在黄麻酒石酸复合材料表面制备纳米铜，实现环氧化物到环碳酸盐的绿色转化

IF 1.5 4区材料科学 Q3 Chemistry

Crystal Research and Technology Pub Date : 2024-10-08 DOI:10.1002/crat.202400114

Sankar Barman, Sushobhan Ghosh

{"title":"在黄麻酒石酸复合材料表面制备纳米铜，实现环氧化物到环碳酸盐的绿色转化","authors":"Sankar Barman, Sushobhan Ghosh","doi":"10.1002/crat.202400114","DOIUrl":null,"url":null,"abstract":"The synthesis of copper nanocrystals on tartaric acid jute composite surface is reported. The formation of nanocrystals is detected by FT IR, Powder X-ray diffraction, SEM, and TEM analysis. The average size of the nanocrystals is found to be 500 nm. The reaction of the copper nanocrystals with CO2 resulted in a decrease in the size of the nanoparticles. Cycloaddition reaction of epoxides to cyclic carbonate is efficiently carried out by the copper nanocrystals on tartaric acid jute composite surface (CUNPJT) without using any cocatalyst and solvent. To the best of author's knowledge, this is the first example of copper nanocrystals catalyzing the cycloaddition of CO2 and epoxide.","PeriodicalId":48935,"journal":{"name":"Crystal Research and Technology","volume":"59 11","pages":""},"PeriodicalIF":1.5000,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Green Conversion of Epoxides to Cyclic Carbonates by Copper Nanocrystals Fabricated on Jute Tartaric Acid Composite Surface\",\"authors\":\"Sankar Barman, Sushobhan Ghosh\",\"doi\":\"10.1002/crat.202400114\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The synthesis of copper nanocrystals on tartaric acid jute composite surface is reported. The formation of nanocrystals is detected by FT IR, Powder X-ray diffraction, SEM, and TEM analysis. The average size of the nanocrystals is found to be 500 nm. The reaction of the copper nanocrystals with CO2 resulted in a decrease in the size of the nanoparticles. Cycloaddition reaction of epoxides to cyclic carbonate is efficiently carried out by the copper nanocrystals on tartaric acid jute composite surface (CUNPJT) without using any cocatalyst and solvent. To the best of author's knowledge, this is the first example of copper nanocrystals catalyzing the cycloaddition of CO2 and epoxide.\",\"PeriodicalId\":48935,\"journal\":{\"name\":\"Crystal Research and Technology\",\"volume\":\"59 11\",\"pages\":\"\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-10-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystal Research and Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/crat.202400114\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Research and Technology","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/crat.202400114","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Chemistry","Score":null,"Total":0}

引用次数: 0

摘要

报告了在酒石酸黄麻复合材料表面合成纳米铜晶体的过程。通过傅立叶变换红外光谱、粉末 X 射线衍射、扫描电镜和 TEM 分析检测了纳米晶体的形成。纳米晶体的平均尺寸为 500 nm。纳米铜晶体与 CO2 反应后，纳米粒子的尺寸减小。酒石酸黄麻复合表面（CUNPJT）上的纳米铜晶体不使用任何助催化剂和溶剂，就能有效地进行环氧化物与环碳酸盐的环加成反应。据作者所知，这是纳米铜晶体催化二氧化碳和环氧化物环化反应的第一个实例。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Green Conversion of Epoxides to Cyclic Carbonates by Copper Nanocrystals Fabricated on Jute Tartaric Acid Composite Surface

The synthesis of copper nanocrystals on tartaric acid jute composite surface is reported. The formation of nanocrystals is detected by FT IR, Powder X-ray diffraction, SEM, and TEM analysis. The average size of the nanocrystals is found to be 500 nm. The reaction of the copper nanocrystals with CO₂ resulted in a decrease in the size of the nanoparticles. Cycloaddition reaction of epoxides to cyclic carbonate is efficiently carried out by the copper nanocrystals on tartaric acid jute composite surface (CUNPJT) without using any cocatalyst and solvent. To the best of author's knowledge, this is the first example of copper nanocrystals catalyzing the cycloaddition of CO₂ and epoxide.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Crystal Research and Technology CRYSTALLOGRAPHY-

CiteScore

2.50

自引率

6.70%

发文量

121

审稿时长

1.9 months

期刊介绍： The journal Crystal Research and Technology is a pure online Journal (since 2012). Crystal Research and Technology is an international journal examining all aspects of research within experimental, industrial, and theoretical crystallography. The journal covers the relevant aspects of -crystal growth techniques and phenomena (including bulk growth, thin films) -modern crystalline materials (e.g. smart materials, nanocrystals, quasicrystals, liquid crystals) -industrial crystallisation -application of crystals in materials science, electronics, data storage, and optics -experimental, simulation and theoretical studies of the structural properties of crystals -crystallographic computing