{"title":"类镁离子和类氯离子的磁场和超精细诱导转变参数的理论研究","authors":"Zhanbin Chen","doi":"10.1016/j.elspec.2024.147420","DOIUrl":null,"url":null,"abstract":"<div><p><span>In this paper, we report an extensive theoretical study of the magnetic-field and hyperfine-induced transition parameters for magnesium-like ions from Cr XIII to Zn XIX and chlorine-like ions from Mn IX to Co XI. These ions have a high abundance in the astrophysical plasma. Zeeman splitting level energies<span>, hyperfine- and/or magnetic-field dependent wavelengths, and transition rates of the 3s3p </span></span><span><math><mrow><msup><mrow></mrow><mrow><mn>3</mn></mrow></msup><msub><mrow><mi>P</mi></mrow><mrow><mn>2</mn><mo>,</mo><mn>1</mn><mo>,</mo><mn>0</mn></mrow></msub><mo>→</mo><mn>3</mn><msup><mrow><mi>s</mi></mrow><mrow><mn>2</mn></mrow></msup></mrow></math></span> <span><math><mrow><msup><mrow></mrow><mrow><mn>1</mn></mrow></msup><msub><mrow><mi>S</mi></mrow><mrow><mn>0</mn></mrow></msub></mrow></math></span> (for magnesium-like ions) and the 3p<sup>4</sup>3d <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>D</mi></mrow><mrow><mn>7</mn><mo>/</mo><mn>2</mn></mrow></msub><mo>→</mo></mrow></math></span> 3p<sup>5</sup> <span><math><mrow><msup><mrow></mrow><mrow><mn>2</mn></mrow></msup><msub><mrow><mi>P</mi></mrow><mrow><mn>3</mn><mo>/</mo><mn>2</mn></mrow></msub></mrow></math></span><span> line (for chlorine-like ions), are computed using the multiconfiguration Dirac–Fock method. Some higher-order effects, such as the Breit interaction and quantum electrodynamics<span> corrections, are included in the relativistic configuration interaction method<span>, as this makes the results more accurate. A comparison between the our predictions and other theoretical and experimental values is made. A satisfactory agreement is achieved. Besides providing valuable information for spectral line<span> analysis, the present work will have a variety of implications for fusion and astrophysical plasma sources, for example, in the determination of magnetic fields in solar coronas and other stars.</span></span></span></span></p></div>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Theoretical investigation of magnetic-field and hyperfine-induced transition parameters for magnesium-like and chlorine-like ions\",\"authors\":\"Zhanbin Chen\",\"doi\":\"10.1016/j.elspec.2024.147420\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span>In this paper, we report an extensive theoretical study of the magnetic-field and hyperfine-induced transition parameters for magnesium-like ions from Cr XIII to Zn XIX and chlorine-like ions from Mn IX to Co XI. These ions have a high abundance in the astrophysical plasma. Zeeman splitting level energies<span>, hyperfine- and/or magnetic-field dependent wavelengths, and transition rates of the 3s3p </span></span><span><math><mrow><msup><mrow></mrow><mrow><mn>3</mn></mrow></msup><msub><mrow><mi>P</mi></mrow><mrow><mn>2</mn><mo>,</mo><mn>1</mn><mo>,</mo><mn>0</mn></mrow></msub><mo>→</mo><mn>3</mn><msup><mrow><mi>s</mi></mrow><mrow><mn>2</mn></mrow></msup></mrow></math></span> <span><math><mrow><msup><mrow></mrow><mrow><mn>1</mn></mrow></msup><msub><mrow><mi>S</mi></mrow><mrow><mn>0</mn></mrow></msub></mrow></math></span> (for magnesium-like ions) and the 3p<sup>4</sup>3d <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>D</mi></mrow><mrow><mn>7</mn><mo>/</mo><mn>2</mn></mrow></msub><mo>→</mo></mrow></math></span> 3p<sup>5</sup> <span><math><mrow><msup><mrow></mrow><mrow><mn>2</mn></mrow></msup><msub><mrow><mi>P</mi></mrow><mrow><mn>3</mn><mo>/</mo><mn>2</mn></mrow></msub></mrow></math></span><span> line (for chlorine-like ions), are computed using the multiconfiguration Dirac–Fock method. Some higher-order effects, such as the Breit interaction and quantum electrodynamics<span> corrections, are included in the relativistic configuration interaction method<span>, as this makes the results more accurate. A comparison between the our predictions and other theoretical and experimental values is made. A satisfactory agreement is achieved. Besides providing valuable information for spectral line<span> analysis, the present work will have a variety of implications for fusion and astrophysical plasma sources, for example, in the determination of magnetic fields in solar coronas and other stars.</span></span></span></span></p></div>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0368204824000033\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0368204824000033","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
在本文中,我们报告了对从 Cr XIII 到 Zn XIX 的类镁离子和从 Mn IX 到 Co XI 的类氯离子的磁场和超精细诱导转变参数的广泛理论研究。这些离子在天体物理等离子体中具有很高的丰度。利用多构型 Dirac-Fock 方法计算了 3s3p 3P2,1,0→3s2 1S0(类镁离子)和 3p43d 4D7/2→ 3p5 2P3/2 线(类氯离子)的泽曼分裂能、超精细和/或磁场相关波长以及转变率。一些高阶效应,如布雷特相互作用和量子电动力学修正,被纳入相对论构型相互作用方法中,因为这样会使结果更加精确。我们将预测值与其他理论值和实验值进行了比较。结果令人满意。除了为光谱线分析提供有价值的信息外,本研究还将对核聚变和天体物理等离子体源产生各种影响,例如,在确定太阳日冕和其他恒星的磁场方面。
Theoretical investigation of magnetic-field and hyperfine-induced transition parameters for magnesium-like and chlorine-like ions
In this paper, we report an extensive theoretical study of the magnetic-field and hyperfine-induced transition parameters for magnesium-like ions from Cr XIII to Zn XIX and chlorine-like ions from Mn IX to Co XI. These ions have a high abundance in the astrophysical plasma. Zeeman splitting level energies, hyperfine- and/or magnetic-field dependent wavelengths, and transition rates of the 3s3p (for magnesium-like ions) and the 3p43d 3p5 line (for chlorine-like ions), are computed using the multiconfiguration Dirac–Fock method. Some higher-order effects, such as the Breit interaction and quantum electrodynamics corrections, are included in the relativistic configuration interaction method, as this makes the results more accurate. A comparison between the our predictions and other theoretical and experimental values is made. A satisfactory agreement is achieved. Besides providing valuable information for spectral line analysis, the present work will have a variety of implications for fusion and astrophysical plasma sources, for example, in the determination of magnetic fields in solar coronas and other stars.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
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