Izabela A. Wrona , Paweł Niegodajew , Artur P. Durajski
{"title":"从二元氢化物中有效选择有前途的高温超导体候选材料的秘诀","authors":"Izabela A. Wrona , Paweł Niegodajew , Artur P. Durajski","doi":"10.1016/j.mtphys.2024.101499","DOIUrl":null,"url":null,"abstract":"<div><p>Recent research on compressed binary hydrides have unveiled the potential for achieving superconductivity at near-room-temperature. Nevertheless, the available decision-making procedures standing behind the selection of constituent elements that may potentially exhibit high values of critical temperature (<em>T</em><sub><em>c</em></sub>) are far from optimal. In other words, a lot of experimental and numerical effort is wasted on exploring unpromising compounds. By conducting a deep study of a database containing over 580 binary hydride superconductors, we were able to observe some interesting relationships between <em>T</em><sub><em>c</em></sub> and selected physico-chemical properties of examined compounds. Among studied parameters, the ratio of the sum of the molecular weight of heavier atoms to the total mass of all hydrogen atoms in the chemical formula of hydride (<em>M</em><sub><em>X</em></sub>/<em>M</em><sub><em>H</em></sub>) was found to be the most valuable indicator that can help to screen for new promising superconductor candidates. This is because the highest <em>T</em><sub><em>c</em></sub> requires the lowest <em>M</em><sub><em>X</em></sub>/<em>M</em><sub><em>H</em></sub> ratio. Statistical analysis indicates a 28% chance of finding <em>T</em><sub><em>c</em></sub> > 200 K within 0 < <em>M</em><sub><em>X</em></sub>/<em>M</em><sub><em>H</em></sub> < 15. It is expected that these findings will not only allow for more efficient use of resources by improving future superconductor candidates selection but also they will accelerate ongoing experimental and numerical research that should bring new exciting discoveries in a much shorter time.</p></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":null,"pages":null},"PeriodicalIF":10.0000,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2542529324001755/pdfft?md5=13d2273880d6e6e0c8e66649437dada0&pid=1-s2.0-S2542529324001755-main.pdf","citationCount":"0","resultStr":"{\"title\":\"A recipe for an effective selection of promising candidates for high-temperature superconductors among binary hydrides\",\"authors\":\"Izabela A. Wrona , Paweł Niegodajew , Artur P. Durajski\",\"doi\":\"10.1016/j.mtphys.2024.101499\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Recent research on compressed binary hydrides have unveiled the potential for achieving superconductivity at near-room-temperature. Nevertheless, the available decision-making procedures standing behind the selection of constituent elements that may potentially exhibit high values of critical temperature (<em>T</em><sub><em>c</em></sub>) are far from optimal. In other words, a lot of experimental and numerical effort is wasted on exploring unpromising compounds. By conducting a deep study of a database containing over 580 binary hydride superconductors, we were able to observe some interesting relationships between <em>T</em><sub><em>c</em></sub> and selected physico-chemical properties of examined compounds. Among studied parameters, the ratio of the sum of the molecular weight of heavier atoms to the total mass of all hydrogen atoms in the chemical formula of hydride (<em>M</em><sub><em>X</em></sub>/<em>M</em><sub><em>H</em></sub>) was found to be the most valuable indicator that can help to screen for new promising superconductor candidates. This is because the highest <em>T</em><sub><em>c</em></sub> requires the lowest <em>M</em><sub><em>X</em></sub>/<em>M</em><sub><em>H</em></sub> ratio. Statistical analysis indicates a 28% chance of finding <em>T</em><sub><em>c</em></sub> > 200 K within 0 < <em>M</em><sub><em>X</em></sub>/<em>M</em><sub><em>H</em></sub> < 15. It is expected that these findings will not only allow for more efficient use of resources by improving future superconductor candidates selection but also they will accelerate ongoing experimental and numerical research that should bring new exciting discoveries in a much shorter time.</p></div>\",\"PeriodicalId\":18253,\"journal\":{\"name\":\"Materials Today Physics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":10.0000,\"publicationDate\":\"2024-07-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2542529324001755/pdfft?md5=13d2273880d6e6e0c8e66649437dada0&pid=1-s2.0-S2542529324001755-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Today Physics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2542529324001755\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Today Physics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2542529324001755","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
A recipe for an effective selection of promising candidates for high-temperature superconductors among binary hydrides
Recent research on compressed binary hydrides have unveiled the potential for achieving superconductivity at near-room-temperature. Nevertheless, the available decision-making procedures standing behind the selection of constituent elements that may potentially exhibit high values of critical temperature (Tc) are far from optimal. In other words, a lot of experimental and numerical effort is wasted on exploring unpromising compounds. By conducting a deep study of a database containing over 580 binary hydride superconductors, we were able to observe some interesting relationships between Tc and selected physico-chemical properties of examined compounds. Among studied parameters, the ratio of the sum of the molecular weight of heavier atoms to the total mass of all hydrogen atoms in the chemical formula of hydride (MX/MH) was found to be the most valuable indicator that can help to screen for new promising superconductor candidates. This is because the highest Tc requires the lowest MX/MH ratio. Statistical analysis indicates a 28% chance of finding Tc > 200 K within 0 < MX/MH < 15. It is expected that these findings will not only allow for more efficient use of resources by improving future superconductor candidates selection but also they will accelerate ongoing experimental and numerical research that should bring new exciting discoveries in a much shorter time.
期刊介绍:
Materials Today Physics is a multi-disciplinary journal focused on the physics of materials, encompassing both the physical properties and materials synthesis. Operating at the interface of physics and materials science, this journal covers one of the largest and most dynamic fields within physical science. The forefront research in materials physics is driving advancements in new materials, uncovering new physics, and fostering novel applications at an unprecedented pace.