离子液体引入NH2-MIL-53（Al）混合基质膜耦合UPLC-MS/MS同时测定不同样品中的新烟碱类杀虫剂及其代谢物

IF 9.8 1区农林科学 Q1 CHEMISTRY, APPLIED

Food Chemistry Pub Date : 2025-02-19 DOI:10.1016/j.foodchem.2025.143522

Qitong Xu , Huawei Wang , Ding Chen , Meng Yu , Jun Li , Chang Xie , Yan Cao , Lipan Wang , Surong Mei

{"title":"离子液体引入NH2-MIL-53（Al）混合基质膜耦合UPLC-MS/MS同时测定不同样品中的新烟碱类杀虫剂及其代谢物","authors":"Qitong Xu , Huawei Wang , Ding Chen , Meng Yu , Jun Li , Chang Xie , Yan Cao , Lipan Wang , Surong Mei","doi":"10.1016/j.foodchem.2025.143522","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, a novel hydroxyl-functionalized imidazolium-based ionic liquid introduced metal-organic framework (OH-IL@NH<sub>2</sub>-MIL-53(Al)) was prepared for the extraction of multiple neonicotinoids (NEOs) and their metabolites. The functionalization of ionic liquid obviously enhanced the generate affinity of OH-IL@NH<sub>2</sub>-MIL-53(Al) towards NEOs and their metabolites through the pre-designed hydrogen-bonding and cation-π electron donor–acceptor interactions. Adsorption studies of OH-IL@NH<sub>2</sub>-MIL-53(Al) showed rapid adsorption rates and excellent adsorption capacities (129.3–204.2 mg/g). Furthermore, OH-IL@NH<sub>2</sub>-MIL-53(Al)-based mix matrix membrane (MMM), named OH-IL@NH<sub>2</sub>-MIL-53(Al)-MMM, was prepared for dispersive membrane extraction (DME). The supporting of MMM integrated the OH-IL@NH<sub>2</sub>-MIL-53(Al) powder, greatly simplifying the extraction procedure. A OH-IL@NH<sub>2</sub>-MIL-53(Al)-MMM-based DME-UPLC-MS/MS with good linearity (R<sup>2</sup> ≥ 9987), low limits of detection (LODs, 0.001–0.120 ng/mL), and large enrichment factors (75–112) was developed. Based on the designed adsorbent, this work provides an easy and efficient method for the simultaneous analysis of fourteen NEOs and their metabolites in different samples and achieved satisfactory spiked recoveries (70.1–113.6 %).</div></div>","PeriodicalId":318,"journal":{"name":"Food Chemistry","volume":"477 ","pages":"Article 143522"},"PeriodicalIF":9.8000,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ionic liquid introduced NH2-MIL-53(Al) mixed matrix membrane coupled with UPLC-MS/MS for the simultaneous determination of neonicotinoid insecticides and their metabolites in different samples\",\"authors\":\"Qitong Xu , Huawei Wang , Ding Chen , Meng Yu , Jun Li , Chang Xie , Yan Cao , Lipan Wang , Surong Mei\",\"doi\":\"10.1016/j.foodchem.2025.143522\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this study, a novel hydroxyl-functionalized imidazolium-based ionic liquid introduced metal-organic framework (OH-IL@NH<sub>2</sub>-MIL-53(Al)) was prepared for the extraction of multiple neonicotinoids (NEOs) and their metabolites. The functionalization of ionic liquid obviously enhanced the generate affinity of OH-IL@NH<sub>2</sub>-MIL-53(Al) towards NEOs and their metabolites through the pre-designed hydrogen-bonding and cation-π electron donor–acceptor interactions. Adsorption studies of OH-IL@NH<sub>2</sub>-MIL-53(Al) showed rapid adsorption rates and excellent adsorption capacities (129.3–204.2 mg/g). Furthermore, OH-IL@NH<sub>2</sub>-MIL-53(Al)-based mix matrix membrane (MMM), named OH-IL@NH<sub>2</sub>-MIL-53(Al)-MMM, was prepared for dispersive membrane extraction (DME). The supporting of MMM integrated the OH-IL@NH<sub>2</sub>-MIL-53(Al) powder, greatly simplifying the extraction procedure. A OH-IL@NH<sub>2</sub>-MIL-53(Al)-MMM-based DME-UPLC-MS/MS with good linearity (R<sup>2</sup> ≥ 9987), low limits of detection (LODs, 0.001–0.120 ng/mL), and large enrichment factors (75–112) was developed. Based on the designed adsorbent, this work provides an easy and efficient method for the simultaneous analysis of fourteen NEOs and their metabolites in different samples and achieved satisfactory spiked recoveries (70.1–113.6 %).</div></div>\",\"PeriodicalId\":318,\"journal\":{\"name\":\"Food Chemistry\",\"volume\":\"477 \",\"pages\":\"Article 143522\"},\"PeriodicalIF\":9.8000,\"publicationDate\":\"2025-02-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Food Chemistry\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0308814625007733\",\"RegionNum\":1,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Food Chemistry","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0308814625007733","RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}

引用次数: 0

摘要

本研究制备了一种新型羟基功能化咪唑基离子液体，引入金属有机骨架（OH-IL@NH2-MIL-53(Al)），用于提取多种新烟碱及其代谢物。离子液体的功能化通过预先设计的氢键和阳离子-π电子供体-受体相互作用，明显增强了OH-IL@NH2-MIL-53（Al）对neo及其代谢物的生成亲和力。吸附研究表明，OH-IL@NH2-MIL-53（Al）吸附速率快，吸附量大（129.3 ~ 204.2 mg/g）。制备了OH-IL@NH2-MIL-53（Al）基混合基质膜（MMM），命名为OH-IL@NH2-MIL-53(Al)-MMM，用于分散膜萃取（DME）。MMM的支持整合了OH-IL@NH2-MIL-53（Al）粉末，大大简化了提取过程。建立了基于OH-IL@NH2-MIL-53(Al)- mmm的DME-UPLC-MS/MS，线性良好（R2 ≥ 9987），检出限低（lod 0.001 ~ 0.120 ng/mL），富集因子大（75 ~ 112）。基于所设计的吸附剂，本研究为同时分析不同样品中的14种neo及其代谢物提供了一种简便、高效的方法，并获得了令人满意的加标回收率（70.1 ~ 113.6 %）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Ionic liquid introduced NH2-MIL-53(Al) mixed matrix membrane coupled with UPLC-MS/MS for the simultaneous determination of neonicotinoid insecticides and their metabolites in different samples

查看原文本刊更多论文

Ionic liquid introduced NH2-MIL-53(Al) mixed matrix membrane coupled with UPLC-MS/MS for the simultaneous determination of neonicotinoid insecticides and their metabolites in different samples

In this study, a novel hydroxyl-functionalized imidazolium-based ionic liquid introduced metal-organic framework (OH-IL@NH₂-MIL-53(Al)) was prepared for the extraction of multiple neonicotinoids (NEOs) and their metabolites. The functionalization of ionic liquid obviously enhanced the generate affinity of OH-IL@NH₂-MIL-53(Al) towards NEOs and their metabolites through the pre-designed hydrogen-bonding and cation-π electron donor–acceptor interactions. Adsorption studies of OH-IL@NH₂-MIL-53(Al) showed rapid adsorption rates and excellent adsorption capacities (129.3–204.2 mg/g). Furthermore, OH-IL@NH₂-MIL-53(Al)-based mix matrix membrane (MMM), named OH-IL@NH₂-MIL-53(Al)-MMM, was prepared for dispersive membrane extraction (DME). The supporting of MMM integrated the OH-IL@NH₂-MIL-53(Al) powder, greatly simplifying the extraction procedure. A OH-IL@NH₂-MIL-53(Al)-MMM-based DME-UPLC-MS/MS with good linearity (R² ≥ 9987), low limits of detection (LODs, 0.001–0.120 ng/mL), and large enrichment factors (75–112) was developed. Based on the designed adsorbent, this work provides an easy and efficient method for the simultaneous analysis of fourteen NEOs and their metabolites in different samples and achieved satisfactory spiked recoveries (70.1–113.6 %).

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Food Chemistry 工程技术-食品科技

CiteScore

16.30

自引率

10.20%

发文量

3130

审稿时长

122 days

期刊介绍： Food Chemistry publishes original research papers dealing with the advancement of the chemistry and biochemistry of foods or the analytical methods/ approach used. All papers should focus on the novelty of the research carried out.