Xuehao Guo, Xiulian Fan, Xilong Zhou, Wenlong Chu, Chenyang Niu, Liqi He, Shizhen Bin and Yu Zhou
{"title":"一种由碳化锆提供的气相碱卤化物辅助稳定前驱体用于合成二维大尺寸 ZrS2 纳米片†。","authors":"Xuehao Guo, Xiulian Fan, Xilong Zhou, Wenlong Chu, Chenyang Niu, Liqi He, Shizhen Bin and Yu Zhou","doi":"10.1039/D4TC02834A","DOIUrl":null,"url":null,"abstract":"<p >Group-IVB transition metal dichalcogenides such as HfS<small><sub>2</sub></small> and ZrS<small><sub>2</sub></small> demonstrate the most promising semiconducting properties, with moderate band gaps and high predicted carrier mobilities. However, the lateral growth of large-domain-size single crystalline ZrS<small><sub>2</sub></small> nanosheets remains to be developed, which limits various electronic and optoelectronic applications. Here, we report a new precursor strategy for the synthesis of large-sized 2D ZrS<small><sub>2</sub></small> nanosheets with lateral orientations. Volatilization of high-melting-point zirconium carbide as a stable precursor was controlled through the assistance of a remote gas-phase alkali halide, which avoids high nucleation density and vertical orientation at the initial stage. The 2D ZrS<small><sub>2</sub></small> nanosheets were regulated by adjusting the growth parameters to give a lateral size of up to 22 μm and a thickness of 8 nm, and exhibited good crystalline qualities and a uniform surface. Field effect transistors of 2D ZrS<small><sub>2</sub></small> nanosheets exhibited n-type transport characteristics with a high on/off ratio and reasonable carrier mobilities. Our new precursor and chemical design pave the way for the synthesis of high-performance group-IVB transition metal dichalcogenide wafers.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 41","pages":" 16677-16682"},"PeriodicalIF":5.7000,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A gas-phase alkali-halide-assisted stable precursor supplied from zirconium carbide for the synthesis of 2D large-sized ZrS2 nanosheets†\",\"authors\":\"Xuehao Guo, Xiulian Fan, Xilong Zhou, Wenlong Chu, Chenyang Niu, Liqi He, Shizhen Bin and Yu Zhou\",\"doi\":\"10.1039/D4TC02834A\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Group-IVB transition metal dichalcogenides such as HfS<small><sub>2</sub></small> and ZrS<small><sub>2</sub></small> demonstrate the most promising semiconducting properties, with moderate band gaps and high predicted carrier mobilities. However, the lateral growth of large-domain-size single crystalline ZrS<small><sub>2</sub></small> nanosheets remains to be developed, which limits various electronic and optoelectronic applications. Here, we report a new precursor strategy for the synthesis of large-sized 2D ZrS<small><sub>2</sub></small> nanosheets with lateral orientations. Volatilization of high-melting-point zirconium carbide as a stable precursor was controlled through the assistance of a remote gas-phase alkali halide, which avoids high nucleation density and vertical orientation at the initial stage. The 2D ZrS<small><sub>2</sub></small> nanosheets were regulated by adjusting the growth parameters to give a lateral size of up to 22 μm and a thickness of 8 nm, and exhibited good crystalline qualities and a uniform surface. Field effect transistors of 2D ZrS<small><sub>2</sub></small> nanosheets exhibited n-type transport characteristics with a high on/off ratio and reasonable carrier mobilities. Our new precursor and chemical design pave the way for the synthesis of high-performance group-IVB transition metal dichalcogenide wafers.</p>\",\"PeriodicalId\":84,\"journal\":{\"name\":\"Journal of Materials Chemistry C\",\"volume\":\" 41\",\"pages\":\" 16677-16682\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2024-09-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Chemistry C\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/tc/d4tc02834a\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry C","FirstCategoryId":"1","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/tc/d4tc02834a","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
A gas-phase alkali-halide-assisted stable precursor supplied from zirconium carbide for the synthesis of 2D large-sized ZrS2 nanosheets†
Group-IVB transition metal dichalcogenides such as HfS2 and ZrS2 demonstrate the most promising semiconducting properties, with moderate band gaps and high predicted carrier mobilities. However, the lateral growth of large-domain-size single crystalline ZrS2 nanosheets remains to be developed, which limits various electronic and optoelectronic applications. Here, we report a new precursor strategy for the synthesis of large-sized 2D ZrS2 nanosheets with lateral orientations. Volatilization of high-melting-point zirconium carbide as a stable precursor was controlled through the assistance of a remote gas-phase alkali halide, which avoids high nucleation density and vertical orientation at the initial stage. The 2D ZrS2 nanosheets were regulated by adjusting the growth parameters to give a lateral size of up to 22 μm and a thickness of 8 nm, and exhibited good crystalline qualities and a uniform surface. Field effect transistors of 2D ZrS2 nanosheets exhibited n-type transport characteristics with a high on/off ratio and reasonable carrier mobilities. Our new precursor and chemical design pave the way for the synthesis of high-performance group-IVB transition metal dichalcogenide wafers.
期刊介绍:
The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study:
Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability.
Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine.
Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices.
Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive.
Bioelectronics
Conductors
Detectors
Dielectrics
Displays
Ferroelectrics
Lasers
LEDs
Lighting
Liquid crystals
Memory
Metamaterials
Multiferroics
Photonics
Photovoltaics
Semiconductors
Sensors
Single molecule conductors
Spintronics
Superconductors
Thermoelectrics
Topological insulators
Transistors