Hui-Ping Yu , Qian-Qian Xu , Xin Wang , Yuan-Yuan Cui , He-Fang Wang , Cheng-Xiong Yang
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引用次数: 0
摘要
本研究精心设计并合成了一种新型氟化磁性微孔有机网络(Fe3O4@FMON),用于从复杂的茶饮料样品中高效、选择性地磁性固相萃取(MSPE)含氟苯甲酰脲类杀虫剂(BUs)。通过预先设计的疏水、π-π堆积、氢键和特异性 FF 相互作用,Fe3O4@FMON 对 BUs 具有良好的萃取效果。该方法线性范围宽(0.10-1000 μg L-1,R2 ≥ 0.996),检出限低(0.01-0.02 μg L-1),富集系数大(85.6-98.0)。通过在 MON 的网络中装饰 F 元素,Fe3O4@FMON 具有良好的疏水性和化学稳定性,可重复使用至少 8 次而不降低回收率。这项工作表明,Fe3O4@FMON 在富集复杂基质中的痕量 BUs 方面具有广阔的应用前景,并激发了 FMON 在含氟分析物样品预处理方面的潜力。
Fabrication of fluorinated magnetic microporous organic network for selective and efficient extraction of benzoylurea insecticides in tea beverages
In this work, a novel fluorinated magnetic microporous organic network (Fe3O4@FMON) was exquisitely designed and synthesized for highly efficient and selective magnetic solid phase extraction (MSPE) of fluorinated benzoylurea insecticides (BUs) from complex tea beverage samples. The Fe3O4@FMON exhibited good extraction for BUs via the pre-designed hydrophobic, π-π stacking, hydrogen bonding and specific FF interactions. A sensitive Fe3O4@FMON-based MSPE-HPLC-UV method with wide linear range (0.10–1000 μg L−1, R2 ≥ 0.996), low limits of detection (0.01–0.02 μg L−1), and large enrichment factors (85.6–98.0) for BUs from tea beverage samples was developed. By decorating F elements within MON's networks, the Fe3O4@FMON characterized good hydrophobicity and chemical stability, which could be reused at least 8 times without decrease of recoveries. This work demonstrated the great prospects of Fe3O4@FMON for enriching trace BUs from complex substrates and triggered the potential of FMON for sample pretreatment of fluorinated analytes.
期刊介绍:
Food Chemistry publishes original research papers dealing with the advancement of the chemistry and biochemistry of foods or the analytical methods/ approach used. All papers should focus on the novelty of the research carried out.