Xifeng Hou , Chenbin Ai , Songyu Yang , Jianjun Zhang , Yanfeng Zhang , Jingze Liu
{"title":"利用调谐能带结构设计富双氧空位Bi2O2S0.8F0.4/BiOBr S - scheme异质结用于CO2光还原","authors":"Xifeng Hou , Chenbin Ai , Songyu Yang , Jianjun Zhang , Yanfeng Zhang , Jingze Liu","doi":"10.1016/j.jmat.2024.100998","DOIUrl":null,"url":null,"abstract":"<div><div>S-scheme heterojunction has garnered significant interest owing to its distinctive band structure and interfacial interaction. In this work, nanosheets-like Bi<sub>2</sub>O<sub>2</sub>S<sub>0.8</sub>F<sub>0.4</sub>/BiOBr heterojunction photocatalyst with dual surface oxygen vacancies was synthesized by epitaxial growing method. The experiment results revealed that the evolution rate of CO from CO<sub>2</sub> photoreduction for optimal Bi<sub>2</sub>O<sub>2</sub>S<sub>0.8</sub>F<sub>0.4</sub>/BiOBr heterojunction was 219.3 μmol⸱g<sup>−1</sup>⸱h<sup>−1</sup>, being 9.8 times greater than that of pure BiOBr. The S-scheme band structure was shown to promote sunlight utilization, raise the reduction power of photogenerated electrons, and improve the separation and transfer of photogenerated charge carriers. Moreover, the presence of dual oxygen vacancies on the interfacial surface of Bi<sub>2</sub>O<sub>2</sub>S<sub>0.8</sub>F<sub>0.4</sub>/BiOBr heterojunction facilitates the adsorption and activation of CO<sub>2</sub> and H<sub>2</sub>O molecules. The work focuses on the combined impact of the S-scheme band structure and oxygen vacancy on the property of photocatalytic reduction of CO<sub>2</sub>. The study presents a straightforward strategy for the on-site creation of S-scheme heterojunction with defect.</div></div>","PeriodicalId":16173,"journal":{"name":"Journal of Materiomics","volume":"11 4","pages":"Article 100998"},"PeriodicalIF":8.4000,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Design of double oxygen vacancy-rich Bi2O2S0.8F0.4/BiOBr S-scheme heterojunction via tuning band structure for CO2 photoreduction\",\"authors\":\"Xifeng Hou , Chenbin Ai , Songyu Yang , Jianjun Zhang , Yanfeng Zhang , Jingze Liu\",\"doi\":\"10.1016/j.jmat.2024.100998\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>S-scheme heterojunction has garnered significant interest owing to its distinctive band structure and interfacial interaction. In this work, nanosheets-like Bi<sub>2</sub>O<sub>2</sub>S<sub>0.8</sub>F<sub>0.4</sub>/BiOBr heterojunction photocatalyst with dual surface oxygen vacancies was synthesized by epitaxial growing method. The experiment results revealed that the evolution rate of CO from CO<sub>2</sub> photoreduction for optimal Bi<sub>2</sub>O<sub>2</sub>S<sub>0.8</sub>F<sub>0.4</sub>/BiOBr heterojunction was 219.3 μmol⸱g<sup>−1</sup>⸱h<sup>−1</sup>, being 9.8 times greater than that of pure BiOBr. The S-scheme band structure was shown to promote sunlight utilization, raise the reduction power of photogenerated electrons, and improve the separation and transfer of photogenerated charge carriers. Moreover, the presence of dual oxygen vacancies on the interfacial surface of Bi<sub>2</sub>O<sub>2</sub>S<sub>0.8</sub>F<sub>0.4</sub>/BiOBr heterojunction facilitates the adsorption and activation of CO<sub>2</sub> and H<sub>2</sub>O molecules. The work focuses on the combined impact of the S-scheme band structure and oxygen vacancy on the property of photocatalytic reduction of CO<sub>2</sub>. The study presents a straightforward strategy for the on-site creation of S-scheme heterojunction with defect.</div></div>\",\"PeriodicalId\":16173,\"journal\":{\"name\":\"Journal of Materiomics\",\"volume\":\"11 4\",\"pages\":\"Article 100998\"},\"PeriodicalIF\":8.4000,\"publicationDate\":\"2024-12-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materiomics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352847824002375\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materiomics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352847824002375","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
S - scheme异质结由于其独特的能带结构和界面相互作用而引起了人们的极大兴趣。本文采用外延生长法合成了具有双表面氧空位的Bi2O2S0.8F0.4 /BiOBr异质结光催化剂。实验结果表明,最优Bi2O2S0.8F0.4/BiOBr异质结中CO2光还原CO的演化速率为219.3 μmol⸱g-1⸱h-1,是纯BiOBr的9.8倍。S - scheme能带结构促进了光能的利用,提高了光生电子的还原能力,并改善了光生载流子的分离和转移。此外,Bi2O2S0.8F0.4/BiOBr异质结界面表面存在双氧空位,有利于CO2和H2O分子的吸附和活化。研究了S - scheme能带结构和氧空位对CO2光催化还原性能的综合影响。该研究提出了一种直接的方法,可以在现场制造S型异质结缺陷。
Design of double oxygen vacancy-rich Bi2O2S0.8F0.4/BiOBr S-scheme heterojunction via tuning band structure for CO2 photoreduction
S-scheme heterojunction has garnered significant interest owing to its distinctive band structure and interfacial interaction. In this work, nanosheets-like Bi2O2S0.8F0.4/BiOBr heterojunction photocatalyst with dual surface oxygen vacancies was synthesized by epitaxial growing method. The experiment results revealed that the evolution rate of CO from CO2 photoreduction for optimal Bi2O2S0.8F0.4/BiOBr heterojunction was 219.3 μmol⸱g−1⸱h−1, being 9.8 times greater than that of pure BiOBr. The S-scheme band structure was shown to promote sunlight utilization, raise the reduction power of photogenerated electrons, and improve the separation and transfer of photogenerated charge carriers. Moreover, the presence of dual oxygen vacancies on the interfacial surface of Bi2O2S0.8F0.4/BiOBr heterojunction facilitates the adsorption and activation of CO2 and H2O molecules. The work focuses on the combined impact of the S-scheme band structure and oxygen vacancy on the property of photocatalytic reduction of CO2. The study presents a straightforward strategy for the on-site creation of S-scheme heterojunction with defect.
期刊介绍:
The Journal of Materiomics is a peer-reviewed open-access journal that aims to serve as a forum for the continuous dissemination of research within the field of materials science. It particularly emphasizes systematic studies on the relationships between composition, processing, structure, property, and performance of advanced materials. The journal is supported by the Chinese Ceramic Society and is indexed in SCIE and Scopus. It is commonly referred to as J Materiomics.