which exhibit elastic flexibility, mechanochromism, and photothermal conversion. The unique one-dimensional (1D) slip-stacked assembly of <strong>3pmNDI</strong> cations, influenced by the presence or absence of lattice water (<strong>1w</strong><em>vs.</em><strong>1</strong>), dictates their mechanical properties and chromic behavior. Compound <strong>1</strong> exhibits an exceptionally low elastic modulus (<em>E</em><small><sub>r</sub></small> = 1.84 ± 0.21 GPa), as measured by nanoindentation, and a photothermal conversion efficiency of 63%. These findings showcase the potential of OIMHs as multifunctional flexible crystals.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 17","pages":" 8470-8478"},"PeriodicalIF":5.1000,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/tc/d5tc00891c?page=search","citationCount":"0","resultStr":"{\"title\":\"Flexible organic–inorganic hybrid crystals of tin(iv) chloride and naphthalenediimide: exploring elasticity, mechanochromism, and photothermal conversion†\",\"authors\":\"Sotaro Kusumoto, Shunya Masuda, Ryo Suzuki, Masaru Tachibana, Masaya Shimabukuro, Mamiko Kobayashi, Naoki Ogiwara, Sayaka Uchida, Tomoya Fukui, Yuta Tsuji, Masaya Okamura, Shiro Hikichi, Yang Kim and Yoshihiro Koide\",\"doi\":\"10.1039/D5TC00891C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Organic–inorganic hybrid metal halides (OIMHs) are emerging functional materials with diverse applications. However, the exploration of mechanically soft OIMHs remains limited. This study introduces tin(<small>IV</small>) OIMH crystals (<strong>1</strong> and <strong>1w</strong>), incorporating a naphthalenediimide (NDI)-based organic cation (<strong>3pmNDI</strong>), which exhibit elastic flexibility, mechanochromism, and photothermal conversion. The unique one-dimensional (1D) slip-stacked assembly of <strong>3pmNDI</strong> cations, influenced by the presence or absence of lattice water (<strong>1w</strong><em>vs.</em><strong>1</strong>), dictates their mechanical properties and chromic behavior. Compound <strong>1</strong> exhibits an exceptionally low elastic modulus (<em>E</em><small><sub>r</sub></small> = 1.84 ± 0.21 GPa), as measured by nanoindentation, and a photothermal conversion efficiency of 63%. These findings showcase the potential of OIMHs as multifunctional flexible crystals.</p>\",\"PeriodicalId\":84,\"journal\":{\"name\":\"Journal of Materials Chemistry C\",\"volume\":\" 17\",\"pages\":\" 8470-8478\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2025-03-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2025/tc/d5tc00891c?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Chemistry C\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/tc/d5tc00891c\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry C","FirstCategoryId":"1","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/tc/d5tc00891c","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Flexible organic–inorganic hybrid crystals of tin(iv) chloride and naphthalenediimide: exploring elasticity, mechanochromism, and photothermal conversion†
Organic–inorganic hybrid metal halides (OIMHs) are emerging functional materials with diverse applications. However, the exploration of mechanically soft OIMHs remains limited. This study introduces tin(IV) OIMH crystals (1 and 1w), incorporating a naphthalenediimide (NDI)-based organic cation (3pmNDI), which exhibit elastic flexibility, mechanochromism, and photothermal conversion. The unique one-dimensional (1D) slip-stacked assembly of 3pmNDI cations, influenced by the presence or absence of lattice water (1wvs.1), dictates their mechanical properties and chromic behavior. Compound 1 exhibits an exceptionally low elastic modulus (Er = 1.84 ± 0.21 GPa), as measured by nanoindentation, and a photothermal conversion efficiency of 63%. These findings showcase the potential of OIMHs as multifunctional flexible crystals.
期刊介绍：
The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study:
Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability.
Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine.
Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices.
Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive.
Bioelectronics
Conductors
Detectors
Dielectrics
Displays
Ferroelectrics
Lasers
LEDs
Lighting
Liquid crystals
Memory
Metamaterials
Multiferroics
Photonics
Photovoltaics
Semiconductors
Sensors
Single molecule conductors
Spintronics
Superconductors
Thermoelectrics
Topological insulators
Transistors
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