从二元氢化物中有效选择有前途的高温超导体候选材料的秘诀

IF 10 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Izabela A. Wrona , Paweł Niegodajew , Artur P. Durajski
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引用次数: 0

摘要

最近对压缩二元氢化物的研究揭示了在接近室温下实现超导的潜力。然而,在选择可能表现出高临界温度(Tc)值的组成元素时,现有的决策程序远非最佳。换句话说,大量的实验和数值工作都浪费在了探索不具潜力的化合物上。通过对包含 580 多种二元氢化物超导体的数据库进行深入研究,我们能够观察到临界温度(Tc)与所选化合物的物理化学特性之间的一些有趣关系。在所研究的参数中,较重原子的分子量总和与氢化物化学式中所有氢原子的总质量之比(MX/MH)被认为是最有价值的指标,有助于筛选新的有前途的候选超导体。这是因为最高的 Tc 需要最低的 MX/MH 比率。统计分析表明,在 0 < MX/MH < 15 的范围内找到 Tc > 200 K 的几率为 28%。预计这些发现不仅能通过改进未来超导体候选者的选择来更有效地利用资源,还能加速正在进行的实验和数值研究,从而在更短的时间内带来新的激动人心的发现。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A recipe for an effective selection of promising candidates for high-temperature superconductors among binary hydrides

A recipe for an effective selection of promising candidates for high-temperature superconductors among binary hydrides

Recent research on compressed binary hydrides have unveiled the potential for achieving superconductivity at near-room-temperature. Nevertheless, the available decision-making procedures standing behind the selection of constituent elements that may potentially exhibit high values of critical temperature (Tc) are far from optimal. In other words, a lot of experimental and numerical effort is wasted on exploring unpromising compounds. By conducting a deep study of a database containing over 580 binary hydride superconductors, we were able to observe some interesting relationships between Tc and selected physico-chemical properties of examined compounds. Among studied parameters, the ratio of the sum of the molecular weight of heavier atoms to the total mass of all hydrogen atoms in the chemical formula of hydride (MX/MH) was found to be the most valuable indicator that can help to screen for new promising superconductor candidates. This is because the highest Tc requires the lowest MX/MH ratio. Statistical analysis indicates a 28% chance of finding Tc > 200 K within 0 < MX/MH < 15. It is expected that these findings will not only allow for more efficient use of resources by improving future superconductor candidates selection but also they will accelerate ongoing experimental and numerical research that should bring new exciting discoveries in a much shorter time.

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来源期刊
Materials Today Physics
Materials Today Physics Materials Science-General Materials Science
CiteScore
14.00
自引率
7.80%
发文量
284
审稿时长
15 days
期刊介绍: Materials Today Physics is a multi-disciplinary journal focused on the physics of materials, encompassing both the physical properties and materials synthesis. Operating at the interface of physics and materials science, this journal covers one of the largest and most dynamic fields within physical science. The forefront research in materials physics is driving advancements in new materials, uncovering new physics, and fostering novel applications at an unprecedented pace.
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