Huanggen Yang, Pei Zhang, Qi Zheng, Asif Hayat, Hisham S. M. Abd-Rabboh, Saleem Raza, Duofu Li and Yan Sui
{"title":"在不同单宁酸(TA)比例的 Ti3C2Tx MXene 纳米片表面原位生长 MOF 以协同光催化降解污染物†。","authors":"Huanggen Yang, Pei Zhang, Qi Zheng, Asif Hayat, Hisham S. M. Abd-Rabboh, Saleem Raza, Duofu Li and Yan Sui","doi":"10.1039/D4TC02771J","DOIUrl":null,"url":null,"abstract":"<p >The integration of a two-dimensional (2D) transition metal carbide (MXene) with metal–organic frameworks (MOFs) presents a promising avenue for addressing the limitations of MXene materials in various applications. In this study, we report the fabrication of a novel photocatalyst by <em>in situ</em>-growth self-assembly, where Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small> MXene serves as a substrate for immobilizing ZIF-8 MOFs. This composite, Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>@ZIF-8, is further modified with tannic acid (TA) and polyphenol compounds to create a cross-linked network, enhancing the heterogeneous interfaces crucial for efficient photocatalysis. Varying concentrations of tannic acid (10, 20, and 30 mg) were explored to optimize photocatalyst performance. Structural characterization confirms the successful synthesis of Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>@ZIF-8@TA composites, revealing their unique network topology. The prepared ZIF-8, Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>@TA, Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>/ZIF-8@TA10, Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>/ZIF-8@TA20 and Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>/ZIF-8@TA30 photocatalysts were characterized by various techniques (SEM, EDX, FTIR, XRD, TGA, DRS, and BET surface area measurements). Under visible light irradiation, the photocatalyst demonstrates remarkable degradation efficiencies, with RhB, Congo red and methyl orange dyes achieving approximate degradation rates of 87%, 85%, and 79%, respectively, within 60 minutes. Notably, the photocatalyst exhibits low energy consumption, affordability, non-toxicity, and environmental compatibility, underscoring its practical potential for wastewater treatment applications. This work highlights the advancement in MXene-based photocatalysts and their significant impact on pollutant removal from wastewater.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 43","pages":" 17620-17634"},"PeriodicalIF":5.7000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synergistic in situ growth of a MOF on the surface of Ti3C2Tx MXene nanosheets with different tannic acid (TA) ratios for the photocatalytic degradation of pollutants†\",\"authors\":\"Huanggen Yang, Pei Zhang, Qi Zheng, Asif Hayat, Hisham S. M. Abd-Rabboh, Saleem Raza, Duofu Li and Yan Sui\",\"doi\":\"10.1039/D4TC02771J\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The integration of a two-dimensional (2D) transition metal carbide (MXene) with metal–organic frameworks (MOFs) presents a promising avenue for addressing the limitations of MXene materials in various applications. In this study, we report the fabrication of a novel photocatalyst by <em>in situ</em>-growth self-assembly, where Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small> MXene serves as a substrate for immobilizing ZIF-8 MOFs. This composite, Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>@ZIF-8, is further modified with tannic acid (TA) and polyphenol compounds to create a cross-linked network, enhancing the heterogeneous interfaces crucial for efficient photocatalysis. Varying concentrations of tannic acid (10, 20, and 30 mg) were explored to optimize photocatalyst performance. Structural characterization confirms the successful synthesis of Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>@ZIF-8@TA composites, revealing their unique network topology. The prepared ZIF-8, Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>@TA, Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>/ZIF-8@TA10, Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>/ZIF-8@TA20 and Ti<small><sub>3</sub></small>C<small><sub>2</sub></small>T<small><sub><em>x</em></sub></small>/ZIF-8@TA30 photocatalysts were characterized by various techniques (SEM, EDX, FTIR, XRD, TGA, DRS, and BET surface area measurements). Under visible light irradiation, the photocatalyst demonstrates remarkable degradation efficiencies, with RhB, Congo red and methyl orange dyes achieving approximate degradation rates of 87%, 85%, and 79%, respectively, within 60 minutes. Notably, the photocatalyst exhibits low energy consumption, affordability, non-toxicity, and environmental compatibility, underscoring its practical potential for wastewater treatment applications. 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Synergistic in situ growth of a MOF on the surface of Ti3C2Tx MXene nanosheets with different tannic acid (TA) ratios for the photocatalytic degradation of pollutants†
The integration of a two-dimensional (2D) transition metal carbide (MXene) with metal–organic frameworks (MOFs) presents a promising avenue for addressing the limitations of MXene materials in various applications. In this study, we report the fabrication of a novel photocatalyst by in situ-growth self-assembly, where Ti3C2Tx MXene serves as a substrate for immobilizing ZIF-8 MOFs. This composite, Ti3C2Tx@ZIF-8, is further modified with tannic acid (TA) and polyphenol compounds to create a cross-linked network, enhancing the heterogeneous interfaces crucial for efficient photocatalysis. Varying concentrations of tannic acid (10, 20, and 30 mg) were explored to optimize photocatalyst performance. Structural characterization confirms the successful synthesis of Ti3C2Tx@ZIF-8@TA composites, revealing their unique network topology. The prepared ZIF-8, Ti3C2Tx@TA, Ti3C2Tx/ZIF-8@TA10, Ti3C2Tx/ZIF-8@TA20 and Ti3C2Tx/ZIF-8@TA30 photocatalysts were characterized by various techniques (SEM, EDX, FTIR, XRD, TGA, DRS, and BET surface area measurements). Under visible light irradiation, the photocatalyst demonstrates remarkable degradation efficiencies, with RhB, Congo red and methyl orange dyes achieving approximate degradation rates of 87%, 85%, and 79%, respectively, within 60 minutes. Notably, the photocatalyst exhibits low energy consumption, affordability, non-toxicity, and environmental compatibility, underscoring its practical potential for wastewater treatment applications. This work highlights the advancement in MXene-based photocatalysts and their significant impact on pollutant removal from wastewater.
期刊介绍:
The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study:
Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability.
Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine.
Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices.
Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive.
Bioelectronics
Conductors
Detectors
Dielectrics
Displays
Ferroelectrics
Lasers
LEDs
Lighting
Liquid crystals
Memory
Metamaterials
Multiferroics
Photonics
Photovoltaics
Semiconductors
Sensors
Single molecule conductors
Spintronics
Superconductors
Thermoelectrics
Topological insulators
Transistors