硅太阳圆片线电解火花复合加工及表面特性研究

W. Wang, Z.D. Liu, Z. Tian, Y. Huang, Z.X. Liu, N.N. Ekere
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引用次数: 6

摘要

本文提出了一种基于线材WESHM策略的切片新方法,将放电和阳极刻蚀结合为一个整体过程。通过实验研究了低电阻(0.1~10Omegamiddotcm)单晶硅和多晶硅的加工速率、表面质量和晶圆厚度对晶圆表面特性的影响。结果表明:在最佳电参数和电解液条件下,最大加工速率为~ 600 mm2/min,晶圆厚度小于120 mm;与线切割加工相比,热影响区和有害金属残留明显减少。陨石坑内部有密集的微米级和亚微米级的锥形孔,这些孔可能是由高温电解侵蚀形成的,表面纹理相当均匀,呈深色。通过测量光在样品上的反射率来评价这种纹理方法的效果。实验结果表明,薄片上的反射率甚至低于标准太阳能电池。此外,对于形成表面的锥形孔隙,研究了分形分析,以描述极其复杂的表面结构,这与反射率有关,可以有效地表征表面形貌。研究结果表明,线电解火花混合加工技术具有实现高质量硅片的良好潜力,可为光伏工业用低阻硅的生产提供一种高效率、低成本的技术。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study of wire electrolytic-spark hybrid machining of silicon solar wafer and surface characteristics
In this paper, a new slicing method based on wire WESHM strategy, which combines electric discharge and anodic etching into a whole process, is presented. Experiments were conducted to evaluate effect of the machining rate, surface quality and wafer thickness of low resistance (0.1~10Omegamiddotcm) mono-crystalline and poly-crystalline silicon on the wafer surface characteristics. The results show that with optimal electrical parameters and electrolyte, the maxim machining rate is ~ 600 mm2/min and wafer thickness is less than 120 mum. In comparison to wire electrical discharge machining (WEDM), heat affected zone and harmful metal residual are remarkably diminished. Dense micron and submicron conic pores, which may be introduced by high temperature electrolytic erosion, are located in the craters and surface texture is quite even giving a dark color. The reflectance of light on the samples was measured to evaluate the effect of this texturing method. Experimental results show the reflectance on sliced wafer is even lower than the standard solar cells. Furthermore, in the case of cone-shaped pores for the formed surface, a fractal analysis was investigated to describe the extremely complicated surface structure, which was related to the reflectivity and could be useful to characterize surface topography properly. It is demonstrated that the wire electrolytic-spark hybrid machining (WESHM) technique has good potential for achieving high quality silicon wafer slices, and can provide a high efficiency, low-cost technique for the production of the low resistance silicon used in the photovoltaic industry.
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