Paundra Rizky Pratama, Azzah Dyah Pramata, Fuko Shiga, Jonas Karl Christopher N. Agutaya, Yusuke Inomata, Biplab Manna, Agung Purniawan, Yuji Akaishi and Tetsuya Kida
{"title":"用 CsPb2I5 和 Cs4PbI6 纳米团簇装饰的绿色发光 CsPbI3 纳米棒†。","authors":"Paundra Rizky Pratama, Azzah Dyah Pramata, Fuko Shiga, Jonas Karl Christopher N. Agutaya, Yusuke Inomata, Biplab Manna, Agung Purniawan, Yuji Akaishi and Tetsuya Kida","doi":"10.1039/D4TC03500C","DOIUrl":null,"url":null,"abstract":"<p >Lead halide-based perovskites (CsPbX<small><sub>3</sub></small>; X = Cl, Br, I) are prominent luminescent materials with pure red, green, and blue emissions; however, when mixed to obtain multiple emissions, they undergo spontaneous anion exchange reactions, which lead to undesirable changes in their photoluminescence (PL) and optical properties. This study presents iodide-based perovskites that can be color-transformed by controlling and coupling their phases in the nanoscale. The green-emitting CsPbI<small><sub>3</sub></small> nanorods decorated with Cs<small><sub>4</sub></small>PbI<small><sub>6</sub></small> and CsPb<small><sub>2</sub></small>I<small><sub>5</sub></small> nanoclusters (MP-nanorods) were produced by sequential transformation using the hot chemical method with the assistance of zirconium tetraisobutoxide and 1-octadecene. At room temperature, MP-nanorods exhibit narrow-band green emission with line widths of around 20.5 nm, originating from the multiphase heterojunction of CsPbI<small><sub>3</sub></small> nanorods coupled with Cs<small><sub>4</sub></small>PbI<small><sub>6</sub></small> nanoclusters. Additionally, they can maintain and differentiate their initial photoemission in the colloidal mixture in the presence of red-emitting CsPbI<small><sub>3</sub></small> quantum dots without suffering from peak merging. The obtained results open the possibility of applications that require a stable mixture of multi-band gap systems such as complex anticounterfeiting, tandem rainbow solar cells, and white LED applications because they can retain their initial color purity without losing their original optical properties.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 43","pages":" 17611-17619"},"PeriodicalIF":5.7000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Green-emitting CsPbI3 nanorods decorated with CsPb2I5 and Cs4PbI6 nanoclusters†\",\"authors\":\"Paundra Rizky Pratama, Azzah Dyah Pramata, Fuko Shiga, Jonas Karl Christopher N. Agutaya, Yusuke Inomata, Biplab Manna, Agung Purniawan, Yuji Akaishi and Tetsuya Kida\",\"doi\":\"10.1039/D4TC03500C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Lead halide-based perovskites (CsPbX<small><sub>3</sub></small>; X = Cl, Br, I) are prominent luminescent materials with pure red, green, and blue emissions; however, when mixed to obtain multiple emissions, they undergo spontaneous anion exchange reactions, which lead to undesirable changes in their photoluminescence (PL) and optical properties. This study presents iodide-based perovskites that can be color-transformed by controlling and coupling their phases in the nanoscale. The green-emitting CsPbI<small><sub>3</sub></small> nanorods decorated with Cs<small><sub>4</sub></small>PbI<small><sub>6</sub></small> and CsPb<small><sub>2</sub></small>I<small><sub>5</sub></small> nanoclusters (MP-nanorods) were produced by sequential transformation using the hot chemical method with the assistance of zirconium tetraisobutoxide and 1-octadecene. At room temperature, MP-nanorods exhibit narrow-band green emission with line widths of around 20.5 nm, originating from the multiphase heterojunction of CsPbI<small><sub>3</sub></small> nanorods coupled with Cs<small><sub>4</sub></small>PbI<small><sub>6</sub></small> nanoclusters. Additionally, they can maintain and differentiate their initial photoemission in the colloidal mixture in the presence of red-emitting CsPbI<small><sub>3</sub></small> quantum dots without suffering from peak merging. The obtained results open the possibility of applications that require a stable mixture of multi-band gap systems such as complex anticounterfeiting, tandem rainbow solar cells, and white LED applications because they can retain their initial color purity without losing their original optical properties.</p>\",\"PeriodicalId\":84,\"journal\":{\"name\":\"Journal of Materials Chemistry C\",\"volume\":\" 43\",\"pages\":\" 17611-17619\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2024-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Chemistry C\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/tc/d4tc03500c\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry C","FirstCategoryId":"1","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/tc/d4tc03500c","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Green-emitting CsPbI3 nanorods decorated with CsPb2I5 and Cs4PbI6 nanoclusters†
Lead halide-based perovskites (CsPbX3; X = Cl, Br, I) are prominent luminescent materials with pure red, green, and blue emissions; however, when mixed to obtain multiple emissions, they undergo spontaneous anion exchange reactions, which lead to undesirable changes in their photoluminescence (PL) and optical properties. This study presents iodide-based perovskites that can be color-transformed by controlling and coupling their phases in the nanoscale. The green-emitting CsPbI3 nanorods decorated with Cs4PbI6 and CsPb2I5 nanoclusters (MP-nanorods) were produced by sequential transformation using the hot chemical method with the assistance of zirconium tetraisobutoxide and 1-octadecene. At room temperature, MP-nanorods exhibit narrow-band green emission with line widths of around 20.5 nm, originating from the multiphase heterojunction of CsPbI3 nanorods coupled with Cs4PbI6 nanoclusters. Additionally, they can maintain and differentiate their initial photoemission in the colloidal mixture in the presence of red-emitting CsPbI3 quantum dots without suffering from peak merging. The obtained results open the possibility of applications that require a stable mixture of multi-band gap systems such as complex anticounterfeiting, tandem rainbow solar cells, and white LED applications because they can retain their initial color purity without losing their original optical properties.
期刊介绍:
The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study:
Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability.
Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine.
Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices.
Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive.
Bioelectronics
Conductors
Detectors
Dielectrics
Displays
Ferroelectrics
Lasers
LEDs
Lighting
Liquid crystals
Memory
Metamaterials
Multiferroics
Photonics
Photovoltaics
Semiconductors
Sensors
Single molecule conductors
Spintronics
Superconductors
Thermoelectrics
Topological insulators
Transistors