Alexander P. Chaynikov , Andrei G. Kochur , Aleksey I. Dudenko
{"title":"被 0.01-100 千伏光子电离的银原子的级联能量再发射。银基放射增敏剂在光子束放射治疗中的可能应用","authors":"Alexander P. Chaynikov , Andrei G. Kochur , Aleksey I. Dudenko","doi":"10.1016/j.elspec.2024.147472","DOIUrl":null,"url":null,"abstract":"<div><p>A method of straightforward construction and analysis of the cascade decay trees is applied to study the cascade energy reemission by silver atoms upon photoionization in the incident photon energy range of 0.01–100 keV. Cascade electrons and photons emitted during the cascade relaxation of an inner-shell vacancy carry away a significant part of the energy initially acquired by the silver atom in a photoionization act. The energies redistributed through following channels were calculated as functions of incident photon energy: energy absorbed by the silver atom itself (<em>a</em>), and energies carried away by the cascade electrons (<em>b</em>) and photons (<em>c</em>). Channel (<em>a</em>) is dominant only at small incident photon energies up to the <em>M</em><sub>5</sub> ionization threshold. Channel (<em>b</em>) dominates between <em>M</em> and <em>K</em> thresholds making 57–85 % of the acquired energy. Above the <em>K</em> threshold, the weight of channel (<em>b</em>) is still significant, 24 %, however, dominant is channel (<em>c</em>).</p></div>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Cascade energy reemission by the silver atom ionized by 0.01–100 keV photons. Possible application of silver-based radiosensitizing agents in photon beam radiation therapy\",\"authors\":\"Alexander P. Chaynikov , Andrei G. Kochur , Aleksey I. Dudenko\",\"doi\":\"10.1016/j.elspec.2024.147472\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A method of straightforward construction and analysis of the cascade decay trees is applied to study the cascade energy reemission by silver atoms upon photoionization in the incident photon energy range of 0.01–100 keV. Cascade electrons and photons emitted during the cascade relaxation of an inner-shell vacancy carry away a significant part of the energy initially acquired by the silver atom in a photoionization act. The energies redistributed through following channels were calculated as functions of incident photon energy: energy absorbed by the silver atom itself (<em>a</em>), and energies carried away by the cascade electrons (<em>b</em>) and photons (<em>c</em>). Channel (<em>a</em>) is dominant only at small incident photon energies up to the <em>M</em><sub>5</sub> ionization threshold. Channel (<em>b</em>) dominates between <em>M</em> and <em>K</em> thresholds making 57–85 % of the acquired energy. Above the <em>K</em> threshold, the weight of channel (<em>b</em>) is still significant, 24 %, however, dominant is channel (<em>c</em>).</p></div>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-07-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0368204824000550\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0368204824000550","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Cascade energy reemission by the silver atom ionized by 0.01–100 keV photons. Possible application of silver-based radiosensitizing agents in photon beam radiation therapy
A method of straightforward construction and analysis of the cascade decay trees is applied to study the cascade energy reemission by silver atoms upon photoionization in the incident photon energy range of 0.01–100 keV. Cascade electrons and photons emitted during the cascade relaxation of an inner-shell vacancy carry away a significant part of the energy initially acquired by the silver atom in a photoionization act. The energies redistributed through following channels were calculated as functions of incident photon energy: energy absorbed by the silver atom itself (a), and energies carried away by the cascade electrons (b) and photons (c). Channel (a) is dominant only at small incident photon energies up to the M5 ionization threshold. Channel (b) dominates between M and K thresholds making 57–85 % of the acquired energy. Above the K threshold, the weight of channel (b) is still significant, 24 %, however, dominant is channel (c).
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.