Ali Mohebbi , Saeid Yaripour , Ali Sadeghi Alavian , Mir Mahdi Daghi , Nazir Fattahi
{"title":"基于 MIL-101 Cr (NH2)@SiO2@NiFe2O4 纳米颗粒的磁性固相萃取方法的开发及其在蜂蜜中全氟辛酸和全氟辛烷磺酸萃取中的应用","authors":"Ali Mohebbi , Saeid Yaripour , Ali Sadeghi Alavian , Mir Mahdi Daghi , Nazir Fattahi","doi":"10.1016/j.jfca.2024.107006","DOIUrl":null,"url":null,"abstract":"<div><div>In the present research, a MIL–101 Cr (NH<sub>2</sub>)@SiO<sub>2</sub>@NiFe<sub>2</sub>O<sub>4</sub> nanoparticles based magnetic solid phase extraction conducted in a narrow bore tube has been developed and validated for extraction of perfluorooctanoic acid and perfluorooctane sulfonate from honey samples. For this purpose, an extraction vessel was designed and honey sample solution was transferred into it. After that, the synthesized magnetic sorbent was added and placed at the bottom of the tube. After a few minutes, the stopcock of the extraction vessel was opened and the sample was passed through in the presence of a magnet. In the subsequent step, the magnetic particles were rinsed with a suitable deep eutectic solvent using vortex agitation. At the end, the eluent phase was taken and analysed using high performance liquid chromatography–tandem mass spectrometry. Under the best conditions, the validation of suggested procedure was done and based on the outcomes, great precision (relative standard deviations ≤ 6.0 %), good linearity (r<sup>2</sup> ≥ 0.9978) in a wide concentration range, low limits of detection (20 and 23 ng kg<sup>–1</sup> for perfluorooctanoic acid and perfluorooctane sulfonate, respectively) and quantification (67 and 77 ng kg<sup>–1</sup> for perfluorooctanoic acid and perfluorooctane sulfonate, respectively), and acceptable extraction recoveries (80 and 74 % for perfluorooctanoic acid and perfluorooctane sulfonate, respectively) were acquired. In the following, the presented method was effectively employed for quantification of perfluorooctanoic acid and perfluorooctane sulfonate in twenty honey samples and based on the outcomes they were free of the mentioned pollutants.</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"138 ","pages":"Article 107006"},"PeriodicalIF":4.0000,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of a MIL–101 Cr (NH2)@SiO2@NiFe2O4 nanoparticles based magnetic solid phase extraction method and its application in extraction of perfluorooctanoic acid and perfluorooctane sulfonate from honey\",\"authors\":\"Ali Mohebbi , Saeid Yaripour , Ali Sadeghi Alavian , Mir Mahdi Daghi , Nazir Fattahi\",\"doi\":\"10.1016/j.jfca.2024.107006\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In the present research, a MIL–101 Cr (NH<sub>2</sub>)@SiO<sub>2</sub>@NiFe<sub>2</sub>O<sub>4</sub> nanoparticles based magnetic solid phase extraction conducted in a narrow bore tube has been developed and validated for extraction of perfluorooctanoic acid and perfluorooctane sulfonate from honey samples. For this purpose, an extraction vessel was designed and honey sample solution was transferred into it. After that, the synthesized magnetic sorbent was added and placed at the bottom of the tube. After a few minutes, the stopcock of the extraction vessel was opened and the sample was passed through in the presence of a magnet. In the subsequent step, the magnetic particles were rinsed with a suitable deep eutectic solvent using vortex agitation. At the end, the eluent phase was taken and analysed using high performance liquid chromatography–tandem mass spectrometry. Under the best conditions, the validation of suggested procedure was done and based on the outcomes, great precision (relative standard deviations ≤ 6.0 %), good linearity (r<sup>2</sup> ≥ 0.9978) in a wide concentration range, low limits of detection (20 and 23 ng kg<sup>–1</sup> for perfluorooctanoic acid and perfluorooctane sulfonate, respectively) and quantification (67 and 77 ng kg<sup>–1</sup> for perfluorooctanoic acid and perfluorooctane sulfonate, respectively), and acceptable extraction recoveries (80 and 74 % for perfluorooctanoic acid and perfluorooctane sulfonate, respectively) were acquired. 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引用次数: 0
摘要
本研究开发并验证了一种基于 MIL-101 Cr (NH2)@SiO2@NiFe2O4 纳米粒子的窄孔管磁性固相萃取法,用于从蜂蜜样品中萃取全氟辛酸和全氟辛烷磺酸。为此,设计了一个萃取容器,并将蜂蜜样品溶液移入其中。然后,加入合成的磁性吸附剂并置于试管底部。几分钟后,打开萃取容器的旋塞,样品在磁铁的作用下通过萃取容器。在随后的步骤中,利用涡旋搅拌用适当的深共晶溶剂冲洗磁性颗粒。最后,提取洗脱相,使用高效液相色谱-串联质谱法进行分析。在最佳条件下,对所建议的程序进行了验证,结果表明,在较宽的浓度范围内,该程序具有很高的精确度(相对标准偏差小于 6.0%)、良好的线性度(r2 ≥ 0.全氟辛酸和全氟辛烷磺酸的检出限(分别为 20 ng kg-1 和 23 ng kg-1)和定量限(分别为 67 ng kg-1 和 77 ng kg-1)均较低,萃取回收率(分别为 80 % 和 74 %)也可接受。随后,采用该方法对 20 份蜂蜜样品中的全氟辛酸和全氟辛烷磺酸进行了有效定量,结果表明蜂蜜中不含有上述污染物。
Development of a MIL–101 Cr (NH2)@SiO2@NiFe2O4 nanoparticles based magnetic solid phase extraction method and its application in extraction of perfluorooctanoic acid and perfluorooctane sulfonate from honey
In the present research, a MIL–101 Cr (NH2)@SiO2@NiFe2O4 nanoparticles based magnetic solid phase extraction conducted in a narrow bore tube has been developed and validated for extraction of perfluorooctanoic acid and perfluorooctane sulfonate from honey samples. For this purpose, an extraction vessel was designed and honey sample solution was transferred into it. After that, the synthesized magnetic sorbent was added and placed at the bottom of the tube. After a few minutes, the stopcock of the extraction vessel was opened and the sample was passed through in the presence of a magnet. In the subsequent step, the magnetic particles were rinsed with a suitable deep eutectic solvent using vortex agitation. At the end, the eluent phase was taken and analysed using high performance liquid chromatography–tandem mass spectrometry. Under the best conditions, the validation of suggested procedure was done and based on the outcomes, great precision (relative standard deviations ≤ 6.0 %), good linearity (r2 ≥ 0.9978) in a wide concentration range, low limits of detection (20 and 23 ng kg–1 for perfluorooctanoic acid and perfluorooctane sulfonate, respectively) and quantification (67 and 77 ng kg–1 for perfluorooctanoic acid and perfluorooctane sulfonate, respectively), and acceptable extraction recoveries (80 and 74 % for perfluorooctanoic acid and perfluorooctane sulfonate, respectively) were acquired. In the following, the presented method was effectively employed for quantification of perfluorooctanoic acid and perfluorooctane sulfonate in twenty honey samples and based on the outcomes they were free of the mentioned pollutants.
期刊介绍:
The Journal of Food Composition and Analysis publishes manuscripts on scientific aspects of data on the chemical composition of human foods, with particular emphasis on actual data on composition of foods; analytical methods; studies on the manipulation, storage, distribution and use of food composition data; and studies on the statistics, use and distribution of such data and data systems. The Journal''s basis is nutrient composition, with increasing emphasis on bioactive non-nutrient and anti-nutrient components. Papers must provide sufficient description of the food samples, analytical methods, quality control procedures and statistical treatments of the data to permit the end users of the food composition data to evaluate the appropriateness of such data in their projects.
The Journal does not publish papers on: microbiological compounds; sensory quality; aromatics/volatiles in food and wine; essential oils; organoleptic characteristics of food; physical properties; or clinical papers and pharmacology-related papers.