Duncan Calvert , Tristan Dew , Arthur Gadon , Jacques Gros , David Cook
{"title":"酒花叶片生物活性化合物的价值评估:不同品种、作物年份和发展阶段的酚类物质的鉴定和定量。","authors":"Duncan Calvert , Tristan Dew , Arthur Gadon , Jacques Gros , David Cook","doi":"10.1016/j.foodchem.2024.142005","DOIUrl":null,"url":null,"abstract":"<div><div>Hop leaves, a by-product from hop cone harvesting, contain phenolic compounds of potential value for food or beverage applications. However, the abundant phenolics in hop leaves remain largely unquantified. This study quantified phenolics in hop leaves over two crop years, for three commercially significant varieties, at different developmental stages post-flowering. Ethanolic hop extracts were characterised using LC-ESI-qTOF-MS/MS and HPLC-DAD for the annotation and quantification of phenolics and bitter resins. Hop leaf phenolic profile exhibited considerable structural diversity, differing significantly from that of respective cones. Kaempferol/quercetin 3-O-glycosides and chlorogenic acids were the most abundant sub-groups with phenolic acids, procyanidins, prenylflavonoids and bitter resins also present. Phenolic profile was mainly variety-dependent with some crop year and developmental effects. Flavonol 3-O-glycosides were the main compounds driving varietal differences. Findings demonstrate the structural diversity and high concentrations of phenolic compounds in hop leaf extracts and their potential as a source of bioactives for valorisation.</div></div>","PeriodicalId":318,"journal":{"name":"Food Chemistry","volume":"465 ","pages":"Article 142005"},"PeriodicalIF":8.5000,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Valorisation of hop leaves for their bioactive compounds: Identification and quantification of phenolics across different varieties, crop years and stages of development.\",\"authors\":\"Duncan Calvert , Tristan Dew , Arthur Gadon , Jacques Gros , David Cook\",\"doi\":\"10.1016/j.foodchem.2024.142005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Hop leaves, a by-product from hop cone harvesting, contain phenolic compounds of potential value for food or beverage applications. However, the abundant phenolics in hop leaves remain largely unquantified. This study quantified phenolics in hop leaves over two crop years, for three commercially significant varieties, at different developmental stages post-flowering. Ethanolic hop extracts were characterised using LC-ESI-qTOF-MS/MS and HPLC-DAD for the annotation and quantification of phenolics and bitter resins. Hop leaf phenolic profile exhibited considerable structural diversity, differing significantly from that of respective cones. Kaempferol/quercetin 3-O-glycosides and chlorogenic acids were the most abundant sub-groups with phenolic acids, procyanidins, prenylflavonoids and bitter resins also present. Phenolic profile was mainly variety-dependent with some crop year and developmental effects. Flavonol 3-O-glycosides were the main compounds driving varietal differences. Findings demonstrate the structural diversity and high concentrations of phenolic compounds in hop leaf extracts and their potential as a source of bioactives for valorisation.</div></div>\",\"PeriodicalId\":318,\"journal\":{\"name\":\"Food Chemistry\",\"volume\":\"465 \",\"pages\":\"Article 142005\"},\"PeriodicalIF\":8.5000,\"publicationDate\":\"2024-11-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Food Chemistry\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0308814624036550\",\"RegionNum\":1,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Food Chemistry","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0308814624036550","RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Valorisation of hop leaves for their bioactive compounds: Identification and quantification of phenolics across different varieties, crop years and stages of development.
Hop leaves, a by-product from hop cone harvesting, contain phenolic compounds of potential value for food or beverage applications. However, the abundant phenolics in hop leaves remain largely unquantified. This study quantified phenolics in hop leaves over two crop years, for three commercially significant varieties, at different developmental stages post-flowering. Ethanolic hop extracts were characterised using LC-ESI-qTOF-MS/MS and HPLC-DAD for the annotation and quantification of phenolics and bitter resins. Hop leaf phenolic profile exhibited considerable structural diversity, differing significantly from that of respective cones. Kaempferol/quercetin 3-O-glycosides and chlorogenic acids were the most abundant sub-groups with phenolic acids, procyanidins, prenylflavonoids and bitter resins also present. Phenolic profile was mainly variety-dependent with some crop year and developmental effects. Flavonol 3-O-glycosides were the main compounds driving varietal differences. Findings demonstrate the structural diversity and high concentrations of phenolic compounds in hop leaf extracts and their potential as a source of bioactives for valorisation.
期刊介绍:
Food Chemistry publishes original research papers dealing with the advancement of the chemistry and biochemistry of foods or the analytical methods/ approach used. All papers should focus on the novelty of the research carried out.