通过在染料敏化太阳能电池中加入溶液可加工银质子和无烟煤衍生石墨烯量子点,增强可见光收集能力

IF 10 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Akshatha A. Rao, Santhosh Narendhiran, Manoj Balachandran
{"title":"通过在染料敏化太阳能电池中加入溶液可加工银质子和无烟煤衍生石墨烯量子点,增强可见光收集能力","authors":"Akshatha A. Rao,&nbsp;Santhosh Narendhiran,&nbsp;Manoj Balachandran","doi":"10.1016/j.mtphys.2024.101512","DOIUrl":null,"url":null,"abstract":"<div><p>The major setback for the enhanced performance of DSSC is the narrow absorption window and the interfacial exciton recombination. Therefore, in this work, the photovoltaic performance of dye-sensitized solar cells has been improved by the synergistic effect of anthracite-derived graphene quantum dots and silver plasmons. GQD and Ag coupled photoanodes were fabricated by a facile solution processable process under room temperature. The as-fabricated DSSC TiO<sub>2</sub>/Ag/GQD (TAG) exhibited an enhanced power conversion efficiency of 10.5 % with a current density of 22.40 mAcm<sup>−2</sup> measured under solar irradiation of 100 mWcm<sup>−2</sup> with AM 1.5G. An enhancement surpassing 30.5 % was obtained for the champion cell when compared to the pristine TiO<sub>2</sub> based DSSC. Furthermore, this study emphasizes developing a cutting-edge approach for the high-quality use of fossil fuel-derived graphene quantum dots in energy conversion systems, thereby encouraging the green conversion of fossil fuels and broadening the potential of anthracite coal's utilization in energy conversion applications.</p></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":null,"pages":null},"PeriodicalIF":10.0000,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced visible light harvesting in dye-sensitized solar cells through incorporation of solution-processable silver plasmons and anthracite-derived graphene quantum dots\",\"authors\":\"Akshatha A. Rao,&nbsp;Santhosh Narendhiran,&nbsp;Manoj Balachandran\",\"doi\":\"10.1016/j.mtphys.2024.101512\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The major setback for the enhanced performance of DSSC is the narrow absorption window and the interfacial exciton recombination. Therefore, in this work, the photovoltaic performance of dye-sensitized solar cells has been improved by the synergistic effect of anthracite-derived graphene quantum dots and silver plasmons. GQD and Ag coupled photoanodes were fabricated by a facile solution processable process under room temperature. The as-fabricated DSSC TiO<sub>2</sub>/Ag/GQD (TAG) exhibited an enhanced power conversion efficiency of 10.5 % with a current density of 22.40 mAcm<sup>−2</sup> measured under solar irradiation of 100 mWcm<sup>−2</sup> with AM 1.5G. An enhancement surpassing 30.5 % was obtained for the champion cell when compared to the pristine TiO<sub>2</sub> based DSSC. Furthermore, this study emphasizes developing a cutting-edge approach for the high-quality use of fossil fuel-derived graphene quantum dots in energy conversion systems, thereby encouraging the green conversion of fossil fuels and broadening the potential of anthracite coal's utilization in energy conversion applications.</p></div>\",\"PeriodicalId\":18253,\"journal\":{\"name\":\"Materials Today Physics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":10.0000,\"publicationDate\":\"2024-07-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Today Physics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2542529324001883\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Today Physics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2542529324001883","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

提高染料敏化太阳能电池性能的主要障碍是狭窄的吸收窗口和界面激子重组。因此,在这项工作中,通过无烟煤衍生的石墨烯量子点和银质子的协同效应,提高了染料敏化太阳能电池的光伏性能。GQD 和银耦合光阳极是在室温下通过简便的溶液加工工艺制作的。所制造的 DSSC TiO2/Ag/GQD (TAG) 在 AM 1.5G 的 100 mWcm-2 太阳辐照下,电流密度为 22.40 mAcm-2,功率转换效率提高了 10.5%。与基于原始 TiO2 的 DSSC 相比,冠军电池的功率转换效率提高了 30.5%。此外,本研究还强调了在能源转换系统中高质量使用化石燃料衍生石墨烯量子点的前沿方法,从而鼓励化石燃料的绿色转换,并拓宽无烟煤在能源转换应用中的利用潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Enhanced visible light harvesting in dye-sensitized solar cells through incorporation of solution-processable silver plasmons and anthracite-derived graphene quantum dots

Enhanced visible light harvesting in dye-sensitized solar cells through incorporation of solution-processable silver plasmons and anthracite-derived graphene quantum dots

The major setback for the enhanced performance of DSSC is the narrow absorption window and the interfacial exciton recombination. Therefore, in this work, the photovoltaic performance of dye-sensitized solar cells has been improved by the synergistic effect of anthracite-derived graphene quantum dots and silver plasmons. GQD and Ag coupled photoanodes were fabricated by a facile solution processable process under room temperature. The as-fabricated DSSC TiO2/Ag/GQD (TAG) exhibited an enhanced power conversion efficiency of 10.5 % with a current density of 22.40 mAcm−2 measured under solar irradiation of 100 mWcm−2 with AM 1.5G. An enhancement surpassing 30.5 % was obtained for the champion cell when compared to the pristine TiO2 based DSSC. Furthermore, this study emphasizes developing a cutting-edge approach for the high-quality use of fossil fuel-derived graphene quantum dots in energy conversion systems, thereby encouraging the green conversion of fossil fuels and broadening the potential of anthracite coal's utilization in energy conversion applications.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Materials Today Physics
Materials Today Physics Materials Science-General Materials Science
CiteScore
14.00
自引率
7.80%
发文量
284
审稿时长
15 days
期刊介绍: Materials Today Physics is a multi-disciplinary journal focused on the physics of materials, encompassing both the physical properties and materials synthesis. Operating at the interface of physics and materials science, this journal covers one of the largest and most dynamic fields within physical science. The forefront research in materials physics is driving advancements in new materials, uncovering new physics, and fostering novel applications at an unprecedented pace.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信