用于模后等温固化改进和加速可靠性评估的环氧模复合材料表征和固化动力学

Matthew M. Fernandez, Beila Angeles, Deo Navaja
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引用次数: 2

摘要

通过动态热分析和热力学试验,对环氧基模具复合材料进行了表征。采用Kissinger方法成功地模拟了模具化合物的固化动力学参数。模后等温固化改善了环氧基模具复合材料的热学和力学性能,如焓、热流、热重失重、弯曲模量和按钮剪切强度。这种改进可归因于进一步的聚合物交联反应。所有主要的改进开始于模具等温固化后的第4小时,并在随后的时间稳定下来。利用动力学模型计算的活化能,通过加速温度循环试验对其可靠性性能进行了评价。加速温度循环试验验证了模后等温固化提高了模具-引线框架界面的可靠性性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Epoxy Mold Compound Characterization and Cure Kinetics for Post Mold Isothermal Cure Improvement and Accelerated Reliability Assessment
Epoxy-based mold compound were successfully characterized through dynamic thermal analyses and thermo-mechanical tests. The mold compound's cure kinetic parameters were successfully modeled using the Kissinger's method. Post mold isothermal cure improved the thermal and mechanical properties of the epoxy-based mold compound such as enthalpy, heat flow, thermogravimetric weight loss, flexural modulus, and button shear strength. The improvements can be attributed with the further polymer cross-linking reaction. All major improvements started at 4th hour post mold isothermal cure and stabilized at succeeding time. Furthermore, the reliability performance was evaluated through an accelerated temperature cycle test using the calculated activation energy from the kinetic model. Accelerated temperature cycle test validated that post mold isothermal cure improve the reliability performance of the mold-to-leadframe interface.
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