Yongrun Dong, Wen Li, Tao Huang, Shuaigang Ge, Linghang Kong, Chuang Ning, Zequan Li, Wei Gao and Bingsuo Zou
{"title":"在聚偏二氟乙烯基质中原位制备高发光 Sb3+/Mn2+共掺杂 Cs2KInCl6 无铅双包晶并将其应用于白光发光二极管和防伪†。","authors":"Yongrun Dong, Wen Li, Tao Huang, Shuaigang Ge, Linghang Kong, Chuang Ning, Zequan Li, Wei Gao and Bingsuo Zou","doi":"10.1039/D4TC03527E","DOIUrl":null,"url":null,"abstract":"<p >Recently, lead-free double perovskites have been regarded as a promising alternative to lead halide perovskites due to their wide emission band, and environmental protection and stability properties, and are expected to become a series of rising star materials in the lighting field. However, currently, the growth of most lead-free double perovskites occurs in the strong acid environment, which not only brings high cost and environment risk, but also makes it hard to realize large-scale applications with powder products. Herein, we apply a strategy of <em>in situ</em> synthesis of lead-free double perovskites in a polymer matrix by using a small amount of precursors and relatively friendly DMSO solvent to obtain efficiently luminescent Sb<small><sup>3+</sup></small>/Mn<small><sup>2+</sup></small> co-doped Cs<small><sub>2</sub></small>KInCl<small><sub>6</sub></small>/PVDF composite films in a large-area. The co-doping of Mn<small><sup>2+</sup></small>/Sb<small><sup>3+</sup></small> into this inorganic double perovskite matrix makes microcrystals with good crystallinity and size distribution in this polymer. The as prepared co-doping composite film with Mn/Sb feeding ratio 16 : 1 shows the brightest white light emission under 320 nm excitation, with a photoluminescence quantum yield (PLQY) as high as 86.98%. The energy transfer (E-T) from the charge-transfer band to the triplet self-trapped exciton (STE) around Sb<small><sup>3+</sup></small> and then to the ferromagnetic (FM) coupled Mn<small><sup>2+</sup></small> pair 3d state was confirmed by the temperature-dependent PL spectra and density functional theory calculations. Finally, a single-compound white light emitting diode with chromatic coordinates of (0.31, 0.33) and fluorescent anti-counterfeiting labels could be fabricated based on this composite film with the best white emission. This work provides a new strategy for the application of lead-free double perovskites in the fields of lighting and anti-counterfeiting.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 43","pages":" 17458-17468"},"PeriodicalIF":5.7000,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"In situ preparation of highly luminescent Sb3+/Mn2+ co-doped Cs2KInCl6 lead-free double perovskites in a PVDF matrix and application to white light emitting diodes and anti-counterfeiting†\",\"authors\":\"Yongrun Dong, Wen Li, Tao Huang, Shuaigang Ge, Linghang Kong, Chuang Ning, Zequan Li, Wei Gao and Bingsuo Zou\",\"doi\":\"10.1039/D4TC03527E\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Recently, lead-free double perovskites have been regarded as a promising alternative to lead halide perovskites due to their wide emission band, and environmental protection and stability properties, and are expected to become a series of rising star materials in the lighting field. However, currently, the growth of most lead-free double perovskites occurs in the strong acid environment, which not only brings high cost and environment risk, but also makes it hard to realize large-scale applications with powder products. Herein, we apply a strategy of <em>in situ</em> synthesis of lead-free double perovskites in a polymer matrix by using a small amount of precursors and relatively friendly DMSO solvent to obtain efficiently luminescent Sb<small><sup>3+</sup></small>/Mn<small><sup>2+</sup></small> co-doped Cs<small><sub>2</sub></small>KInCl<small><sub>6</sub></small>/PVDF composite films in a large-area. The co-doping of Mn<small><sup>2+</sup></small>/Sb<small><sup>3+</sup></small> into this inorganic double perovskite matrix makes microcrystals with good crystallinity and size distribution in this polymer. The as prepared co-doping composite film with Mn/Sb feeding ratio 16 : 1 shows the brightest white light emission under 320 nm excitation, with a photoluminescence quantum yield (PLQY) as high as 86.98%. The energy transfer (E-T) from the charge-transfer band to the triplet self-trapped exciton (STE) around Sb<small><sup>3+</sup></small> and then to the ferromagnetic (FM) coupled Mn<small><sup>2+</sup></small> pair 3d state was confirmed by the temperature-dependent PL spectra and density functional theory calculations. Finally, a single-compound white light emitting diode with chromatic coordinates of (0.31, 0.33) and fluorescent anti-counterfeiting labels could be fabricated based on this composite film with the best white emission. This work provides a new strategy for the application of lead-free double perovskites in the fields of lighting and anti-counterfeiting.</p>\",\"PeriodicalId\":84,\"journal\":{\"name\":\"Journal of Materials Chemistry C\",\"volume\":\" 43\",\"pages\":\" 17458-17468\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2024-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Chemistry C\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/tc/d4tc03527e\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry C","FirstCategoryId":"1","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/tc/d4tc03527e","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
In situ preparation of highly luminescent Sb3+/Mn2+ co-doped Cs2KInCl6 lead-free double perovskites in a PVDF matrix and application to white light emitting diodes and anti-counterfeiting†
Recently, lead-free double perovskites have been regarded as a promising alternative to lead halide perovskites due to their wide emission band, and environmental protection and stability properties, and are expected to become a series of rising star materials in the lighting field. However, currently, the growth of most lead-free double perovskites occurs in the strong acid environment, which not only brings high cost and environment risk, but also makes it hard to realize large-scale applications with powder products. Herein, we apply a strategy of in situ synthesis of lead-free double perovskites in a polymer matrix by using a small amount of precursors and relatively friendly DMSO solvent to obtain efficiently luminescent Sb3+/Mn2+ co-doped Cs2KInCl6/PVDF composite films in a large-area. The co-doping of Mn2+/Sb3+ into this inorganic double perovskite matrix makes microcrystals with good crystallinity and size distribution in this polymer. The as prepared co-doping composite film with Mn/Sb feeding ratio 16 : 1 shows the brightest white light emission under 320 nm excitation, with a photoluminescence quantum yield (PLQY) as high as 86.98%. The energy transfer (E-T) from the charge-transfer band to the triplet self-trapped exciton (STE) around Sb3+ and then to the ferromagnetic (FM) coupled Mn2+ pair 3d state was confirmed by the temperature-dependent PL spectra and density functional theory calculations. Finally, a single-compound white light emitting diode with chromatic coordinates of (0.31, 0.33) and fluorescent anti-counterfeiting labels could be fabricated based on this composite film with the best white emission. This work provides a new strategy for the application of lead-free double perovskites in the fields of lighting and anti-counterfeiting.
期刊介绍:
The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study:
Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability.
Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine.
Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices.
Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive.
Bioelectronics
Conductors
Detectors
Dielectrics
Displays
Ferroelectrics
Lasers
LEDs
Lighting
Liquid crystals
Memory
Metamaterials
Multiferroics
Photonics
Photovoltaics
Semiconductors
Sensors
Single molecule conductors
Spintronics
Superconductors
Thermoelectrics
Topological insulators
Transistors