{"title":"多孔硫代氨基脲官能化共价有机框架可作为 Hg2+ 的灵敏荧光传感器","authors":"Yuan-Jie Xue","doi":"10.1016/j.jfca.2024.106500","DOIUrl":null,"url":null,"abstract":"<div><p>The detection of heavy metal pollution in food and environment is of great significance for environmental pollution control and human health. 1,3,5-Tris(p-formylphenyl)benzene (TFPB) and thiosemicarbazide (TS) were used as building blocks to construct a thiosemicarbazide functionalized covalent organic framework (COF) through Schiff base condensation reaction. Hg<sup>2+</sup> ions can significantly enhance the fluorescence of the prepared COF-TFPB-TS, and thus COF-TFPB-TS can be utilized for highly selective and sensitive detection of Hg<sup>2+</sup> ions. Moreover, COF-TFPB-TS showed high performance for detecting Hg<sup>2+</sup> in fresh fruit juice, mineral water and tap water, which demonstrated its ability to be applied in real sample testing.</p></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"134 ","pages":"Article 106500"},"PeriodicalIF":4.0000,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A porous thiosemicarbazide functionalized covalent organic framework served as sensitive fluorescent sensor for Hg2+\",\"authors\":\"Yuan-Jie Xue\",\"doi\":\"10.1016/j.jfca.2024.106500\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The detection of heavy metal pollution in food and environment is of great significance for environmental pollution control and human health. 1,3,5-Tris(p-formylphenyl)benzene (TFPB) and thiosemicarbazide (TS) were used as building blocks to construct a thiosemicarbazide functionalized covalent organic framework (COF) through Schiff base condensation reaction. Hg<sup>2+</sup> ions can significantly enhance the fluorescence of the prepared COF-TFPB-TS, and thus COF-TFPB-TS can be utilized for highly selective and sensitive detection of Hg<sup>2+</sup> ions. Moreover, COF-TFPB-TS showed high performance for detecting Hg<sup>2+</sup> in fresh fruit juice, mineral water and tap water, which demonstrated its ability to be applied in real sample testing.</p></div>\",\"PeriodicalId\":15867,\"journal\":{\"name\":\"Journal of Food Composition and Analysis\",\"volume\":\"134 \",\"pages\":\"Article 106500\"},\"PeriodicalIF\":4.0000,\"publicationDate\":\"2024-07-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Food Composition and Analysis\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0889157524005349\",\"RegionNum\":2,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Food Composition and Analysis","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0889157524005349","RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
A porous thiosemicarbazide functionalized covalent organic framework served as sensitive fluorescent sensor for Hg2+
The detection of heavy metal pollution in food and environment is of great significance for environmental pollution control and human health. 1,3,5-Tris(p-formylphenyl)benzene (TFPB) and thiosemicarbazide (TS) were used as building blocks to construct a thiosemicarbazide functionalized covalent organic framework (COF) through Schiff base condensation reaction. Hg2+ ions can significantly enhance the fluorescence of the prepared COF-TFPB-TS, and thus COF-TFPB-TS can be utilized for highly selective and sensitive detection of Hg2+ ions. Moreover, COF-TFPB-TS showed high performance for detecting Hg2+ in fresh fruit juice, mineral water and tap water, which demonstrated its ability to be applied in real sample testing.
期刊介绍：
The Journal of Food Composition and Analysis publishes manuscripts on scientific aspects of data on the chemical composition of human foods, with particular emphasis on actual data on composition of foods; analytical methods; studies on the manipulation, storage, distribution and use of food composition data; and studies on the statistics, use and distribution of such data and data systems. The Journal''s basis is nutrient composition, with increasing emphasis on bioactive non-nutrient and anti-nutrient components. Papers must provide sufficient description of the food samples, analytical methods, quality control procedures and statistical treatments of the data to permit the end users of the food composition data to evaluate the appropriateness of such data in their projects.
The Journal does not publish papers on: microbiological compounds; sensory quality; aromatics/volatiles in food and wine; essential oils; organoleptic characteristics of food; physical properties; or clinical papers and pharmacology-related papers.
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