{"title":"zif -67模板化NiCoP双金属催化剂提高水裂解性能","authors":"Meijie Ding , Qingsong Yu , Zhiqiang Wei , Dexue Liu","doi":"10.1016/j.mssp.2025.109461","DOIUrl":null,"url":null,"abstract":"<div><div>Efficient electrocatalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are essential to overcoming the slow kinetics of water electrolysis. In this study, a bimetallic NiCoP catalyst with a distinctive hollow structure was synthesized via a ZIF-67 template, followed by etching with Ni<sup>2+</sup> aqueous solution and a subsequent phosphorization process. The resulting material demonstrates exceptional electrochemical performance. In HER, it exhibits excellent catalytic activity, achieving an overpotential of 134.6 mV at a current density of 10 mA cm<sup>−2</sup> and a Tafel slope of 72.3 mV·dec<sup>−1</sup>. For OER, at a current density of 10 mA cm<sup>−2</sup>, the overpotential is 273 mV, with a Tafel slope of 88.9 mV·dec<sup>−1</sup>. Moreover, the catalyst shows excellent long-term stability. Density functional theory (DFT) calculations indicate that the incorporation of Ni into CoP alters the electronic states at the Fermi level, thereby improving its electrical conductivity. This work not only offers novel insights into the structural design of water splitting catalysts but also highlights the promising potential of NiCoP as an efficient catalyst in the energy conversion domain.</div></div>","PeriodicalId":18240,"journal":{"name":"Materials Science in Semiconductor Processing","volume":"192 ","pages":"Article 109461"},"PeriodicalIF":4.6000,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"ZIF-67-templated NiCoP bimetallic catalysts for enhanced water splitting performance\",\"authors\":\"Meijie Ding , Qingsong Yu , Zhiqiang Wei , Dexue Liu\",\"doi\":\"10.1016/j.mssp.2025.109461\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Efficient electrocatalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are essential to overcoming the slow kinetics of water electrolysis. In this study, a bimetallic NiCoP catalyst with a distinctive hollow structure was synthesized via a ZIF-67 template, followed by etching with Ni<sup>2+</sup> aqueous solution and a subsequent phosphorization process. The resulting material demonstrates exceptional electrochemical performance. In HER, it exhibits excellent catalytic activity, achieving an overpotential of 134.6 mV at a current density of 10 mA cm<sup>−2</sup> and a Tafel slope of 72.3 mV·dec<sup>−1</sup>. For OER, at a current density of 10 mA cm<sup>−2</sup>, the overpotential is 273 mV, with a Tafel slope of 88.9 mV·dec<sup>−1</sup>. Moreover, the catalyst shows excellent long-term stability. Density functional theory (DFT) calculations indicate that the incorporation of Ni into CoP alters the electronic states at the Fermi level, thereby improving its electrical conductivity. This work not only offers novel insights into the structural design of water splitting catalysts but also highlights the promising potential of NiCoP as an efficient catalyst in the energy conversion domain.</div></div>\",\"PeriodicalId\":18240,\"journal\":{\"name\":\"Materials Science in Semiconductor Processing\",\"volume\":\"192 \",\"pages\":\"Article 109461\"},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2025-03-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Science in Semiconductor Processing\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1369800125001982\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science in Semiconductor Processing","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1369800125001982","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
摘要
高效的析氢反应(HER)和析氧反应(OER)电催化剂是克服水电解缓慢动力学的必要条件。在本研究中,通过ZIF-67模板合成了具有独特空心结构的双金属NiCoP催化剂,然后用Ni2+水溶液蚀刻,随后进行磷酸化处理。所得材料表现出优异的电化学性能。在HER中,它表现出优异的催化活性,在电流密度为10 mA cm−2时,过电位为134.6 mV, Tafel斜率为72.3 mV·dec−1。对于OER,在电流密度为10 mA cm−2时,过电位为273 mV,塔菲尔斜率为88.9 mV·dec−1。此外,该催化剂还具有良好的长期稳定性。密度泛函理论(DFT)计算表明,Ni加入到CoP中改变了费米能级的电子态,从而提高了其导电性。这项工作不仅为水分解催化剂的结构设计提供了新的见解,而且突出了NiCoP作为一种高效催化剂在能量转换领域的潜力。
ZIF-67-templated NiCoP bimetallic catalysts for enhanced water splitting performance
Efficient electrocatalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are essential to overcoming the slow kinetics of water electrolysis. In this study, a bimetallic NiCoP catalyst with a distinctive hollow structure was synthesized via a ZIF-67 template, followed by etching with Ni2+ aqueous solution and a subsequent phosphorization process. The resulting material demonstrates exceptional electrochemical performance. In HER, it exhibits excellent catalytic activity, achieving an overpotential of 134.6 mV at a current density of 10 mA cm−2 and a Tafel slope of 72.3 mV·dec−1. For OER, at a current density of 10 mA cm−2, the overpotential is 273 mV, with a Tafel slope of 88.9 mV·dec−1. Moreover, the catalyst shows excellent long-term stability. Density functional theory (DFT) calculations indicate that the incorporation of Ni into CoP alters the electronic states at the Fermi level, thereby improving its electrical conductivity. This work not only offers novel insights into the structural design of water splitting catalysts but also highlights the promising potential of NiCoP as an efficient catalyst in the energy conversion domain.
期刊介绍:
Materials Science in Semiconductor Processing provides a unique forum for the discussion of novel processing, applications and theoretical studies of functional materials and devices for (opto)electronics, sensors, detectors, biotechnology and green energy.
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Coverage will include: advanced lithography for submicron devices; etching and related topics; ion implantation; damage evolution and related issues; plasma and thermal CVD; rapid thermal processing; advanced metallization and interconnect schemes; thin dielectric layers, oxidation; sol-gel processing; chemical bath and (electro)chemical deposition; compound semiconductor processing; new non-oxide materials and their applications; (macro)molecular and hybrid materials; molecular dynamics, ab-initio methods, Monte Carlo, etc.; new materials and processes for discrete and integrated circuits; magnetic materials and spintronics; heterostructures and quantum devices; engineering of the electrical and optical properties of semiconductors; crystal growth mechanisms; reliability, defect density, intrinsic impurities and defects.