Jiaxin Zhang, Liqiong Deng, Shihong Xia, Chenyu Guo, Kunzi Liu, Li Chen, Wei Liu, Hui Xiao, Zhenhai Yang, Wei Guo and Jichun Ye
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However, a combination of III-nitride and other wide bandgap materials can either enrich the functionality of devices such as spectrum-selective and broadband UV detectionor offer opportunities to enhance device performance, including high photoresponsivity, high external quantum efficiency, low dark current and fast response time. This topical review focuses on giving a thorough review of the III-nitride-based hybrid-type UV PDs, their recent progress and future prospects. We highlight the different optical and electrical properties of various materials including GaN, Ga2O3, ZnO, perovskite, etc. By carefully choosing the materials on both sides of the heterojunction and modulating the thickness and Fermi levels and corresponding layers, p–i–n, Schottky or metal–semiconductor–metal-type PDs were successfully fabricated. They displayed outstanding device performance and novel spectral-selective properties. The advantages for future development of these hybrid-type PDs will be discussed, such as inherently formed p–n junction with large depletion regions at the interface of two different materials and capability of bandgap engineering to tune the band offset between the conduction and valence bands, thus enabling large barrier height for one type of carrier without influencing the other. 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引用次数: 0
摘要
固态紫外线(UV)光电探测器(PD)具有体积小、无需外部冷却、选择性高以及能够利用半导体材料的能带结构实现各种波长的检测等优点,因此受到了广泛关注。III 族氮化物薄膜是典型的宽带隙半导体,具有成熟的 n 型和 p 型掺杂能力,是固态紫外-光致发光器件的理想候选材料。然而,III 族氮化物与其他宽带隙材料的结合既可以丰富器件的功能,如光谱选择性和宽带紫外检测,也可以提供提高器件性能的机会,包括高光致发光性、高外部量子效率、低暗电流和快速响应时间。本专题综述将重点全面回顾基于 III 族氮化物的混合型紫外光直放电器件及其最新进展和未来前景。我们重点介绍了各种材料(包括氮化镓、氧化镓、氧化锌、过氧化物等)的不同光学和电学特性。通过精心选择异质结两侧的材料、调节厚度和费米级以及相应的层,成功制备出了 p-i-n、肖特基或金属-半导体-金属型 PD。它们显示出出色的器件性能和新颖的光谱选择特性。我们将讨论这些混合型光致发光器件未来发展的优势,例如在两种不同材料的界面上固有地形成了具有较大耗尽区的 p-n 结,以及通过带隙工程来调整导带和价带之间的带偏移,从而使一种载流子具有较大的势垒高度而不影响另一种载流子的能力。此外,还将讨论混合型 UV-PD 因界面质量差而产生的缺点,以及在纳米结构混合 UV-PD 中形成电接触所面临的挑战。
Recent advances and prospects for a GaN-based hybrid type ultraviolet photodetector
Solid-state ultraviolet (UV) photodetectors (PDs) have received significant attention due to their advantages of small size, absence of external cooling, high selectivity and the ability to utilize the energy band structure semiconductor materials to achieve detection across various wavelengths. III-nitride thin films, as typical wide bandgap semiconductors with mature n-type and p-type doping capabilities, are ideal candidates for solid-state UV-PDs. However, a combination of III-nitride and other wide bandgap materials can either enrich the functionality of devices such as spectrum-selective and broadband UV detectionor offer opportunities to enhance device performance, including high photoresponsivity, high external quantum efficiency, low dark current and fast response time. This topical review focuses on giving a thorough review of the III-nitride-based hybrid-type UV PDs, their recent progress and future prospects. We highlight the different optical and electrical properties of various materials including GaN, Ga2O3, ZnO, perovskite, etc. By carefully choosing the materials on both sides of the heterojunction and modulating the thickness and Fermi levels and corresponding layers, p–i–n, Schottky or metal–semiconductor–metal-type PDs were successfully fabricated. They displayed outstanding device performance and novel spectral-selective properties. The advantages for future development of these hybrid-type PDs will be discussed, such as inherently formed p–n junction with large depletion regions at the interface of two different materials and capability of bandgap engineering to tune the band offset between the conduction and valence bands, thus enabling large barrier height for one type of carrier without influencing the other. The drawbacks of hybrid-type UV-PD due to poor interface quality and challenges in forming electrical contact in nanostructured hybrid UV-PD will also be discussed.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.