Muhammad Umair Ali, Atta Ur Rehman and Aleksandra B. Djurišić
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引用次数: 0
摘要
近年来,金属卤化物包晶发光二极管(LED)在稳定性方面取得了重大进展,其记录寿命显著延长。然而,大量已发表的论文仍然报告了半衰期 T50,与已报告的记录相比明显较短。从这个角度,我们讨论了不同发射范围的稳定性成就和仍然存在的挑战。与其他颜色的发光二极管相比,蓝色发光二极管通常表现出更快的性能衰减,而近红外和绿色发光二极管的半衰期记录已超过 30 000 小时。为了确定实现更高稳定性器件的可行方法,我们将重点放在绿色 LED 上,并讨论降解机制和影响器件稳定性的因素,重点是电化学过程和离子迁移,以及这些过程如何受到包晶石成分和器件结构的影响。
Has the perovskite LED stability problem been solved?†
Significant progress in the stability of metal halide perovskite light emitting diodes (LEDs) has been made in recent years, with impressive increases in record lifetimes. However, a large number of published papers still report half lifetimes, T50, which are significantly shorter compared to reported records. In this perspective, we discuss the stability achievements for different emission ranges and the remaining challenges. Blue LEDs generally exhibit much faster performance degradation compared to other colours, while for near-infrared and green LEDs record half-lifetimes exceeding 30 000 h have been reported. To identify promising approaches towards higher stability devices, we focus on green LEDs and discuss mechanisms of degradation and factors affecting the device stability, focusing on the electrochemical processes and ion migration, and how these processes are affected by the perovskite composition and device architecture.
期刊介绍:
The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study:
Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability.
Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine.
Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices.
Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive.
Bioelectronics
Conductors
Detectors
Dielectrics
Displays
Ferroelectrics
Lasers
LEDs
Lighting
Liquid crystals
Memory
Metamaterials
Multiferroics
Photonics
Photovoltaics
Semiconductors
Sensors
Single molecule conductors
Spintronics
Superconductors
Thermoelectrics
Topological insulators
Transistors